Abstract
The paper reports data obtained in the course of a comprehensive physicochemical study of Li-tosudite, a mixed-layer mineral from hydrothermally altered rocks in western Chukotka, Russia, whose formula was reliably established. The enthalpy of formation of Li-tosudite from Chukotka, Ca0.15(Li0.9Mg0.2Al6.0)[Si6.4Al1.6O20](OH)10 · 3.3H2O, from elements was experimentally determined by melt solution calorimetry in a high-temperature Calvet microcalorimeter: ΔfH oel (298.15 К) =–15087 ± 26 kJ/mol. The standard entropy and Gibbs free energy of formation of this mineral were evaluated.
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Original Russian Text © L.P. Ogorodova, M.F. Vigasina, E.A. Vlasov, L.V. Mel’chakova, V.V. Krupskaya, E.M. Spiridonov, 2018, published in Geokhimiya, 2018, No. 3, pp. 245–249.
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Ogorodova, L.P., Vigasina, M.F., Vlasov, E.A. et al. Li-Tosudite: X-Ray Diffraction, IR Spectroscopic, Thermal, and Thermochemical Studies. Geochem. Int. 56, 234–239 (2018). https://doi.org/10.1134/S0016702918030059
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DOI: https://doi.org/10.1134/S0016702918030059