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The effect of hydration of ions of inorganic salts on the shape of the Raman stretching band of water

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Abstract

The shape of the Raman stretching band of water molecules in aqueous solutions of electrolytes KBr, KCl, KI, NaCl, and NaI is studied. It is confirmed that the characteristics of the stretching band strongly depend on the concentration and type of salt. The behavior of different parameters of the band is explained in terms of the theory of hydration of salts.

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References

  1. D. Eisenberg and W. Kauzmann, The Structure and Properties of Water (Oxford Univ. Press, New York, 1969; Gidrometeoizdat, Leningrad, 1975).

    Google Scholar 

  2. G. E. Walrafen, J. Chem. Phys. 40, 3249 (1964).

    Google Scholar 

  3. G. E. Walrafen, M. R. Fisher, M. S. Hokmabadi, and W. H. Yang, J. Chem. Phys. 85, 6970 (1986).

    ADS  Google Scholar 

  4. G. E. Walrafen, M. S. Hokmabadi, W.-H. Yang, et al., J. Phys. Chem. 93, 2909 (1989).

    Article  Google Scholar 

  5. G. E. Walrafen, W.-H. Yang, Y. C. Chu, and M. S. Hokmabadi, J. Phys. Chem. 100, 1381 (1996).

    Google Scholar 

  6. Yu. Ya. Efimov and Yu. I. Naberukhin, Zh. Strukt. Khim. 21(3), 95 (1980).

    Google Scholar 

  7. K. Furic, I. Ciglenecki, and B. Cosovic, J. Mol. Struct. 6, 225 (2000).

    Google Scholar 

  8. F. Rull and J. A. De Saja, J. Raman Spectrosc. 17, 167 (1986).

    Article  Google Scholar 

  9. P. Terpstra, D. Combes, and A. Zwick, J. Chem. Phys. 92, 65 (1990).

    Article  ADS  Google Scholar 

  10. T. A. Dolenko, I. V. Churina, V. V. Fadeev, and S. M. Glushkov, J. Raman Spectrosc. 31, 863 (2000).

    Article  Google Scholar 

  11. K. P. Mishchenko, Zh. Fiz. Khim. 26, 1736 (1952).

    Google Scholar 

  12. O. A. Samoilov, The Structure of Aqueous Solutions of Electrolytes and Hydration of Ions (Akad. Nauk SSSR, Moscow, 1957) [in Russian].

    Google Scholar 

  13. G. A. Krestov, Zh. Strukt. Khim. 3, 137 (1962).

    Google Scholar 

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Translated from Optika i Spektroskopiya, Vol. 98, No. 2, 2005, pp. 269–273.

Original Russian Text Copyright © 2005 by Burikov, Dolenko, Velikotny\(\overset{\lower0.5em\hbox{$\smash{\scriptscriptstyle\smile}$}}{l}\), Sugonyaev, Fadeev.

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Burikov, S.A., Dolenko, T.A., Velikotnyi, P.A. et al. The effect of hydration of ions of inorganic salts on the shape of the Raman stretching band of water. Opt. Spectrosc. 98, 235–239 (2005). https://doi.org/10.1134/1.1870066

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  • DOI: https://doi.org/10.1134/1.1870066

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