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New cluster-type rhodium selenochlorides in oxidative carbonylation of methane

  • Inorganic Synthesis and Industrial Inorganic Chemistry
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Abstract

New rhodium selenochlorides Rh4Se16Cl10 and Rh4Se18Cl10 whose structure is based on the cluster “cubane” [Rh4(μ3-Se)4] and products of their thermal transformations were obtained. The catalytic properties of the compounds on various carbon and silica supports in oxidative carbonylation of methane in the gas phase and their dependence on the catalyst preparation technique, type of support, and size of its nanopores were analyzed.

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Authors and Affiliations

  1. Vernadskii Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine

    S. V. Volkov, L. B. Khar’kova, Z. A. Fokina, O. G. Yanko, P. E. Strizhak, G. R. Kosmambetova, V. I. Gritsenko & A. M. Korduban

  2. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine

    S. V. Volkov, L. B. Khar’kova, Z. A. Fokina, O. G. Yanko, P. E. Strizhak, G. R. Kosmambetova, V. I. Gritsenko & A. M. Korduban

  3. Kurdyumov Institute of Metal-Physics, National Academy of Sciences of Ukraine, Kiev, Ukraine

    S. V. Volkov, L. B. Khar’kova, Z. A. Fokina, O. G. Yanko, P. E. Strizhak, G. R. Kosmambetova, V. I. Gritsenko & A. M. Korduban

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  1. S. V. Volkov
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  2. L. B. Khar’kova
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  3. Z. A. Fokina
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  4. O. G. Yanko
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  5. P. E. Strizhak
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  6. G. R. Kosmambetova
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  7. V. I. Gritsenko
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  8. A. M. Korduban
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Additional information

Original Russian Text © S.V. Volkov, L.B. Khar’kova, Z.A. Fokina, O.G. Yanko, P.E. Strizhak, G.R. Kosmambetova, V.I. Gritsenko, A.M. Korduban, 2007, published in Zhurnal Prikladnoi Khimii, 2007, Vol. 80, No. 2, pp. 195–201.

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Volkov, S.V., Khar’kova, L.B., Fokina, Z.A. et al. New cluster-type rhodium selenochlorides in oxidative carbonylation of methane. Russ J Appl Chem 80, 193–200 (2007). https://doi.org/10.1134/S107042720702005X

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  • DOI: https://doi.org/10.1134/S107042720702005X

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