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Geminal acylnitrostyrenes in the reaction with ortho-aminothiophenol

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Abstract

The synthesis of previously unknown 2,3- and 2,5-dihydro-1,5-benzothiazepines sontaining nitro group was performed by the easy sondensation of geminal acylnitrostyrenes with the o-aminothiophenol. The structure of the obtained sompounds was studied by physicochemical methods. By X-ray diffraction analysis the geometry and structural parameters of 4-methyl-3-nitro-2-phenyl-2,3-dihydro-1,5-benzothiazepine were determined.

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Authors and Affiliations

  1. Herzen Russian State Pedagogical University, nab. r. Moiki 48, St. Petersburg, 191186, Russia

    V. M. Berestovitskaya, R. I. Baichurin & N. I. Aboskalova

  2. Nesmeyanov Institute of Organoelemental Compounds, Russian Academy of Sciences, Moscow, Russia

    K. A. Lysenko & I. V. Anan’ev

Authors
  1. V. M. Berestovitskaya
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  2. R. I. Baichurin
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  3. N. I. Aboskalova
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  4. K. A. Lysenko
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  5. I. V. Anan’ev
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Correspondence to V. M. Berestovitskaya.

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Original Russian Text © V.M. Berestovitskaya, R.I. Baichurin, N.I. Aboskalova, K.A. Lysenko, I.V. Anan’ev, 2011, published in Zhurnal Obshchei Khimii, 2011, Vol. 81, No. 6, pp. 970–977.

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Berestovitskaya, V.M., Baichurin, R.I., Aboskalova, N.I. et al. Geminal acylnitrostyrenes in the reaction with ortho-aminothiophenol. Russ J Gen Chem 81, 1163–1170 (2011). https://doi.org/10.1134/S1070363211060156

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  • DOI: https://doi.org/10.1134/S1070363211060156

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