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Reaction of tetrafluorosilane with tris(2-hydroxyethyl)amine, tris(2-trimethylsiloxyethyl)amine and bis(2-trimethylsiloxyethyl)amine and its N-methyl derivative. 1,1-difluoroquasisilatranes

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Abstract

Reaction of tetrafluorosilane with tris(2-hydroxyethyl)-and tris(2-trimethylsiloxyethyl)amine results in formation of 1-fluorosilatrane and fluorosilatrane in 75 and 53% yield, respectively. Reaction of tetrafluorosilane with bis(2-trimethylsiloxyethyl)amine and its N-methyl derivative leads to the hitherto unknown 1,1-difluoroquasisilatranes (N → Si) F2Si(OCH2CH2)2NR (R = H, Me) containing donor-acceptor bond N → Si and pentacoordinate silicon atom. The structure of the synthesized compounds was proved by 1H, 13C, 15N, 19F, 29Si NMR and IR spectroscopy.

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References

  1. Ennan, A.A., Gavrilova, L.A., and Kirichenko, I.N., Zh. Neorg. Khim., 1974, vol. 19, no. 12, p. 3264.

    CAS  Google Scholar 

  2. Krebs, R., Schomburg, D., and Schutzler, R., Z. Naturforsch, 1985, vol. 40B, p. 282.

    CAS  Google Scholar 

  3. Voronkov, M.G. and Zelchan, G.I., Chem. Heterocycl. Comp., 1965, no. 1, p. 51.

  4. Voronkov, M.G. and D’yakov, V.M., Silatranes (Silatrany), Novosibirsk: Nauka, 1978.

    Google Scholar 

  5. Voronkov, M.G., Dyakov, V.M., and Kirpichenko, S.V., J. Organometal. Chem., 1982, vol. 233, p. 1.

    Article  CAS  Google Scholar 

  6. Voronkov, M.G., Shevchenko, S.G., Brodskaya, E.I., Baryshok, V.P., D’yakov, V.M., Frolov, Yu.L., Raikh, P., and Anisimova, I.L., Atlas spektrov organicheskikh soedinenii. IK-i KR-spektry silatranov i modelnykh soedinenii (Atlas of Spectra of Organic Compounds. IR and Raman Spectra of Silatranes and Model Compounds), Novosibirsk: Inst. Org. Khim., Academy of Sciences of USSR, Siberian Branch, 1985, vol. 31.

    Google Scholar 

  7. Voronkov, M.G., Baryshok, V.P., Petukhov, L.P., Rakhlin, V.I., Mirskov, R.G., and Pestunovich, V.A., J. Organometal. Chem., 1988, vol. 358, nos. 1–3, p. 39.

    Article  CAS  Google Scholar 

  8. Pestunovich, V., Kirpichenko, S. and Voronkov, M. in: The Chemistry of Organic Silicon Compounds, Rappoport, Z. and Apeloig, Y., Eds., New York: Wiley, 1998, vol. 2, p. 1447.

    Chapter  Google Scholar 

  9. Voronkov, M.G., Boyarkina, E.V., Gebel’, I.A., Albanov, A.I., and Basenko, S.V., Zh. Obshc. Khim., 2005, vol. 75, no. 12, p. 2018.

    Google Scholar 

  10. Witanowski, M. and Stefaniak, L., in: Annual Reports on NMR Spectroscopy, Webb, G.A., Ed., London: Academic Press, 1981.

    Google Scholar 

  11. Birgele, I.S., Kemme, A.A., Kupchee, E.L., Liepin’sh, E.E., Mazeika, I.B., and Shats, V.D., Kremniiorganicheskie proizvodnye aminospirtov (Organosilicon Derivatives of Alkanolamines), Lukevics, E.Ya., Riga: Zinatne, 1987.

    Google Scholar 

  12. Frolov, Yu.L., Voronkov, M.G., Gavrilova, G.A., Chipanina, N.N., Gubanova, L.I., and Dyakov, V.M., J. Organometal. Chem., 1983, vol. 244, p. 107.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia

    M. G. Voronkov, E. A. Grebneva, O. M. Trofimova, A. I. Albanov, N. F. Chernov & N. N. Chipanina

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  1. M. G. Voronkov
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  2. E. A. Grebneva
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  3. O. M. Trofimova
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  4. A. I. Albanov
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  5. N. F. Chernov
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  6. N. N. Chipanina
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Original Russian Text © M.G. Voronkov, E.A. Grebneva, O.M. Trofimova, A.I. Albanov, N.F. Chernov, N.N. Chipanina, 2006, published in Zhurnal Obshchei Khimii, 2006, Vol. 76, No. 12, pp. 1938–1941.

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Voronkov, M.G., Grebneva, E.A., Trofimova, O.M. et al. Reaction of tetrafluorosilane with tris(2-hydroxyethyl)amine, tris(2-trimethylsiloxyethyl)amine and bis(2-trimethylsiloxyethyl)amine and its N-methyl derivative. 1,1-difluoroquasisilatranes. Russ J Gen Chem 76, 1851–1853 (2006). https://doi.org/10.1134/S1070363206120012

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  • DOI: https://doi.org/10.1134/S1070363206120012

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