Skip to main content
SpringerLink
Log in

Nitrosoruthenium hydroxo and aqua complexes of the trans-dipyridine series: Synthesis, structures, and characterization

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

A procedure for the synthesis of trans-Ru(NO)(Py)2Cl2(OH) (I) from K2[Ru(NO)Cl5] was proposed. Treatment of hydroxo complex I with HCl or H2SO4 at room temperature gave the corresponding salts trans-[Ru(NO)(Py)2Cl2(H2O)]Cl · 2H2O (II) and trans-[Ru(NO)(Py)2Cl2(H2O)]HSO4 (III). All the complexes obtained were characterized by 1H and 13C NMR and IR spectroscopy and elemental analysis; their structures were determined by X-ray diffraction. The structures are stabilized by π-stacking between the pyridine ligands of adjacent complex species.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Woike, T., Kirchner, W., Shetter, G., et al., Opt. Commun., 1994, vol. 106, p. 6.

    Article  CAS  Google Scholar 

  2. Coppens, P., Novozhilova, I., and Kovalevsky, A., Chem. Rev., 2002, vol. 102, p. 861.

    Article  CAS  Google Scholar 

  3. Schaniel, D., Woike, T., and Delley, B., Phys. Chem. Chem. Phys., 2005, vol. 7, p. 1164.

    Article  CAS  Google Scholar 

  4. Kushch, L.A., Golhen, S., Cador, O., et al., J. Cluster Sci., 2006, vol. 17, p. 303.

    Article  CAS  Google Scholar 

  5. Schaniel, D., Woike, T., Kusch, L., and Yagubskii, E., Chem. Phys., 2007, vol. 340, p. 211.

    Article  CAS  Google Scholar 

  6. Schaniel, D., Cormary, B., Malfant, I., et al., Phys. Chem. Chem. Phys., 2007, vol. 9, p. 3717.

    Article  CAS  Google Scholar 

  7. Cormary, B., Ladeira, S., Jacob, K., et al., Inorg. Chem., 2012, vol. 51, p. 7492.

    Article  CAS  Google Scholar 

  8. Charonnat, R., Ann. Chim., 1931, Ser. 10, vol. 16, p. 125.

    Google Scholar 

  9. Serli, B., Zangrando, E., Gianferrara, T., et al., Coord. Chem. Rev., 2003, no. 245, p. 73.

    Google Scholar 

  10. Nishimura, H., Matsuzawa, H., Togano, T., et al., Dalton Trans., 1990, p. 137.

    Google Scholar 

  11. Emel’yanov, V.A., Khranenko, S.P., and Belyaev, A.V., Russ. J. Inorg. Chem., 2001, vol. 46, no. 3, p. 346.

    Google Scholar 

  12. Klimova, V.A., Osnovnye mikrometody analiza organicheskikh soedinenii (Principal Methods of Micro Analysis of Organic Compounds), Moscow: Nauka, 1965.

    Google Scholar 

  13. Sheldrick, G.M., SHELX-97. Release 97-1. Programs for the Refinement of Crystal Structures, Göttingen (Germany): Univ. of Göttingen, 1997.

    Google Scholar 

  14. Mercer, E.E., Campbell, W.M., Jr., and Wallace, R.M., Inorg. Chem., 1964, vol. 3, no. 7, p. 1018.

    Article  CAS  Google Scholar 

  15. Emel’yanov, V.A., Baidina, I.A., Khranenko, S.P., et al., Zh. Strukt. Khim., 2003, vol. 44, no. 1, p. 48.

    Google Scholar 

  16. Emel’yanov, V.A., Baidina, I.A., Gromilov, S.A., et al., Zh. Strukt. Khim., 2000, vol. 41, no. 6, p. 1242.

    Google Scholar 

  17. Il’in, M.A., Emel’yanov, V.A., Belyaev, A.V., et al., Russ. J. Inorg. Chem., 2008, vol. 53, no. 7, p. 1070.

    Article  Google Scholar 

  18. Mercer, E.E., McAlister, W.A., and Durig, J.R., Inorg. Chem., 1966, vol. 5, no. 11, p. 1881.

    Article  CAS  Google Scholar 

  19. Rose, M.J. and Mascharak, P.K., Coord. Chem. Rev., 2008, no. 252, p. 2093.

    Google Scholar 

  20. Il’in, M.A., Emel’yanov, V.A., Baidina, I.A., et al., Russ. J. Inorg. Chem., 2007, vol. 52, no. 1, p. 62.

    Article  Google Scholar 

  21. Borges, S.S.S., Davanzo, C.U., Castellano, E.E., et al., Inorg. Chem., 1998, vol. 37, p. 2670.

    Article  CAS  Google Scholar 

  22. Gomes, M.G., Davanzo, C.U., Silva, S.C., et al., Dalton Trans., 1998, p. 601.

    Google Scholar 

  23. Coe, B.J., Meyer, T.J., and White, P.S., Inorg. Chem., 1995, vol. 34, p. 593.

    Article  CAS  Google Scholar 

  24. Bottomley, F. and Mukaida, M., Dalton Trans., 1982, p. 1933.

    Google Scholar 

  25. Ooyama, D. and Miura, Y., Kanazawa (Kitanaka), Y., et al., Inorg. Chim. Acta, 1995, vol. 237, p. 47.

    Article  CAS  Google Scholar 

  26. Kumar, A., Pandey, R., Gupta, R.K., et al., Polyhedron, 2012, vol. 52, p. 837.

    Article  Google Scholar 

  27. Il’in, M.A., Emel’yanov, V.A., and Baidina, I.A., J. Struct. Chem., 2010, vol. 51, no. 1, p. 99.

    Article  Google Scholar 

  28. F. Bottomley, J. Chem. Soc., Dalton Trans., 1974, p. 1600.

    Google Scholar 

  29. Bezerra, C.W.B., da Silva, S.C., Gambardella, M.T.P., et al., Inorg. Chem., 1999, vol. 38, p. 5660.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    A. N. Makhinya, M. A. Il’in, E. V. Kabin, I. A. Baidina, M. R. Gallyamov & N. I. Alferova

  2. Novosibirsk National Research State University, Novosibirsk, Russia

    A. N. Makhinya, M. A. Il’in & E. V. Kabin

Authors
  1. A. N. Makhinya
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. A. Il’in
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. V. Kabin
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. I. A. Baidina
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. M. R. Gallyamov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. N. I. Alferova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. N. Makhinya.

Additional information

Original Russian Text © A.N. Makhinya, M.A. Il’in, E.V. Kabin, I.A. Baidina, M.R. Gallyamov, N.I. Alferova, 2014, published in Koordinatsionnaya Khimiya, 2014, Vol. 40, No. 5, pp. 298–304.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Makhinya, A.N., Il’in, M.A., Kabin, E.V. et al. Nitrosoruthenium hydroxo and aqua complexes of the trans-dipyridine series: Synthesis, structures, and characterization. Russ J Coord Chem 40, 297–303 (2014). https://doi.org/10.1134/S107032841405008X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S107032841405008X

Keywords

Search

Navigation