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The first seven-electron triangular tungsten sulfide cluster

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Abstract

A new cluster complex [W3S4(Dppe)3Br3] · 3THF (Dppe = Ph2PCH2CH2PPh2), the first example of a triangular tungsten cluster with a seven-electron core, was synthesized. The molecular and crystal structures of the compound were determined by X-ray diffraction.

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Authors and Affiliations

  1. Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    P. A. Petrov, A. I. Smolentsev & S. N. Konchenko

Authors
  1. P. A. Petrov
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  2. A. I. Smolentsev
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  3. S. N. Konchenko
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Correspondence to P. A. Petrov.

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Original Russian Text © P.A. Petrov, A.I. Smolentsev, S.N. Konchenko, 2013, published in Koordinatsionnaya Khimiya, 2013, Vol. 39, No. 7, pp. 410–413.

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Petrov, P.A., Smolentsev, A.I. & Konchenko, S.N. The first seven-electron triangular tungsten sulfide cluster. Russ J Coord Chem 39, 510–513 (2013). https://doi.org/10.1134/S1070328413070099

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  • DOI: https://doi.org/10.1134/S1070328413070099

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