Abstract
Novel homo-and heterometal complexes based on 4,6-di-tert-butyl-2-nitrosophenol (HL) were synthesized, and their physicochemical properties were studied. The data of the 1H NMR, electronic spectroscopy, magnetochemical measurements, and the atomic absorption study suggest that the nitroso group of a ligand can be bidentate in polynuclear coordination compounds. The experimental data were obtained for the first time on self-assembling of both homo-and heterometal trinuclear complexes with predicted properties from the initial metal chelates of ortho-nitrosophenols.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Gowenlock, B.G. and Richter-Addo, G.B., Chem. Rev., 2004, vol. 104, p. 3315.
Lee. J., Chen, L., West, A.H., and Richter-Add, G.B. Chem. Rev., 2002, vol. 102, p. 1019.
Lyubchenko, S.N., Ionov, A.M., Shcherbakov, I.N., et al., Koord. Khim., 2006, vol. 32, no. 8, p. 563 [Russ. J. Coord. Chem. (Engl. Transl.), vol. 32, no. 8, p. 539].
Das, A.K., Rueda, A., Falvello, L.R., et al., Inorg. Chem., 1999, vol. 38, p. 4365.
Kalinnikov, V.T. and Rakitin, Yu.V., Vvedenie v magnetokhimiyu (Introduction to Magnetochemistry), Moscow: Nauka, 1980.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © A.M. Ionova, S.N. Lyubchenko, V.A. Kegan, A.Yu. Tsivadze, 2008, published in Koordinatsionnaya Khimiya, 2008, Vol. 34, No. 3, pp. 200–202.
Rights and permissions
About this article
Cite this article
Ionov, A.M., Lyubchenko, S.N., Kogan, V.A. et al. Homo-and heterometal complexes with sterically eclipsed ortho-nitrosophenol. Russ J Coord Chem 34, 195–197 (2008). https://doi.org/10.1134/S1070328408030081
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070328408030081