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Structure, shape, and orientation of an island adsorbed on a single-crystal surface in the case of lattice mismatch

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Abstract

A computer simulation is carried out to examine the structure, shape, and orientation of a monolayer adatom island as dependent on its size in the case of lattice mismatch between the island and the substrate, taking into account adatom relaxation in a constant substrate field. The island orientation with respect to the substrate lattice is shown to be influenced by the relaxation of the island structure and shape. The formation of a superstructure is revealed whose period is inversely proportional to the degree of lattice mismatch. The island is found to change its shape and orientation in the course of growth. The simulated results are compared with previous experimental findings.

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References

  1. Goryll, M., Vescan, L., and Lüth, H., Morphology and Photoluminescence of Ge Islands Grown on Si(001), Thin Solid Films, 1998, vol. 336,issues 1–2, pp. 244–247.

    Article  Google Scholar 

  2. Yang, Y.-N. and Williams, E.D., Domain-Boundary-Induced Metastable Reconstructions during Epitaxial Growth of Si/Si(111), Phys. Rev. B, 1995, vol. 51, no. 19, pp. 13 238–13 243.

    Article  Google Scholar 

  3. Yokoyama, T., Tanaka, H., Itoh, M., Yokotsuka, T., and Sumita, I., Scanning-Tunneling-Microscope Observation of 2 × 1 Structure on a Homoepitaxially Grown Si(111) Surface, Phys. Rev. B, 1994, vol. 49, no. 8, pp. 5703–5705.

    Article  Google Scholar 

  4. Jiang, Q., Chan, A., and Wang, G.-C., Dynamic Scaling of Island-Size Distribution in Submonolayer Growth of 1 × 1 Films, Phys. Rev. B, 1994, vol. 50, no. 15, pp. 11 116–11 120.

    Article  Google Scholar 

  5. Lin, X.F., Wan, K.J., and Nogami, J., Surface Reconstructions in the Ag/Si(001) System, Phys. Rev. B, 1994, vol. 49, no. 11, pp. 7385–7393.

    Article  Google Scholar 

  6. Lin, X.F., Wan, K.J., and Nogami, J., Ag on Si(001): Growth Behavior of the Annealed Surface, Phys. Rev. B, 1993, vol. 47, no. 16, pp. 10 947–10 950.

    Article  Google Scholar 

  7. Müller, B., Nedelmann, L., Fischer, B., Brune, H., and Kern, K., Initial Stages of Cu Epitaxy on Ni(100): Postnucleation and a Well-Defined Transition in Critical Island Size, Phys. Rev. B, 1996, vol. 54, no. 24, pp. 17 858–17 865.

    Article  Google Scholar 

  8. Schuster, R., Röder, H., Bromann, K., Brune, H., and Kern, K., Stress Relief via Island Formation of an Isotropically Strained Bimetallic Surface Layer: The Mesoscopic Morphology of the Ag/Pt(111) Surface Alloy, Phys. Rev. B, 1996, vol. 54, no. 19, pp. 13 476–13 479.

    Article  Google Scholar 

  9. Itoh, M., Island-Size Dependence of Reconstructed Structures on Si(111), Phys. Rev. B, 1997, vol. 56, no. 7, pp. 3583–3586.

    Article  Google Scholar 

  10. Lorenz, W.J. and Staikov, G., 2D and 3D Thin Film Formation and Growth Mechanisms in Metal Electrocrystallization—An Atomistic View by In Situ STM, Surf. Sci., 1995, vol. 335, pp. 32–43.

    Article  Google Scholar 

  11. Chen, K.M., Jesson, D.E., Pennycook, S.J., Thundat, T., and Warmack, R.J., Critical Nuclei Shapes in the Stress-Driven 2D-to-3D Transition, Phys. Rev. B, 1997, vol. 56, no. 4, pp. R1700–R1703.

    Article  Google Scholar 

  12. Zeldovich, Ya.B., On Phase Nucleation: Cavitation, Zh. Eksp. Teor. Fiz., 1942, issue 12, p. 525.

  13. Zhdanov, G.S., Growth Kinetics of Condensed-Phase Islands, Fiz. Tverd. Tela (Leningrad), 1984, vol. 26,issue 3, pp. 2937–2942.

    Google Scholar 

  14. Osipov, A.V., Non-steady-State Diffusion Growth of Two-Dimensional Nuclei in Thin Films, Metallofizika, 1988, vol. 10, no. 6, pp. 97–99.

    MathSciNet  Google Scholar 

  15. Osipov, A.V., Field Theory of Nucleus Growth in Thin Films, Metallofizika, 1990, vol. 12, no. 1, pp. 62–66.

    MathSciNet  Google Scholar 

  16. Osipov, A.V., Nucleus Size Distribution and Supersaturation Kinetics of Thin Films, Poverkhnost Fiz. Khim. Mekh., 1989, no. 11, pp. 116–118.

  17. Borman, V.D., Gusev, E.P., Devyatko, Yu.N., et al., Early Kinetics of Oxide Island Growth on a Metal Surface, Poverkhnost Fiz. Khim. Mekh., 1990, no. 8, pp. 22–30.

  18. Devyatko, Yu.N., Rogozhkin, S.V., et al., Surface Phase Nucleation as the Relaxation of the Order-Parameter Field, Zh. Eksp. Teor. Fiz., 1993, vol. 103, pp. 285–300.

    Google Scholar 

  19. Devyatko, Yu.N., Rogozhkin, S.V., and Fedotov, B.A., Instability of the Axisymmetric Shape of Two-Dimensional Nuclei as a Function of the Relaxation of the Order-Parameter Field, Phys. Rev. B, 1994, vol. 50, no. 9, pp. 5857–5864.

    Article  Google Scholar 

  20. Devyatko, Yu.N., Rogozhkin, S.V., and Fedotov, B.A., Theory of the Kinetics of Nucleation in Adsorbing Layer: The Approach Based on the Relaxation of Order Parameter Field, Surf. Sci., 1996, vol. 345,issues 1–2, pp. 138–154.

    Article  Google Scholar 

  21. Devyatko, Yu.N., Musin, R.N., and Rogozhkin, S.V., Order-Parameter Expansion of Free Energy and the Metastable-State Relaxation of an Adatom System, Preprint of Moscow Engineering Physics Institute, Moscow, 1990, no. 046-90.

  22. Borman, V.D., Gusev, E.P., Lebedinskii, Yu.Yu., and Troyan, V.I., Detection of a Phase Transition in an Oxygen-Nickel System: Oxygen Penetration through the Nickel Surface Layer, Poverkhnost Fiz. Khim. Mekh., 1988, no. 11, p. 138–141.

  23. Ying, S.C., Structure and Dynamics of a Submonolayer Film Adsorbed on Solid Surfaces, Phys. Rev. B, 1971, vol. 3, no. 12, pp. 4160–4171.

    Article  Google Scholar 

  24. Burkov, S.E., Orientational Phase Transitions of the Second Order in Monolayers, Pis’ma Zh. Eksp. Teor. Fiz., 1979, vol. 29,issue 8, pp. 457–460.

    Google Scholar 

  25. Uimin, G.V. and Shur, L.N., Orientational Phase Transitions in an Adsorbed Monolayer, Pis’ma Zh. Eksp. Teor. Fiz., 1978, vol. 28,issue 1, pp. 20–23.

    Google Scholar 

  26. Bulaevskii, L.N. and Khomskii, D.L., Lattice-Matching Effects and Collective Excitations in Systems with Charge-Density Waves, Zh. Eksp. Teor. Fiz., 1978, vol. 74,issue 5, pp. 1863–1870.

    Google Scholar 

  27. Pokrovskii, V.L. and Talapov, A.L., Theory of Two-Dimensional Mismatched Crystals, pp. 269–294.

  28. Blackman, J.A., Evans, B.L., and Maaroof, A.I., Analysis of Island-Size Distributions in Ultrathin Metallic Films, Phys. Rev. B, 1994, vol. 49, no. 19, pp. 13 863–13 871.

    Article  Google Scholar 

  29. Lamelas, F.J., Tang, M.-T., Evans-Lutterodt, K., Fuoss, P.H., and Brown, W.L., Epitaxial Orientations of Aluminum on Silicon (001), Phys. Rev. B, 1992, vol. 46, no. 23, pp. 15 570–15 573.

    Article  Google Scholar 

  30. Nogami, J., Baski, A.A., and Quate, C.F., Aluminum on the Si(100) Surface: Growth of the First Monolayer, Phys. Rev. B, 1991, vol. 44, no. 3, pp. 1415–1418.

    Article  Google Scholar 

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Original Russian Text © Yu.N. Devyatko, S.V. Rogozhkin, A.V. Fadeev, 2006, published in Mikroelektronika, 2006, Vol. 35, No. 5, pp. 362–373.

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Devyatko, Y.N., Rogozhkin, S.V. & Fadeev, A.V. Structure, shape, and orientation of an island adsorbed on a single-crystal surface in the case of lattice mismatch. Russ Microelectron 35, 310–321 (2006). https://doi.org/10.1134/S1063739706050064

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  • DOI: https://doi.org/10.1134/S1063739706050064

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