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Molecular structure and spectral characteristics of bis(S-methyl-N-(2-pyridyl)methylendithiocarbazato)nickel(II), (Ni(NNS)2)

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Abstract

A nickel(II) complex of the pyridine-2-aldehyde Schiff base of S-methyldithiocarbazate (HNNS) has been synthesized and characterized by means of elemental analysis, IR and UV-vis spectra. The crystal structure of the complex has been determined by single-crystal X-ray diffraction. The complex crystallizes in the monoclinic, space P21/c, with a = 14.092(2), b = 16.886(2), c = 8.857(2)Å; β = 105.78(3) °, V = 2028.2(6) Å3, and Z = 4. The nickel atom is octahedrally coordinated by two uninegatively charged tridentate Schiff base in a mer-configuration via the pyridine nitrogen atom, azomethine nitrogen atom, and mecaptide sulfur atom.

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Zhongshan University, Guangzhou, 510275, China

    Cheng-Yong Su, Xiao-Ping Yang, Li-Ge Wang & Bei-Sheng Kang

  2. Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Academia Sinica, Lanzhou, 730000

    Ze-Fu Zhang

  3. Department of Pharmacy, School of Life-Science, Zhongshan University, Guangzhou, 510275, China

    Qin Zhou

Authors
  1. Cheng-Yong Su
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  2. Ze-Fu Zhang
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  3. Qin Zhou
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  4. Xiao-Ping Yang
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  5. Li-Ge Wang
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  6. Bei-Sheng Kang
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Su, CY., Zhang, ZF., Zhou, Q. et al. Molecular structure and spectral characteristics of bis(S-methyl-N-(2-pyridyl)methylendithiocarbazato)nickel(II), (Ni(NNS)2). Journal of Chemical Crystallography 28, 871–874 (1998). https://doi.org/10.1023/A:1022842301321

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  • DOI: https://doi.org/10.1023/A:1022842301321

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