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Partial Alkane Oxidation Kinetics at High Pressures: Methane Oxidation in Stainless Steel and Quartz Reactors

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Abstract

Homogeneous partial methane oxidation in quartz and stainless steel flow reactors was studied systematically in the pressure range 15–80 atm. Product yields were determined as functions of basic process parameters (pressure, temperature, residence time of the mixture in the reactor, initial oxygen concentration). The process was found to depend strongly on the material of the reactor surface.

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Authors and Affiliations

  1. Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow, 119991, Russia

    V. S. Arutyunov

  2. Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    V. M. Rudakov, V. I. Savchenko, E. V. Sheverdenkin, O. G. Sheverdenkina & A. Yu. Zheltyakov

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  1. V. S. Arutyunov
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  2. V. M. Rudakov
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  3. V. I. Savchenko
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  4. E. V. Sheverdenkin
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  5. O. G. Sheverdenkina
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  6. A. Yu. Zheltyakov
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Arutyunov, V.S., Rudakov, V.M., Savchenko, V.I. et al. Partial Alkane Oxidation Kinetics at High Pressures: Methane Oxidation in Stainless Steel and Quartz Reactors. Theoretical Foundations of Chemical Engineering 36, 472–476 (2002). https://doi.org/10.1023/A:1020677829300

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  • DOI: https://doi.org/10.1023/A:1020677829300

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