Abstract
This paper is a survey of the main facts and concepts concerning the effect of additives on the structure and physicochemical and catalytic properties of oxide catalysts in selective oxidation reactions. The phenomena occurring in monophasic and supported mixed oxides containing the additives, including modification of structure, solid state reactions, segregation, defect formation, and spill-over of the reactants, are briefly described. The effect of additives on acid--base and redox properties, and on their bearing on catalytic performance are discussed, with particular emphasis on alkali metal additives. The perspectives of further studies on the problem are proposed.
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References
B. Grzybowska-Świerkosz, Topics Catal. 11/12 (2000) 23, and references therein.
V.D. Sokolovskii, Catal. Rev. Sci. Eng. 32 (1990) 1.
P. Moriceau, A. Lebouteiller, E. Bordes and P. Courtine, Phys. Chem. Chem. Phys. 1 (1999) 5735.
K. Brückman, J. Haber and T. Wiltowski, J. Catal. 106 (1987) 188.
A. Satsuma, A. Furuta, T. Hattori and Y. Murakami, J. Phys. Chem. 95 (1991) 3248.
A. Brückner and M. Baerns, Appl. Catal. A: General 157 (1997) 311.
R.K. Grasselli, Catal. Today 49 (1999) 141, and references therein.
A.W. Sleight and W. Jeitschko, Mater. Res. Bull. 9 (1974) 951.
J.F. Brazdil, M. Mehicic, L.C. Glaeser, M.A.S. Hazle and R.K. Grasselli, ACS Symp. Ser. 288 (1985) 26.
J. Słoczyński and B. Śliwa, Z. Anorg. Allg. Chem. 438 (1978) 295.
P. Forzatti, F. Trifirò and P.L. Villa, J. Catal. 55 (1978) 52; P. Forzatti and P. Tittarelli, J. Solid State Chem. 33 (1980) 421.
M.C. Kung, and H.H. Kung, J. Catal. 134 (1992) 668.
M.T. Sananes-Schulz, A. Tuel, G.J. Hutchings and J.C. Volta, J. Catal. 166 (1997) 388; S. Mota, J.C. Volta, G. Vorbeck and J.A. Dalmon, J. Catal. 193 (2000) 319.
K. Aykan, A.W. Sleight and D.B. Rogers, J. Catal. 29 (1973) 185.
R.W. Sleight and W.Y. Linn, Ann. N.Y. Acad. Sci. 272 (1978) 22.
L.Ya. Margolis and A.A. Firsova, Int. Rev. Phys. Chem. 8 (1989) 1.
V.A. Zazhigalov, J. Haber, J. Stoch, I.V. Bacherikova, G.A. Komashko and A.I. Pyatnitskaya, Appl. Catal. A: General 134 (1996) 225.
G. Deo, I.E. Wachs and J. Haber, Crit. Rev. Surf. Chem. 4 (1994) 141, and references therein.
G.C. Bond and S.F. Tahir, Appl. Catal. 71 (1991) 1.
B. Grzybowska-Świerkosz, Appl. Catal. A: General 157 (1997) 263.
B. Grzybowska, J. Słoczyński, R. Grabowski, K. Wcisto, A. Kozłowska, J. Stoch and J. Zieliński, J. Catal. 178 (1998) 687.
D. Courcot, B. Grzybowska, Y. Barbaux, M. Rigole, A. Ponchel and M. Guelton, J. Chem. Soc. Faraday Trans. 92 (1996) 1609.
P. Concepción, S. Kuba, H. Knözinger, B. Solsona and J.M. López Nieto, Stud. Surf. Sci. Catal. 130 (2000) 767.
G. Deo and I.E. Wachs, J. Catal. 146 (1994) 335.
G. Ramis and G. Busca, Catal. Lett. 18 (1993) 299.
V. Ermini, E. Finocchio, S. Sechi, G. Busca and S. Rossini, Appl. Catal. A: General 198 (2000) 67.
B. Grzybowska, K. Samson and I. Gressel, unpublished results.
B. Grzybowska, P. Mekšs, R. Grabowski, K. Wcisło, Y. Barbaux and L. Gengembre, Stud. Surf. Sci. Catal. 82 (1994) 151.
R. Grabowski, B. Grzybowska, K. Samson, J. Stoczyñski, J. Stoch and K. Wciso, Appl. Catal. A: General 125 (1995) 129.
D.A. Bulushev, L. Kiwi-Minsker, V.I. Zaikovskii, O.B. Lapina, A.A. Ivanov, S.I. Reshetnikov and A. Renken, Appl. Catal. A: General 202 (2000) 243.
D. Courcot, A. Ponchel, B. Grzybowska, Y. Barbaux, M. Rigole, M. Guelton and J.P. Bonnelle, Catal. Today 33 (1997) 109.
C. Martin, M.C. Mendizabal and V. Rives, J. Mater. Sci. 27 (1992) 5575.
K. Chen, S. Xie, A. Bell and E. Iglesia, J. Catal. 195 (2000) 244.
I.E. Wachs and B.M. Weckhuysen, Appl. Catal. A: General 157 (1997) 67; M.A. Vuurman, D.J. Stufkens, A. Oskam, G. Deo and I.E. Wachs, J. Chem. Soc. Faraday Trans. 92 (1996) 3259.
M.D. Amiridis, R.V. Duevel and I.E. Wachs, Appl. Catal. B: Environmental 20 (1999) 111.
J. Zhu and S.L.T. Andersson, J. Chem. Soc. Faraday Trans. 1, 85 (1989) 3629.
G. Centi, G. Golinelli and G. Busca, J. Phys. Chem. 94 (1990) 6813.
B. Grzybowska, I. Gressel, K. Samson, K. Wcisło, J. Stoch, M. Mikołajczyk and F. Dautzenberg, Polish J. Chem. 75 (2001) 1513.
J.K. Nørskov and P. Stolze, Surf. Sci. 189/190 (1987) 91.
R. Gryboś and M. Witko, to be published.
J. Zhu, B. Rebenstorf and S.L.T. Andersson, J. Chem. Soc. Faraday Trans. 85 (1989) 3645.
R.X. Valenzuela, E.A. Mamedov and V.C. Corberan, React. Kin. Catal. Lett. 55 (1995) 213.
J. Słoczyński, Appl. Catal. A: General 146 (1996) 401.
J.M. López Nieto, R. Coenraads, A. Dejoz and M.I. Vazquez, Stud. Surf. Sci. Catal. 110 (1997) 443.
M.G. Nobbenhuis, P. Hug, T. Mallat and A. Baiker, Appl. Catal. A: General 108 (1994) 241.
Y. Takita, K. Tanaka, S. Ichimaru, Y. Mizihara, Y. Abe and T. Ishihara, Appl. Catal. A: General 103 (1993) 281.
I.E. Wachs, J.M. Jehng, G. Deo, B.M. Weckhuysen, V.V. Guliants, J.B. Benziger and S. Sundaresan, J. Catal. 170 (1997) 75.
M. Ai, Bull. Chem. Soc. Japan 50 (1977) 355, and references therein.
A. Haras, M. Witko and B. Grzybowska, to be published.
L. Lietti and P. Forzatti, Appl. Catal. B: Environmental 3 (1993) 13.
G.K. Boreskov, A.A. Ivanov, O.M. Ilinich and V.G. Ponomareva, React. Kin. Catal. Lett. 3 (1975) 1.
A. Galli, J.M. López Nieto, A. Dejoz and M.I. Vazquez, Catal. Lett. 34 (1995) 51.
T. Blasco and J.M. López Nieto, Appl. Catal. A: General 157 (1997) 117.
A.A. Lemonidou, L. Nalbandian and I.A. Vasalos, Catal. Today 61 (2000) 333.
R.M. Martin-Aranda, M.F. Portela, L.M. Madeira, F. Freire and M. Oliveira, Appl. Catal. A: General 127 (1995) 201.
R. Grabowski, B. Grzybowska, A. Kozłowska, J. Słoczyński and K. Wcisło, Topics Catal. 3 (1996) 277.
C. Martin, V. Rives and A.R. Gonzαlez-Elipe, J. Catal. 114 (1988) 473.
A.J. Van Hengstum, J. Pranger, J.G. van Ommen and P.J. Gellings, Appl. Catal. 11 (1984) 317.
A. Satsuma, F. Okada, A. Hattori, A. Miyamoto, T. Hattori and Y. Murakami, Appl. Catal. 72 (1991) 295.
A. Klisińska, K. Samson and B. Grzybowska, unpublished results.
H.H. Kung and M.C. Kung,Appl. Catal. A: General 157 (1997) 105.
W.D. Harding, H.H. Kung, V.L. Kozhevnikov and K.R. Poeppelmeier, J. Catal. 144 (1993) 597.
K. Samson, I. Gressel and B. Grzybowska, unpublished results.
A. Baiker, M. Glinski, J. Kijenski, V.K. Sharma and A. Wokaun, J. Phys. Chem. 90 (1986) 4217.
E.V. Kondratenko, D. Wolf and M. Baerns, Catal. Lett. 58 (1999) 217.
A. Brückner, G.U. Wolf, M. Meisel, R. Stößer, H. Mehner, F. Majunke and M. Baerns, J. Catal. 154 (1995) 11.
A.P.E. York, A. Brückner, G.U. Wolf, P.M. Wilde and M. Meisel, Chem. Commun. (1996) 239.
M.P. Kiskinowa, Stud. Surf. Sci. Catal. 70 (1992) 227.
B. Grzybowska, J. Słoczyński, R. Grabowski, K. Samson, I. Gressel, K. Wcisło, L. Gengembre and Y. Barbaux, Appl. Catal. A: General 230 (2002) 1.
T.V. Andrushkevich, Catal. Rev. Sci. Eng. 35 (1993) 213.
J. Tichý, Appl. Catal. A: General 157 (1997) 363.
P. Forzatti, E. Tronconi, A.S. Elmi and G. Busca, Appl. Catal. A: General 157 (1997) 387.
T. Inoue, A. Asakuva and Y. Iwasawa, J. Catal. 171 (1997) 184.
B. Grzybowska, A. Klisińska and K. Samson, unpublished results.
G.C. Bond and D.T. Thompson, Catal. Rev. Sci. Eng. 41 (1999) 319.
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Grzybowska-Świerkosz, B. Effect of Additives on the Physicochemical and Catalytic Properties of Oxide Catalysts in Selective Oxidation Reactions. Topics in Catalysis 21, 35–46 (2002). https://doi.org/10.1023/A:1020547830167
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DOI: https://doi.org/10.1023/A:1020547830167