Abstract
The NiK-absorption spectra of Ni(dpm)2 and its adducts in crystal and solution have been studied. X-ray spectra were recorded on a synchrotron radiation station of the Institute of Nuclear Physics, Siberian Branch, Russian Academy of Sciences. It is shown that the fundamental absorption maximum in the compounds is of Rydberg character. The fine structure of the fundamental maximum was used for structure elucidation of the nearest environment of the metal atom of the complex in solutions and adducts. Participation of the highest unoccupied AO of the metal in chemical bonding in the compounds is discussed.
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REFERENCES
Yu. A. Zolotov, Extraction of Intracomplex Compounds [in Russian], Nauka, Moscow (1968).
R. L. Barinskii and V. I. Nefedov, X-Ray Spectral Determination of Atomic Charge in Molecules [in Russian], Nauka, Moscow (1966).
L. N. Mazalov, V. D. Yumatov, V. V. Murakhtanov, et al., X-Ray Spectra of Molecules [in Russian], Nauka, Novosibirsk (1977).
Z. V. Vedrinskii and I. I. Geguzin, X-Ray Absorption Spectra of Solids [in Russian], Énergoatomizdat, Moscow (1991).
Yu. F. Migal and V. S. Kovalev, Zh. Strukt. Khim., 42, No. 3, 433-438 (2001).
A. V. Kondratenko, L. N. Mazalov, and I. A. Topol, Highly Excited States of Molecules [in Russian], Nauka, Novosibirsk (1982).
L. N. Mazalov and É. E. Weinstein, Zh. Strukt. Khim., 7, No. 3, 475-477 (1966).
L. N. Mazalov, F. H. Gelmukhanov, P. I. Vadash, and A. P. Sadovskii, Izv. Sib. Otd. Akad. Nauk SSSR, Ser. Khim., 4, No. 9, 3-9 (1972).
G. V. Romanenko, N. V. Podberezskaya, L. N. Myachina, and V. V. Bakakin, Zh. Strukt. Khim., 30, No. 1, 130 (1989).
I. P. Noskova and N. N. Kazanova, ibid., 20, No. 4, 718-721 (1979).
N. N. Kazanova and B. K. Novosadov, Koordinats. Khim., 1, No. 2, 209-213 (1975).
I. B. Lvov and Yu. V. Ivanov, Abstracts of Papers from the 16th International Seminar School on Electronic and X-Ray Spectroscopy “X-Ray and Electronic Spectra of Chemical Compounds,” Voronezh (1996), p. 33.
I. V. Lvov and Yu. V. Ivanov, Poverkhnost, No. 8, 5-10 (1997).
V. I. Vovna, I. V. Lvov, and Yu. V. Ivanov, ibid., No. 8, 31-39 (1997).
L. S. Lussier, C. Sandorfy, A. Gansot, and E. Penigault, J. Phys. Chem., 88, 5491-5503 (1984).
V. I. Vovna, M. V. Kazachek, S. N. Slabzhennikov, and O. M. Ustinov, Zh. Fiz. Khim., 74, No. 6, 1055-1059 (2000).
S. V. Volkov and V. A. Zasukha, Quantum Chemistry of Condensed Coordinated Systems [in Russian], Naukova Dumka, Kiev (1985).
F. A. Cotton and C. J. Ballhausen, J. Chem. Phys., 25, No. 4, 617-619 (1956).
F. A. Cotton and H. P. Hanson, ibid., 25, No. 4, 619-623 (1956).
É. E. Weinstein, X-Ray Spectra of Atoms in Chemical Compounds and Alloys [in Russian], USSR Academy of Sciences, Moscow (1950).
R. L. Barinskii, A. E. Shvelashvili, and B. A. Malyukov, Zh. Strukt. Khim., 5, No. 3, 497-500 (1964).
R. L. Barinskii, I. M. Kulikova, and N. P. Lipatova, ibid., 14, No. 2, 372 (1973).
I. M. Kulikova, Abstract of Physical and Mathematical Sciences Candidate's Dissertation, Rostov-on-Don (1973).
I. A. Baidina, S. A. Gromilov, and G. I. Zharkova, Zh. Strukt. Khim., 42, No. 4, 776-778 (2001).
K. I. Narbut, R. L. Barinskii, and É. E. Weinstein, Dokl. Akad. Nauk SSSR, 82, No. 4, 567-570 (1952).
É. E. Weinstein and Yu. F. Kopelev, ibid., 131, No. 5, 1117 (1961).
K. I. Narbut and L. N. Izraileva, Izv. Akad. Nauk SSSR, Ser. Fiz., 27, No. 3, 351 (1963).
HyperChem TM Release 5.02 for Windows 95/MT Molecular Modeling System, Hypercube Inc. (1997).
A. D. Becke, Phys. Rev., A36, 3-98 (1988).
A. D. Becke, J. Chem. Phys., 98, 1372 (1993).
P. J. Hay and W. R. Wadt, ibid., 82, 294 (1985).
Jaguar 3.5, Schrödinger Inc., Portland, UK (1998).
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Mazalov, L.N., Igumenov, I.K., Bausk, N.V. et al. Structural Study of Ni(dpm)2 in Solution by X-Ray Absorption Spectroscopy. Journal of Structural Chemistry 43, 257–265 (2002). https://doi.org/10.1023/A:1019696323457
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DOI: https://doi.org/10.1023/A:1019696323457