Abstract
Ca3MgNi14, Nd1.5Ca1.5MgNi14, Gd1.5Ca1.5MgNi14 and Er1.5Ca1.5MgNi14 alloys were prepared by high frequency induction melting and sintering. Characterization and analysis were performed by X-ray diffraction/Rietveld full-spectrum fitting, gaseous P-C-T hydrogen storage test and electrochemical properties tests. It can be found that all alloys consist of Gd2Co7-type 3R phase and Ce2Ni7-type 2H phase. Although the hydrogen storage capacities of Nd1.5Ca1.5MgNi14, Gd1.5Ca1.5MgNi14 and Er1.5Ca1.5MgNi14 decrease to some extent compared to that of Ca3MgNi14, their equilibrium pressures for absorption and desorption increase markedly. Moreover, R1.5Ca1.5MgNi14 alloys have better cycling stabilities and high-rate discharge(HRD) properties as compared to Ca3MgNi14. The hydrogen diffusion in alloy electrodes is the main factor to influence the HRD performance.
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Xiao L., Chu W., Sun W. J., Xue Y., Jiang C. F., Chem. Res. Chinese Universities, 2017, 33(3), 422
Zhou X. F., Zhou Y. B., Tang C. M., Chem. J. Chinese Universities, 2019, 40(3), 473
Erika T., Sebastian C., Fernando Z., Verónica D., Int. J. Hydrogen Energy, 2016, 41(43), 19684
Liu J., Han S., Li Y., Zhang L., Zhao Y., Yang S., Liu B., Int. J. Hydrogen Energy, 2016, 41(44), 20261
Xue C., Zhang L., Fan Y., Fan G., Liu B., Han S., Int. J. Hydrogen Energy, 2017, 42(9), 6051
Liu J., Han S., Han D., Li Y., Yang S., Zhang L., Zhao Y., J. Power Sources, 2015, 287, 237
Kadir K., Sakai T., Uehara I., J. Alloys Compd., 1999, 287, 264
Kadir K., Sakai T., Uehara I., J. Alloys Compd., 2000, 302(1/2), 112
Chen J., Takeshita H. T., Tanaka H., Kuriyama N., Sakai T., Uehara I., Haruta M., J. Alloys Compd., 2000, 302(1/2), 304
Xin G., Yuan H., Yang K., Jiang L., Liu X., Wang S., Int. J. Hydro-gen Energy, 2016, 41(46), 21261
Si T. Z., Zhang Q. A., Pang G., Liu D. M., Liu N., Int. J. Hydrogen Energy, 2009, 34(3), 1483
Zhang Q. A., Pang G., Si T. Z., Liu D. M., Acta Mater., 2009, 57(6), 2002
Zhang Q. A., Zhao G. P., Si T. Z., Int. J. Hydrogen Energy, 2006, 31(9), 1182
Zhang P., Liu Y., Tang R., Zhu J., Wei X., Liu S., Yu G., Electrochim. Acta, 2006, 51(28), 6400
Xin G., Yuan H., Yang K., Jiang L., Liu X., Wang S., RSC Adv., 2016, 6(26), 21742
Belgacem Y. B., Khaldi C., Lamloumi J., Takenouti H., J. Solid State Electrochem., 2016, 20(7), 1949
Chebab S., Abdellaoui M., Latroche M., Paul-Boncour V., J. Renew. Sustain. Energy, 2016, 5(3), 12
Chen J., Kuriyama N., Takeshita H. T., Tanaka H., Sakai T., Haruta M., Electrochem. Solid-state Lett., 2000, 3(6), 249
Zang J. H., Zhang Q. A., Sun D. L., J. Alloys Compd., 2019, 771, 711
Zang J. H., Zhang Q. A., Sun D. L., J. Alloys Compd., 2019, 794, 45
Lv W., Yuan J., Zhang B., Wu Y., J. Alloys Compd., 2018, 730, 360
Si T. Z., Zhang Q. A., Liu N., Int. J. Hydrogen Energy, 2008, 33(6), 1729
Liu Y., Cao Y., Huang L., Gao M., Pan H., J. Alloys Compd., 2011, 509(3), 675
Izumi F., Mater. Sci. Forum, 2000, 321, 198
Zhang Q., Fang M., Si T., Fang F., Sun D., Ouyang L., Min Z., J. Phys. Chem. C, 2010, 114(26), 11686
Buschow K. H. J., Van Der Goot A. S., J. Less Common Metals, 1970, 22(4), 419
Sakaki K., Terashita N., Tsunokake S., Nakamura Y., Akiba E., J. Phys. Chem. C, 2012, 116(36), 19156
Dymek M., Nowak M., Jurczyk M., Bala H., J. Alloys Compd., 2018, 749, 534
Zhang L., Han S., Li Y., Liu J., Zhang J., Wang J., Yang S., Int. J. Hydrogen Energy, 2013, 38(25), 10431
Zhang F., Luo Y., Deng A., Tang Z., Kang L., Chen J., Electrochim. Acta, 2006, 52(1), 24
Volodin A. A., Wan C., Denys R. V., Tsirlina G. A., Tarasov B. P., Fichtner M., Ulmer U., Yu Y., Nwakwuo C. C., Yartys V. A., Int. J. Hydrogen Energy, 2016, 41(23), 9954
Li Y., Wang C., Dong Z., Wang J., Yang S., Ke D., Han S., Int. J. Hydrogen Energy, 2017, 42(30), 19148
Zhang Y. H., Cai Y., Zhao C., Zhai T. T., Zhang G. F., Zhao D. L., Int. J. Hydrogen Energy, 2012, 37(19), 14590
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Supported by the National Natural Science Foundation of China(Nos.51571001, 51571063).
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Zang, J., Zhang, Q. & Sun, D. Crystal Structures and Electrochemical Properties of R1.5Ca1.5MgNi14(R=Nd, Gd and Er) Hydrogen Storage Alloys. Chem. Res. Chin. Univ. 35, 1040–1045 (2019). https://doi.org/10.1007/s40242-019-9173-7
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DOI: https://doi.org/10.1007/s40242-019-9173-7