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Porous Organic Frameworks-derived Porous Carbons with Outstanding Gas Adsorption Performance

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Chemical Research in Chinese Universities Aims and scope

Abstract

A series of porous carbon materials was synthesized via high temperature pyrolysis from well-defined and thermally stable precursors, namely porous organic frameworks(POFs), in inert atmosphere. The porous carbon materials showed enhanced gas adsorption capacities together with increased heat of adsorption and stronger affinity between the frameworks and the gases as compared to the precursor materials. To exemplify, sample C-POF-TBBP-1000 with a high BET surface area of 1290 m2/g can adsorb 2.8 mmol/g CH4(273 K, 101.325 kPa), 5.4 mmol/g CO2(273 K, 101.325 kPa) and 2.2% H2(mass fraction, 77 K, 101.325 kPa), thereby surpassing most other porous adsorbent materials reported till date. The study highlights the potential of porous carbons derived from novel porous organic framework structures for gas adsorption applications.

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References

  1. Rochelle G. T., Science 2009, 325(5948), 1652

    Article  CAS  PubMed  Google Scholar 

  2. Das S., Heasman P., Ben T., Qiu S. L., Chem. Rev. 2017, 117(3), 1515

    Article  CAS  PubMed  Google Scholar 

  3. Côté. P., Benin A. I., Ockwig N. W., O’Keeffe M., Matzger A. J., Yaghi O. M., Science 2005, 310(5751), 1166

    Article  CAS  Google Scholar 

  4. Liu Y. Z., Ma Y. H., Zhao Y. B, Sun X. X., Gándara F., Furakawa H., Liu Z., Zhu C. H., Suenaga K., Oleynikov P., Alshammari A. S., Zhang X., Terasaki O., Yaghi O. M., Science 2016, 351(6271), 365

    Article  CAS  Google Scholar 

  5. Ding S. Y., Wang W., Chem. Soc. Rev. 2013, 42(2), 548

    Article  CAS  PubMed  Google Scholar 

  6. Pei C. Y., Ben T., Qiu S. L., Materials Horizons 2015, 2(1), 11

    Article  CAS  Google Scholar 

  7. Ben T., Ren H., Ma S. Q., Cao D. P., Lan J. H., Jing X. F., Wang W. C., Xu. J., Deng. F., Simmons M. J., Qiu S. L., Zhu G. S., Angew. Chem. Int. Ed. 2009, 48(50), 9457

    Article  CAS  Google Scholar 

  8. Ben T., Qiu S., Cryst. Eng. Comm. 2013, 15(1), 17

    Article  CAS  Google Scholar 

  9. Xu S. J., Luo Y. L., Tan B., Macromol. Rapid Commun. 2013, 34(6), 471

    Article  CAS  PubMed  Google Scholar 

  10. Jiang J. X., Trewin A., Adams D. J., Cooper A. I., Chem. Sci. 2011, 2(9), 1777

    Article  CAS  Google Scholar 

  11. Ben T., Li Y. Q., Zhu L. K., Zhang D. L., Cao D. P., Xiang Z. H., Yao X. D., Qiu S. L., Energy. Environ. Sci. 2012, 5(8), 8370

    Article  CAS  Google Scholar 

  12. Fu J. R., Saikat D., Xing G. L., Ben T., Valtchev V., Qiu S. L., J. Am. Chem. Soc., 2016, 138(24), 7673

    Article  CAS  PubMed  Google Scholar 

  13. Li H., Pan Q. Y., Ma Y. C., Guan X. Y., Xue M., Fang Q. R., Valthev V., Qiu S. L., J. Am. Chem. Soc., 2016, 138(44), 14783

    Article  CAS  PubMed  Google Scholar 

  14. Zhu Y. W., Murali S., Stoller M. D., Ganesh K. J., Cai W. W., Ferreira P. J., Pirkle A., Wallance R. M., Cychosz K. A., Thommes M., Su D., Stach E. A., Ruoff R. S., Science 2011, 332(6037), 1537

    Article  CAS  Google Scholar 

  15. Li Y. Q., Roy S., Ben T., Xu S. X., Qiu S. L., Phys. Chem. Chem. Phys. 2014, 16(25), 12909

    Article  CAS  PubMed  Google Scholar 

  16. Dong Y., Das S., Zhu L. K., Ben T., Qiu S. L., J. Mater. Chem. A, 2016, 4(48), 18822

    Article  CAS  Google Scholar 

  17. Lu W. G., Yuan D. Q., Sculley J. L., Zhao D., Krishna R., Zhou H. C., J. Am. Chem. Soc., 2011, 133(45), 18126

    Article  CAS  PubMed  Google Scholar 

  18. Lu W. G., Sculley J. P., Yuan D. Q., Krishna R., Wei Z. W., Zhou H. C., Angew. Chem. 2012, 51(30), 7480

    Article  CAS  Google Scholar 

  19. Li Y. Q., Ben T., Zhang B. Y., Fu Y., Qiu S. L., Sci. Rep. 2013, 3, 2420

    Article  PubMed  PubMed Central  Google Scholar 

  20. Lee J. M., Briggs M. E., Hasell T., Cooper A. I., Adv. Mater. 2016, 28(44), 9804

    Article  CAS  PubMed  Google Scholar 

  21. Ren H., Ben T., Sun F. X., Guo M. Y., Jing X. F., Ma H. P., Cai K., Qiu S. L., J. Mater. Chem., 2011, 21(28), 10348

    Article  CAS  Google Scholar 

  22. Xu Y. H., Jiang D. L., Chem. Commun. 2014, 50(21), 2781

    Article  CAS  Google Scholar 

  23. Yan T. T., Xing G. L., Ben T., Qiu S. L., Chem. J. Chinese Universi-ties, 2018, 39(5), 1072

    CAS  Google Scholar 

  24. Wei D. C., Liu Y. Q., Wang Y., Zhang H. L., Huang L. P., Yu G., Nano Lett. 2009, 9(5), 1752

    Article  CAS  PubMed  Google Scholar 

  25. Cuesta A., Dhamelincourt P., Laureyns L., Alonso M. A., Tascon J. M. D., J. Mater. Chem., 1998, 8(12), 2875

    Article  CAS  Google Scholar 

  26. Ferrari A. C., Basko D. M., Nat. Nanotechnol. 2013, 8(4), 235

    Article  CAS  PubMed  Google Scholar 

  27. Zhao W. X., Han S., Zhuang X. D., Zhang F., Mai Y. Y., Feng X. L., J. Mater. Chem. A, 2015, 3(46), 23352

    Article  CAS  Google Scholar 

  28. Wang J., Krishna R., Yang J. F., Deng S. G., Environ. Sci. Technol. 2015, 49(15), 9364

    Article  CAS  PubMed  Google Scholar 

  29. Li T., Rosi N. L., Chem. Commun. 2013, 49(97), 11385

    Article  CAS  Google Scholar 

  30. Lau C. H., Baatmao R., Hill M. R., Chem. Commun. 2013, 49(35), 3634

    Article  CAS  Google Scholar 

  31. Ratvijitvech T., Dawson R., Laybourn A., Khimyak Y. Z., Adams D. J., Cooper A. I., Polymer 2014, 55(1), 321

    Article  CAS  Google Scholar 

  32. Li Y. Q., Ben T., Qiu S. L., Acta Chim. Sinica 2015, 73(6), 605

    Article  CAS  Google Scholar 

  33. Zhao Y. F., Yao K. X., Teng B. Y., Zhang T., Han Y., Energy Environ. Science 2013, 6(12), 3684

    Article  CAS  Google Scholar 

  34. Dybtsev D. N., Chun H., Yoon S. H., Kim D. W., Kim K., J. Am. Chem. Soc., 2004, 126(1), 32

    Article  CAS  PubMed  Google Scholar 

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Authors and Affiliations

  1. College of Chemistry, Jilin University, Changchun, 130012, P. R. China

    Tingting Yan, Guolong Xing, Saikat Das, Teng Ben & Shilun Qiu

Authors
  1. Tingting Yan
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  2. Guolong Xing
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  3. Saikat Das
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  4. Teng Ben
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  5. Shilun Qiu
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Corresponding author

Correspondence to Teng Ben.

Additional information

Supported by the National Natural Science Foundation of China(Nos.21390394, 21471065) and the “111” Project of China (No.B07016).

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Yan, T., Xing, G., Das, S. et al. Porous Organic Frameworks-derived Porous Carbons with Outstanding Gas Adsorption Performance. Chem. Res. Chin. Univ. 34, 338–343 (2018). https://doi.org/10.1007/s40242-018-8014-4

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  • DOI: https://doi.org/10.1007/s40242-018-8014-4

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