Skip to main content

Advertisement

SpringerLink
Log in

Chemiluminescent determination of cyromazine in milk samples using copper(III) chelate-Triton X-100 by flow injection analysis

  • Published:
Chemical Research in Chinese Universities Aims and scope

Abstract

Cyromazine(CYR) was determined in milk samples using copper(III) chelate-Triton X-100 chemiluminescence(CL) system associated with flow-injection(FI) in KOH medium. The relative CL intensity for CYR concentration was linear over the range of 5×10–4―10 μg/mL(R 2=0.9990, n=11) with injection rate of 160 h–1 and the relative standard deviation(RSD, n=4) of 1.2%―2.6%. The limit of detection(LOD) for signal-to-noise ratio of 3 was 1.5×10–4 μg/mL. The influences of key chemical and physical parameters, some major fresh water ions at their maximum admissible concentrations and a number of pesticides were examined as potential interferences. The concentrations of CYR in spiked milk samples were successfully determined by the proposed method and the results were in good agreement with the previously reported HPLC method, having recovery range of (92±4)%―(106±2)%. The possible CL reaction mechanism for copper(III) complex-Triton X-100-CYR was also briefly discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Bel Y., Wiesner P., Kayser H., Arch. Insect. Biochem. Physiol., 2000, 45, 69

    Article  CAS  Google Scholar 

  2. Thomson W. T., Agricultural Chemicals, Book I, Insecticides, Thompson Publications, Fresno, California, 1994

    Google Scholar 

  3. Cook A. M., Hutter R. S., J. Agric. Food Chem., 1981, 29, 1135

    Article  CAS  Google Scholar 

  4. Melnick R. L., Boorman G. A., Haseman J. K., Montali R. J., Huff J., Toxicol. Appl. Pharm., 1984, 72, 292

    Article  CAS  Google Scholar 

  5. Us FDA, Code of Federal Regulations: Tolerances for Residues of New Animal Drugs in Food, Part 556.67, Title 21, 1987

    Google Scholar 

  6. Wei R., Wang R., Zeng Q., Chen M., Liu T., J. Chromatogr. Sci., 2009, 47, 581

    Article  CAS  Google Scholar 

  7. Codex Alimentarius Commission, Pesticide Residues in Food and Feed, Cyromazine, Updated as at the 35th Session of the Codex Alimentarius Commission, 2012

    Google Scholar 

  8. Bai W., Zhu C., Zhang G., Huang Y., Yan J., Yan M., Chen A., Anal. Methods, 2016, 8, 5869

    Article  CAS  Google Scholar 

  9. Zhoun Y. Y., Yang J., Liu M., Wang S. F., Lu Q., J. Lumin., 2010, 130, 817

    Article  Google Scholar 

  10. Armenta S., Quintas G., Garrigues S., de la Guardia M., Anal. Chim. Acta, 2004, 524, 257

    Article  CAS  Google Scholar 

  11. Mercan H., Inam R., Enein H. Y. A., Anal. Lett., 2011, 44, 1392

    Article  CAS  Google Scholar 

  12. Liu J. X., Zhong Y. B., Liu J., Zhang H. C., Xi J. Z., Wang J. P., Food Control, 2010, 21, 1482

    Article  CAS  Google Scholar 

  13. Le T., Yan P., Xu J., Hao Y., Food Chem., 2013, 138, 1610

    Article  CAS  Google Scholar 

  14. Wang C. Y., Qi Y. X., Liu X. Q., Adv. Mat. Res., 2014, 1033/1034, 533

    Google Scholar 

  15. Meng Z., Shi Z., Liang S., Dong X., Lv Y., Sun H., Food Control, 2015, 55, 158

    Article  CAS  Google Scholar 

  16. Wu X., Ge X., Liang S., Sun H., Food Anal. Methods, 2014, 7, 774

    Article  Google Scholar 

  17. Wang H., Lin L., Sun Q., Lin Q., Xiong X., Wu K., Yu C. P., Int. J. Environ. Anal. Chem., 2014, 94, 1173

    Article  CAS  Google Scholar 

  18. Furusawa N., J. Anal. Sci. Meth. Instrum., 2012, 2, 68

    CAS  Google Scholar 

  19. Zhang Y., Lin S., Jiang P., Zhu X., Ling J., Zhang W., Dong X., J. Chromatogr. A, 2014, 1337, 17

    Article  CAS  Google Scholar 

  20. Shang B., Chen Y., Wang Z., Yang W., Zhang L., J. Anim. Vet. Adv., 2011, 10, 73

    Article  CAS  Google Scholar 

  21. Mansilha C., Melo A., Rebelo H., Ferreira I. M. P. L. V. O., Pinho O., Domingues V., Pinho C., Gameiro P., J. Chromatogr. A, 2010, 1217, 6681

    Article  CAS  Google Scholar 

  22. Wang T., Dong Y., Chen P., Su M., Sun H., World J. Pharm.& Pharm. Sci., 2015, 4, 1340

    CAS  Google Scholar 

  23. Gracia L. G., Campana A. M. G., Chinchilla J. J. S., Perez J. F. H., Casado A. G., Trends Anal. Chem., 2005, 24, 927

    Article  Google Scholar 

  24. Wang X., Lin J. M., Liu M. L., Cheng X. L., Trends Anal. Chem., 2009, 28, 75

    Article  Google Scholar 

  25. Adcock J. L., Barnett N. W., Barrow C. J., Francis P. S., Anal. Chim. Acta, 2014, 807, 9

    Article  CAS  Google Scholar 

  26. Yang C., Zhang Z., Talanta, 2010, 81, 477

    Article  CAS  Google Scholar 

  27. Yang C., Chen F., Chang Z., Sun Y., Zhang Z., Spectrochim. Acta A, 2014, 121, 288

    Article  CAS  Google Scholar 

  28. Asghar M., Yaqoob M., Munawar N., Nabi A., Anal. Sci., 2016, 32, 337

    Article  CAS  Google Scholar 

  29. Hu Y., Zhang Z., Li G., Talanta, 2010, 81, 499

    Article  CAS  Google Scholar 

  30. Iranifam M., Luminescence, 2013, 28, 798

    Article  CAS  Google Scholar 

  31. Wu Z. J., Zhang Z. B., Liu L. S., Electrochim. Acta, 1997, 42, 2719

    Article  CAS  Google Scholar 

  32. Shi S. S., Chen P. Y., Sun H. W., Chinese J. Anal. Lab., 2011, 30, 47

    Google Scholar 

  33. Sun H., Wang J., Chen P., Wang T., Asian J. Pharm. Sci. Res., 2011, 1, 21

    Google Scholar 

  34. Sun H., Wang J., Wang T., Luminescence, 2013, 28, 592

    Article  CAS  Google Scholar 

  35. Yao H., Zhang M., Zeng W., Zeng X., Zhang Z., Spectrochim. Acta A, 2014, 117, 645

    Article  CAS  Google Scholar 

  36. Hu Y., Li G., Zhang Z., Luminescence, 2011, 26, 313

    Article  CAS  Google Scholar 

  37. Das K. Jain B., Patel H. S., Spectrochim. Acta A, 2004, 60, 2059

    Article  Google Scholar 

  38. Hait S. K., Moulik S. P., J. Surfact. Deterg., 2001, 4, 303

    Article  CAS  Google Scholar 

  39. Saha D. C., Ray K., Misra T. N., Spectrochim. Acta A, 2000, 56, 797

    Article  CAS  Google Scholar 

  40. Zhao J., Wei Y. J., Spectroscopy and Spectral Analysis, 2006, 26(8), 1523

    CAS  Google Scholar 

  41. He Y., Shen X., Gao H., He Y., J. Photochem. Photobiol. A: Chem., 2008, 193, 178

    Article  CAS  Google Scholar 

  42. Crabb N. T., Persinger H. E., J. Amer. Oil Chem. Soc., 1964, 41, 752

    Article  CAS  Google Scholar 

  43. Greff R. A., Setzkorn E. A., Leslie W. D., J. Amer. Oil Chem. Soc., 1965, 42, 180

    Article  CAS  Google Scholar 

  44. Jaiswal P. K., Ysdava K. L., J. Indian Chem., 1973, 11, 837

    CAS  Google Scholar 

  45. Jose T. P., Tuwar S. M., J. Mol. Struct., 2007, 827, 137

    Article  CAS  Google Scholar 

  46. Chou S. S., Hwang D. F., Lee H. F., J. Food Drug Anal., 2003, 11, 290

    CAS  Google Scholar 

  47. Waseem A., Yaqoob M., Nabi A., Luminescence, 2010, 25, 71

    CAS  Google Scholar 

  48. Miller J. N., Miller J. C., Statistics and Chemometrics for Analytical Chemistry, 5th Ed., Pearson Education Limited, London, 2005, 45

    Google Scholar 

  49. Sanchez F. G., Ruiz C. C., J. Lumin., 1993, 55, 321

    Article  Google Scholar 

  50. Kalyanasundaram K., Thomas J. K.; Ed.: Mittal K. L., Micellization, Solubilization, and Microemulsion, Vol. 2, Plenum, New York, 1977, 569

    Book  Google Scholar 

  51. Forster T., Ann. Phys., 1948, 2, 55

    Article  CAS  Google Scholar 

  52. Liang F. H., Wang D., Ma P. Y., Wang X. H., Song D. Q., Yu Y., Chem. Res. Chinese Universities, 2015, 31(5), 724

    Article  CAS  Google Scholar 

  53. Clegg R. M., Lab. Tech. Biochem. Mol. Biol., 2009, 33, 1

    Article  Google Scholar 

  54. Mote U. S., Patil S. R., Kolekar G. B., J. Mol. Liq., 2010, 157, 102

    Article  CAS  Google Scholar 

  55. Liu T., Guo R., J. Surfact.Deterg., 2008, 11, 33

    Article  CAS  Google Scholar 

  56. Goutailler G., Valette J. C., Guillard C., Paisse O., Faure R., J. Pho-tochem. Photobiol. A: Chem., 2001, 141, 79

    Article  CAS  Google Scholar 

  57. Young L., Tetrahedron Lett., 1968, 9, 5105

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, University of Balochistan, Quetta, 87300, Pakistan

    Muhammad Asghar, Mohammad Yaqoob & Abdul Nabi

Authors
  1. Muhammad Asghar
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Mohammad Yaqoob
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Abdul Nabi
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Mohammad Yaqoob.

Additional information

Supported by the Higher Education Commission of Pakistan(No.20-2732/NRPU/R&D/HEC).

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Asghar, M., Yaqoob, M. & Nabi, A. Chemiluminescent determination of cyromazine in milk samples using copper(III) chelate-Triton X-100 by flow injection analysis. Chem. Res. Chin. Univ. 33, 354–359 (2017). https://doi.org/10.1007/s40242-017-6402-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s40242-017-6402-9

Keywords

Search

Navigation