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Effect of Composition and Thickness on the Hardness and Scratch Resistance of Copper and Copper Alloy Coatings

  • Research Article - Mechanical Engineering
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Abstract

Coatings are extensively used as corrosion resistance, wear resistance, and antibacterial surfaces. Copper and copper alloys are among the most widely applied coating materials for industrial and medical applications. In this work, mechanical assessment of Cu, Cu 4%Sn, Cu 17%Ni 10%Zn (German Silver), and Cu 17%Al 1%Fe coatings deposited on stainless steel 316L substrates using twin wire arc thermal spraying is studied experimentally. Microstructure, hardness, and scratch resistance were studied for all coated samples. The effects of having different coating compositions on the mechanical properties are analyzed. The effect of the coatings thickness is also investigated for Cu 17%Ni 10%Zn and Cu 17%Al 1%Fe coatings with different thicknesses between 200 and \(400\,\upmu \hbox {m}\). The study focused on how the scratch resistance increases with increasing the coating thickness on the expense of the adhesion. A comparison of the coating hardness profile between different copper and copper alloy compositions was presented. An interesting observation was that even though scratch hardness increases with the coating thickness, hardness decreases as a function of the distance from the interface.

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References

  1. Sharifahmadian, O.; Salimijazi, H.R.; Fathi, M.H.; Mostaghimi, J.; Pershin, L.: Relationship between surface properties and antibacterial behavior of wire arc spray copper coatings. Surf. Coat. Technol. 233, 74–79 (2013)

    Article  Google Scholar 

  2. Zhang, E.; Li, F.; Wang, H.; Liu, J.; Wang, C.; Li, M.; Yang, K.: A new antibacterial titanium–copper sintered alloy: preparation and antibacterial property. Mater. Sci. Eng. C. Mater. Biol. Appl. 33(7), 42807 (2013)

    Google Scholar 

  3. Jin, X.; Gao, L.; Liu, E.; Yu, F.; Shu, X.; Wang, H.: Microstructure, corrosion and tribological and antibacterial properties of Ti–Cu coated stainless steel. J. Mech. Behav. Biomed. Mater. 50, 23–32 (2015)

    Article  Google Scholar 

  4. Wu, H.; Zhang, X.; Geng, Z.; Yin, Y.; Hang, R.; Huang, X.; Yao, X.; Tang, B.: Preparation, antibacterial effects and corrosion resistant of porous Cu–TiO\(_2\) coatings. Appl. Surf. Sci. 308, 43–49 (2014)

    Article  Google Scholar 

  5. Jaiswal, S.; McHale, P.; Duffy, B.: Preparation and rapid analysis of antibacterial silver, copper and zinc doped sol–gel surfaces. Colloids Surf. B Biointerfaces 94, 1706 (2012)

    Article  Google Scholar 

  6. Li, W.; Lu, Y.; Yuan, K.; Yuan, C.: Effects of cerium on microstructure and bonding strength of Cu–14Al–4.5Fe bronze plasma sprayed coating. J. Rare Earths 29(4), 363–369 (2011)

    Article  Google Scholar 

  7. Culha, O.; Celik, E.; Ak Azem, N.F.; Birlik, I.; Toparli, M.; Turk, a: Microstructural, thermal and mechanical properties of HVOF sprayed Ni–Al-based bond coatings on stainless steel substrate. J. Mater. Process. Technol. 204(1–3), 221–230 (2008)

    Article  Google Scholar 

  8. Santana, Y.Y.; Renault, P.O.; Sebastiani, M.; La Barbera, J.G.; Lesage, J.; Bemporad, E.; Le Bourhis, E.; Puchi-Cabrera, E.S.; Staia, M.H.: Characterization and residual stresses of WC–Co thermally sprayed coatings. Surf. Coat. Technol. 202(18), 4560–4565 (2008)

    Article  Google Scholar 

  9. Deshpande, S.; Sampath, S.; Zhang, H.: Mechanisms of oxidation and its role in microstructural evolution of metallic thermal spray coatings—case study for Ni–Al. Surf. Coat. Technol. 200(18–19), 5395–5406 (2006)

    Article  Google Scholar 

  10. Planche, M.P.; Liao, H.; Coddet, C.: Relationships between in-flight particle characteristics and coating microstructure with a twin wire arc spray process and different working conditions. Surf. Coat. Technol. 182(2–3), 215–226 (2004)

    Article  Google Scholar 

  11. Eason, P.D.; Fewkes, Ja; Kennett, S.C.; Eden, T.J.; Tello, K.; Kaufman, M.J.; Tiryakioğlu, M.: On the characterization of bulk copper produced by cold gas dynamic spray processing in as fabricated and annealed conditions. Mater. Sci. Eng. A 528(28), 8174–8178 (2011)

    Article  Google Scholar 

  12. Qian, J.; Yin, Y.; Li, T.; Hu, X.; Wang, C.; Li, S.: Structure, micro-hardness and corrosion behaviour of the Al–Si/Al\(_2\)O\(_3\) coatings prepared by laser plasma hybrid spraying on magnesium alloy. Vacuum 117, 55–59 (2015)

    Article  Google Scholar 

  13. Bull, S.J.; Berasetegui, E.G.E.: Chapter 7 An Overview of the Potential of Quantitative Coating Adhesion Measurement by Scratch Testing, 15th edn. Elsevier Masson SAS, Amsterdam (2006)

    Google Scholar 

  14. Briscoe, B.J.; Evans, P.D.; Biswas, S.K.; Sinha, S.K.: The hardnesses of poly(methylmethacrylate). Tribol. Int. 29(2), 93–104 (1996)

    Article  Google Scholar 

  15. Beegan, D.; Chowdhury, S.; Laugier, M.T.: Comparison between nanoindentation and scratch test hardness (scratch hardness) values of copper thin films on oxidised silicon substrates. Surf. Coat. Technol. 201(12), 5804–5808 (2007)

    Article  Google Scholar 

  16. Sinha, S.K.; Song, T.; Wan, X.; Tong, Y.: Scratch and normal hardness characteristics of polyamide 6/nano-clay composite. Wear 266(7–8), 814–821 (2009)

    Article  Google Scholar 

  17. Chen, Z.; Wu, L.Y.L.: Scratch Damage Resistance of Silica-Based Sol–Gel Coatings on Polymeric Substrates, 2nd edn. Elsevier, Amsterdam (2013)

    Google Scholar 

  18. Gedzevicius, I.; Valiulis, A.V.: Analysis of wire arc spraying process variables on coatings properties. J. Mater. Process. Technol. 175(1–3), 206–211 (2006)

    Article  Google Scholar 

  19. Pistofidis, N.; Vourlias, G.; Pavlidou, E.; Patsalas, P.; Stergioudis, G.; Polychroniadis, E.K.: Study of the structure and morphology of plasma-sprayed tin coating. Surf. Coat. Technol. 200, 6245–6250 (2006)

  20. Kudashov, D.V.; Zauter, R.; Müller, H.R.: Spray-formed high-aluminium bronzes. Mater. Sci. Eng. A 477(1–2), 43–49 (2008)

    Article  Google Scholar 

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Authors and Affiliations

  1. Mechanical Engineering Department, King Fahd University of Petroleum and Minerals, Dhahran, 31261, Saudi Arabia

    Khaled S. Al-Athel, Mohamed Ibrahim, Abul Fazal M. Arif & Syed Sohail Akhtar

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  1. Khaled S. Al-Athel
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  2. Mohamed Ibrahim
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  3. Abul Fazal M. Arif
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  4. Syed Sohail Akhtar
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Correspondence to Khaled S. Al-Athel.

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Al-Athel, K.S., Ibrahim, M., Arif, A.F.M. et al. Effect of Composition and Thickness on the Hardness and Scratch Resistance of Copper and Copper Alloy Coatings. Arab J Sci Eng 42, 4895–4904 (2017). https://doi.org/10.1007/s13369-017-2661-5

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  • DOI: https://doi.org/10.1007/s13369-017-2661-5

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