Abstract
The volcano plots reported in the field of electrocatalysis utilize data with a difference of three orders of magnitude between the worst and the best rhenium electrocatalytic activity toward the hydrogen evolution reaction (HER). However, the commonly used mean value of the exchange density current (j 0) of the HER on rhenium is log j 0 = −2.9 A cm−2, which is higher than the value used for platinum (log j 0 = −3.3 A cm−2). This fact seems to contradict Sabatier’s principle and points to the possibility that this value corresponds more to rhenized surfaces than to metallic rhenium. Rhenized surfaces are primarily composed of a mixture of oxides; therefore, the electrocatalytic behavior is attributed to these thin films rather than to metallic rhenium. In addition, a selected review of rhenized electrodes is included herein because these issues have not been considered in the electrocatalysis literature at the present time. We initially believed that the kinetic parameters might have been overestimated due to the formation of rhenide ion or rhenium hydride species; however, no evidence of the formation of these species was found. Our experimental mean value of the exchange current density of the HER on metallic rhenium is 7 × 10−5 A cm−2 in acidic solution. Therefore, our results are in accordance with Sabatier’s principle, which states that a weak adsorption energy of hydrogen on rhenium (energy, 6.9 kJ mol−1) results in a slow rate of reaction (log j 0 = −4.2 A cm−2), whereas an intermediate adsorption energy of hydrogen on platinum (12 kJ mol−1) produces a fast reaction (log j 0 = −3.3 A cm−2).
References
G. Pecherskaya, V.V. Stender, Zhur. Fiz. Khim. 24, 856 (1950). Abstracts from SciFinder® ACS (2013)
M.J. Joncich, L.S. Stewart, F.A. Posey, J. Electrochem. Soc. 112, 717 (1965)
a) V. L. Krasikov, Elektrokhimiya, 17, 1518 (1981); b) V.L. Krasikov, Elektrokhimiya, 19, 209 (1983).
S. Szabó, I. Bakos et al., Proceedings of the 7th International Symposium on Scientific Bases for the Preparation of Heterogeneous Catalysts (Elsevier, Amsterdam, 1998), pp. 269–276
J.H. Chun, S.K. Jeon, K.H. Ra, J.Y. Chun, Int. J. Hydrogen Energy 30, 485 (2005)
E. Méndez, M.F. Cerdá, A.M. Castro-Luna, C.F. Zinola, C. Kremer, M.E. Martins, J. Colloid Interface Sci. 263, 119 (2003)
S. Trasatti, in Advances in Electrochemistry and Electrochemical Engineering, ed. by H. Gerisher, C.W. Tobias (Wiley, New York, 1977), p. 19
W. Schmickler, E. Santos, Interfacial Electrochemistry, 2nd edn. (Springer, Berlin, 2010), p. 166
A.J. Arvia, A.E. Bolzan, M.A. Pasquale, in Catalysis in Electrochemistry: From Fundamentals to Strategies for Fuel Cell Development, ed. by E. Santos, W. Schmickler (Wiley, USA, 2011), p. 35
S. Trasatti, J. Electroanal. Chem. 39, 163 (1972)
a) J. K. Nørskov, T. Bligaard, A. Logadottir, J. R. Kitchin, J. G. Chen, S. Pandelov, U. Stimming, J. Electrochem. Soc., 152, J23 (2005), b) K.Nørskov, T. Bligaard, A. Logadottir, J. R. Kitchin, J. G. Chen, S. Pandelov, U. Stimming, J. Electrochem. Soc. 153, L33 (2006)
Y.Y. Andreev, Prot. Met. Phys. Chem. Surf. 48, 290 (2012)
N. Eliaz, E. Gileadi, in Modern Aspects of Electrochemistry, ed. by C.G. Vayenas, R.E. White, M.E. Gamboa-Aldeco, vol. 42 (Springer, New York, 2008), p. 268. 270–279
B.P. Hahn, R.A. May, K.J. Stevenson, Langmuir 23, 10837 (2007)
R.J. Magee, T.J. Cardwell, in Encyclopedia of Electrochemistry of the Elements, ed. by A.J. Bard, vol. 2 (Marcel Dekker, New York, 1973), pp. 129–131. 133-136,145-146, 149, 175–177
R. Schrebler, P. Cury, M. Orellana, H. Gomez, R. Cordova, E.A. Dalchiele, Electrochim. Acta 46, 4309 (2001)
J.O. Zerbino, A.M. Castro-Luna, C.F. Zinola, E. Méndez, M.E. Martins, J. Electroanal. Chem. 521, 168 (2002)
R. Schrebler, P. Cury, C. Suárez, E. Muñoz, F. Vera, R. Córdova, H. Gómez, J.R. Ramos-Barrado, D. Leinen, E.A. Dalchiele, Thin Solid Films 483, 50 (2005)
M.H. Miles, M.A. Thomason, J. Electrochem. Soc. 123, 1459 (1976)
J. Gómez, J.I. Gardiazábal, R. Schrebler, H. Gómez, R. Córdova, J. Electroanal. Chem. 260, 113 (1989)
M.H. Miles, J. Electroanal. Chem. 60, 89–96 (1975)
B.V. Tilak, A.C. Ramamurthy, B.E. Conway, Proceedings of the Indian Academy of Sciences-Chemical Sciences, vol. 97 (Springer, India, 1986), p. 366
G.E.F. Lundell, H.B. Knowles, H.B. Bur, Stand. J. Res. 18, 629 (1937)
L. Pauling, Chem. Eng. News 25, 297 (1947)
J.B. Bravo, E. Griswold, J. Kleinberg, J. Phys. Chem. 58, 18 (1954)
J.W. Cobble, J. Phys. Chem. 61, 727 (1957)
A.P. Ginsberg, J.M. Miller, J.R. Cavanaugh, B.P. Dailey, Nature 185, 528 (1960)
N.N. Greenwood, A. Earnshaw, Chemistry of the Elements, 2nd edn. (Butterworth-Heinemann, Oxford, 1997), p. 1048. 1050, 1054, 1058
J.E. Ellis, Inorg. Chem. 45, 3167 (2006)
N. de Zoubov, M. Pourbaix, in Atlas of Electrochemical Equilibria in Aqueous Solutions (NACE, Texas, 1974), pp. 300–306
G. Inzelt, in The Encyclopedia of Electrochemistry, ed. by A.J. Bard, M. Stratman, F. Scholz, C.J. Pickett, vol. 7 (Wiley-VCH, Weinheim, 2006), pp. 35–36
A.J. Bard, R. Parsons, J. Jordan, Standard Potentials in Aqueous Solution (Marcel Dekker, New York, 1985), pp. 444–451
M.S. Antelman, Encyclopedia of Chemical Electrode Potentials (Plenum Press, New York, 1982), p. 176
A.J. Dean, Lange’s Handbook of Chemistry, 15th edn. (McGraw-Hill, New York, 1999), p. 6.110
N. Takeno, Atlas of Eh-pH Diagrams (National Institute of Advanced Industrial Science and Technology, Japan, 2005), p. 211
S.G. Bratsch, J. Phys. Chem. Ref. Data 18, 1 (1989)
C.G. Zoski, Handbook of Electrochemistry (Elsevier, Netherlands, 2007), p. 456
S. Krause, in Instrumentation and Electroanalytical Chemistry, ed. by A.J. Bard, M. Stratmann, vol. 3 (Wiley-VCH, Berlin, 2003), p. 202
P. Wehner, J.C. Hindman, J. Am. Chem. Soc. 75, 2873 (1953)
C.L. Rulfs, P.J. Elving, J. Am. Chem. Soc. 73, 3284 (1951)
C.L. Rulfs, P.J. Elving, J. Am. Chem. Soc. 73, 3287 (1951)
Rhenium, ASM Handbook, vol. 2 (10th (ASM International, Ohio, 1998), pp. 4843–4844
H. Kita, J. Res. Inst. Catal. Hokkaido Univ 13, 151 (1965)
V.I. Kopylets, Mater Sci 35, 438 (1999)
A.J. Appleby, H. Kita, M. Chemla, G. Bronoel, in Encyclopedia of Electrochemistry of the Elements, ed. by A.J. Bard, vol. 9 (M. Dekke, New York, 1982), pp. 456–457
M.M. Jaksic, J. New Mater. Electrochem. Syst. 3, 153 (2000)
J.O. Zerbino, A.M. Castro-Luna, C.F. Zinola, E. Méndez, M.E. Martins, J. Braz. Chem. Soc. 13, 510 (2002)
A.V. Uscategui, E. Mosquera, L. Cifuentes, Mater. Lett. 94, 44 (2013)
S. Szabo, I. Bakos, J. Electroanal. Chem. 492, 103 (2000)
M. Castriota, E. Cazzanelli, G. Das, R. Kalendarev, A. Kuzmin, S. Marino, G. Mariotto, J. Purans, N. Scaramuzza, Mol. Cryst. Liq. Cryst. Sci. Technol. Sect. 474, 1 (2007)
J.S. Lord, W.G. Williams, Solid State Ion. 145, 381 (2001)
M. Calatayud, F. Tielens, in Catalysis in Electrochemistry: From Fundamentals to Strategies for Fuel Cell Development, ed. by E. Santos, W. Schmickler (Wiley, New York, 2011), p. 395
B.E. Conway, G. Jerkiewicz, Electrochim. Acta 45, 4075 (2000)
B.E. Conway, G. Jerkiewicz, Solid State Ion. 150, 93 (2002)
G. Jerkiewicz, Electrocatalysis 1, 17 (2010)
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This work was performed under the support of the CONACYT (project numbers 102018 and 224366).
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Garcia-Garcia, R., Ortega-Zarzosa, G., Rincón, M.E. et al. The Hydrogen Evolution Reaction on Rhenium Metallic Electrodes: A Selected Review and New Experimental Evidence. Electrocatalysis 6, 263–273 (2015). https://doi.org/10.1007/s12678-014-0240-z
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DOI: https://doi.org/10.1007/s12678-014-0240-z