1 Introduction
Christopher was born in Leoben, Austria in 1968 and studied materials science at the Montan University, where he graduated with excellence in 1992. In his early academic career, Christopher studied ceramic matrix composites and crystallographic fractometry of fracture surfaces and he completed his dissertation on this topic at the Erich Schmid Institute for Materials Science in Austria.
Christopher joined the European Space Agency in 1998 as a materials engineer, and he was made Head of the Materials Physics and Chemistry Section in 2012. In early 2019, he was promoted to the Lead Engineer position within the Product Assurance and Safety Department. During his career in ESA, Christopher won several team achievement awards and he is owner of several patents. He also gave an annual summer course within the Department of Materials Science at his former university on the subject of Materials for Space Application.
After moving into the space business, Christopher continued to develop his expertise in materials science and engineering, especially focusing on the environmental durability of polymeric materials. He constructed numerous environmental test facilities for performing environmental exposure testing of materials and components, of which some notable examples were a synergistic radiation test facility, an atomic oxygen simulation facility, several UV test facilities, a high-temperature thermal vacuum oven and a facility for performing electrostatic discharge testing of materials (Fig. 1).
Coupled to these facilities, a number of innovative measurement devices for studying degradation effects were developed, including a spectrophotometer for performing thermo-optical measurements under vacuum and an in-situ temperature measurement system (Fig. 2).
Christopher utilized many different techniques to study degradation effects on materials. A particular interest was thermal analysis, and he utilized a number of advanced methods including coupled mass spectrometry & thermo-gravimetric analysis. He also used model-free kinetics to predict the lifetime performance of adhesive systems. Indeed, accelerated testing and lifetime prediction was a common theme across much of his work and this remains a significant challenge today in the field of environmental testing.
It is of course difficult to make a complete list of the materials investigated, but there are some notable examples. During his career, he investigated all classes of materials (metals, polymers, ceramics and composites) from aerogel to film application. Metal bi-layers and interfaces with polymer substrates were a recurring theme in Christopher’s work, particularly the effects of extreme thermal cycling and radiation. Thermal control materials also feature prominently, including optical solar reflectors, solar cell materials, multi-layer insulation and various types of thermal control coating.
2 Materials
Christopher performed a number of studies allowing the development of new materials for space application. Related to fiber-reinforced polymer (CFRP), in one study, carbon fiber/ PEEK composite was used to produce composite overwrapped pressure vessels (COPV) by mean of Laser-Assisted Tape-Placement including a full PEEK-based liner. Such concept led to low permeability and enhanced damage resistance to crack formation under cryogenic application [1,2,3].
One of these was self-healing of composite structures, utilizing multi-component adhesive systems embedded in thin fibers. In 2005, he looked at self-healing material and concepts applied to composite structure for space application within Europe. The work performed demonstrated that autonomous healing concept implemented in composite structure via hollow fibers led to healing of damages and stay functional even after being exposed to vacuum and thermal cycling [4]. After this pioneering work, the self-healing concept was applied to PI film to enhance its resistance toward atomic oxygen erosion in Low Earth Orbit environment [5] and applied on COPV using intrinsic healing materials for ballistic impact protection together with damage detection capabilities [6]. This baseline work performed is now pursued within ESA looking into self-healing concept for ballistic impact protection for inflatable structure.
Under Christopher’s leadership, in 2015, ESA acquired the prototype of the first commercial 3D printer capable to print PolyEtherEtherKetone (PEEK) based on the Fused Filament Fabrication technology for its assessment for in-space manufacturing purpose [7]. Since then, this material in combination with this technology has been further developed worldwide for many on-ground applications. From a specific space application, his input led to the development of the ESA MELT printer (Fig. 3) suitable for operation in microgravity under the ISS operation constrain [8]. Other topics like the development of electrically conductive PEEK [9], PEEK recycling, looking into effect of vacuum during printing process [10] were conducted in his team. Finally, he contributed to better evaluate this specific material/process relationship in view of qualification and standardization for space application.
More recently, he started to look at additive manufacturing, going beyond 3D printing to assess 4D printing concepts for space application [11] using multi-material 3D printing technology. Mixing rigid and flexible polymers, it is possible to design and manufacture object with programmed residual strain that will lead to shape changing upon thermal stimulus (Fig. 4). At this time, the environmental exposure effects on the reversibility, durability and efficiency of such technology are being assessed.
Thermoelectric materials are very appealing for space application. Improvement of their efficiency has been one of Christopher’s fields of investigation. He looked at the improvement of bulk properties of Chevrel phase-derived Ag3.6Mo9Se11 alloy by Cu insertion (Ag3.6Cu0.2Mo9Se11 and Ag3.6Cu0.4Mo9Se11) [12], at optimize synthesis process for the enhancement of SnTe [13,14,15] and at SnSe single crystalline phase as promising new candidate for thermoelectric application [16].
3 Space environment
Spaceflight experiments were of particular interest to Christopher, and he studied materials retrieved from the Long Duration Exposure Facility, the Hubble Space Telescope [17], as well as the Materials Exposure and Degradation Facility (MEDET) (Fig. 5) [18]. Very recently, he was involved in a new opportunity to expose new materials on the International Space Station.
During his career, he dedicated a lot of effort to increase the understanding of the effect of the space environment on materials in general with a strong focus on thermo-optical properties [19]. Most of the materials used for thermal control were investigated: Polyimide [20], thin-polymer-film materials for potential use as solar sails [21], metal-polymer-based film [22,23,24].
Finally, the summary would not be complete without highlighting the specific space missions which Christopher contributed to. Notable examples are ESA’s Venus Express [20, 25, 26], and the Bepi-Colombo mission to Mercury [27,28,29,30]. These missions created very specific challenges related to synergistic degradation of materials due to high-temperature and high-intensity UV exposure. Christopher led numerous investigations on the degradation properties of thermal control materials [31] and solar array materials [32] for these missions. A very notable contribution to the Bepi Colombo mission was the development and testing of a new high-temperature ceramic coating for the high gain antenna (Fig. 6) [33].
4 Closing remarks
This special issue gathers several original contributions related to the field of Materials’ Physics and Chemistry for Space Application. We hope that this special journal edition can be used as a lasting reminder for Christopher’s family of the work he performed, as well as a motivation for a future generation of young scientists and engineers working in this specialized field. Christopher’s sudden passing at an early age is a great loss to the materials science and space community and his many friends and colleagues. We shall continue the work in his memory and continue to aim for scientific and engineering excellence, to quote a phrase which Christopher often used.
References
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Murray, B.R., Doyle, A., Feerick, P.J., Semprimoschnig, C.O.A., Leen, S.B., Brádaigh, C.M.Ó.: Rotational moulding of PEEK polymer liners with carbon fibre/PEEK over tape-placement for space cryogenic fuel tanks. Mater. Des. 132, 567–581 (2017). https://doi.org/10.1016/j.matdes.2017.07.026
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This special edition is dedicated to the memory and legacy of our respected colleague Christopher Semprimoshnig, who sadly passed away in June 2020 at the age of 52. Christopher leaves behind his wife Carla, and two children Sophie and Lucas. The intention of this special issue is to showcase the general field of “Materials’ Physics and Chemistry for Space Applications” which Christopher dedicated his career to, including the many diverse technical topics studied over the years together with his team within the European Space Agency, as well as with many international partners in academia, national space agencies, research institutes and industries.
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Lafont, U., Tighe, A., Rampini, R. et al. Materials’ physics and chemistry for space application: in memoriam of Christopher Semprimoschnig. CEAS Space J 13, 317–322 (2021). https://doi.org/10.1007/s12567-021-00382-4
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DOI: https://doi.org/10.1007/s12567-021-00382-4