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Heterojunction between bimetallic metal-organic framework and TiO2: Band-structure engineering for effective photoelectrochemical water splitting

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Abstract

Bimetallic Fe/Ni-based metal-organic frameworks (MOFs) with different Fe/Ni ratios were coated on TiO2 nanorods (NRs), and the performances of the heterojunction photoanodes in photoelectrochemical water splitting were investigated. The bandgaps and band positions of the MOFs could be modulated by changing the ratio of the Fe and Ni components. An ideal band alignment was achieved between the TiO2 NRs and bimetallic MOFs with an optimum ratio of [Fe]/[Ni] = 0.25/0.75, which allowed efficient light absorption and charge separation. The coating of NH2−MIL(Fe)−88 layer on the TiO2 NRs decreased the photocurrent density by 33%. In comparison, TiO2/NH2−MIL(Ni)−88 showed a modest improvement in photocurrent density (0.85 mA·cm−2 at 1.23 V vs. a reversible hydrogen electrode (RHE)). When bimetallic NH2−MIL(Fe0.25Ni0.75)−88 was coated on the TiO2 NRs, the photocurrent density reached 1.56 mA·cm−2, which was an efficiency enhancement of 3.2 times. The mechanism underlying high photoelectrochemical performance was investigated.

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References

  1. Jiang, C. R.; Moniz, S. J. A.; Wang, A. Q.; Zhang, T.; Tang, J. W. Photoelectrochemical devices for solar water splitting-materials and challenges. Chem. Soc. Rev. 2017, 46, 4645–4660.

    Article  CAS  Google Scholar 

  2. Nair, V.; Perkins, C. L.; Lin, Q. Y.; Law, M. Textured nanoporous Mo: BiVO4 photoanodes with high charge transport and charge transfer quantum efficiencies for oxygen evolution. Energy Environ. Sci. 2016, 9, 1412–1429.

    Article  CAS  Google Scholar 

  3. Zhao, Y. H.; Brocks, G.; Genuit, H.; Lavrijsen, R.; Verheijen, M. A.; Bieberle-Hutter, A. Boosting the performance of WO3/n-Si heterostructures for photoelectrochemical water splitting: From the role of Si to interface engineering. Adv. Energy Mater. 2019, 9, 1900940.

    Article  Google Scholar 

  4. Kment, S.; Riboni, F.; Pausova, S.; Wang, L.; Wang, L. Y.; Han, H.; Hubicka, Z.; Krysa, J.; Schmuki, P.; Zboril, R. Photoanodes based on TiO2 and α-Fe2O3 for solar water splitting-superior role of 1D nanoarchitectures and of combined heterostructures. Chem. Soc. Rev. 2017, 46, 3716–3769.

    Article  CAS  Google Scholar 

  5. Linsebigler, A. L.; Lu, G. Q.; Yates, J. T. Jr. Photocatalysis on TiO2 surfaces: Principles, mechanisms, and selected results. Chem. Rev. 1995, 95, 735–758.

    Article  CAS  Google Scholar 

  6. Zhao, C. X.; Luo, H.; Chen, F.; Zhang, P.; Yi, L. H.; You, K. Y. A novel composite of TiO2 nanotubes with remarkably high efficiency for hydrogen production in solar-driven water splitting. Energy Environ. Sci. 2014, 7, 1700–1707.

    Article  CAS  Google Scholar 

  7. Ge, M. Z.; Li, Q. S.; Cao, C. Y.; Huang, J. Y.; Li, S. H.; Zhang, S. N.; Chen, Z.; Zhang, K. Q.; Al-Deyab, S. S.; Lai, Y. K. One-dimensional TiO2 nanotube photocatalysts for solar water splitting. Adv. Sci. 2017, 4, 1600152.

    Article  Google Scholar 

  8. Hendry, E.; Koeberg, M.; O’Regan, B.; Bonn, M. Local field effects on electron transport in nanostructured TiO2 revealed by terahertz spectroscopy. Nano Lett. 2006, 6, 755–759.

    Article  CAS  Google Scholar 

  9. Salvador, P. Hole diffusion length in n-TiO2 single crystals and sintered electrodes: Photoelectrochemical determination and comparative analysis. J. Appl. Phys. 1984, 55, 2977–2985.

    Article  CAS  Google Scholar 

  10. Chen, C. L.; Wei, Y. L.; Yuan, G. Z.; Liu, Q. L.; Lu, R. R.; Huang, X.; Cao, Y.; Zhu, P. H. Synergistic effect of Si doping and heat treatments enhances the photoelectrochemical water oxidation performance of TiO2 nanorod arrays. Adv. Funct. Mater. 2017, 27, 1701575.

    Article  Google Scholar 

  11. Yu, Z. R.; Liu, H. B.; Zhu, M. Y.; Li, Y.; Li, W. X. Interfacial charge transport in 1D TiO2 based photoelectrodes for photoelectrochemical water splitting. Small 2021, 17, 1903378.

    Article  CAS  Google Scholar 

  12. Li, H. M.; Wang, T.; Liu, S. S.; Luo, Z. B.; Li, L. L.; Wang, H. Y.; Zhao, Z. J.; Gong, J. L. Controllable distribution of oxygen vacancies in grain boundaries of p-Si/TiO2 heterojunction photocathodes for solar water splitting. Angew. Chem., Int. Ed. 2021, 60, 4034–4037.

    Article  CAS  Google Scholar 

  13. Gao, C. M.; Wei, T.; Zhang, Y. Y.; Song, X. H.; Huan, Y.; Liu, H.; Zhao, M. W.; Yu, J. H.; Chen, X. D. A photoresponsive rutile TiO2 heterojunction with enhanced electron-hole separation for high-performance hydrogen evolution. Adv. Mater. 2019, 31, 1806596.

    Article  Google Scholar 

  14. Cao, S.; Chan, T. S.; Lu, Y. R.; Shi, X. H.; Fu, B.; Wu, Z. J.; Li, H. M.; Liu, K.; Alzuabi, S.; Cheng, P. et al. Photocatalytic pure water splitting with high efficiency and value by Pt/porous brookite TiO2 nanoflutes. Nano Energy 2020, 67, 104287.

    Article  CAS  Google Scholar 

  15. Xu, Q. L.; Zhang, L. Y.; Yu, J. G.; Wageh, S.; Al-Ghamdi, A. A.; Jaroniec, M. Direct Z-scheme photocatalysts: Principles, synthesis, and applications. Mater. Today 2018, 21, 1042–1063.

    Article  CAS  Google Scholar 

  16. Low, J.; Jiang, C. J.; Cheng, B.; Wageh, S.; Al-Ghamdi, A. A.; Yu, J. G. A review of direct Z-scheme photocatalysts. Small Methods 2017, 1, 1700080.

    Article  Google Scholar 

  17. Che, H. B.; Xiao, L. Y.; Zhou, W. Y.; Zhou, Q. Q.; Li, H. Y.; Hu, P.; Wang, J. S.; Chen, X. B.; Wang, H. L. Decorating tungsten oxide on g-C3N4 nanosheet as Z-scheme heterogeneous photocatalyst for efficient hydrogen evolution. J. Alloys Compd. 2022, 896, 162931.

    Article  CAS  Google Scholar 

  18. Xie, M. Z.; Fu, X. D.; Jing, L. Q.; Luan, P.; Feng, Y. J.; Fu, H. G. Long-lived, visible-light-excited charge carriers of TiO2/BiVO4 nanocomposites and their unexpected photoactivity for water splitting. Adv. Energy Mater. 2014, 4, 1300995.

    Article  Google Scholar 

  19. Resasco, J.; Zhang, H.; Kornienko, N.; Becknell, N.; Lee, H.; Guo, J. H.; Briseno, A. L.; Yang, P. D. TiO2/BiVO4 nanowire heterostructure photoanodes based on type II band alignment. ACS Cent. Sci. 2016, 2, 80–88.

    Article  CAS  Google Scholar 

  20. Tian, Z. L.; Zhang, P. F.; Qin, P.; Sun, D.; Zhang, S. N.; Guo, X. W.; Zhao, W.; Zhao, D. Y.; Huang, F. Q. Novel black BiVO4/TiO2−x photoanode with enhanced photon absorption and charge separation for efficient and stable solar water splitting. Adv. Energy Mater. 2019, 9, 1901287.

    Article  Google Scholar 

  21. Yang, Y. L.; Wang, S. C.; Jiao, Y. L.; Wang, Z. L.; Xiao, M.; Du, A. J.; Li, Y. L.; Wang, J. S.; Wang, L. Z. An unusual red carbon nitride to boost the photoelectrochemical performance of wide bandgap photoanodes. Adv. Funct. Mater. 2018, 28, 1805698.

    Article  Google Scholar 

  22. Xiao, L. M.; Liu, T. F.; Zhang, M.; Li, Q. Y.; Yang, J. J. Interfacial construction of zero-dimensional/one-dimensional g-C3N4 nanoparticles/TiO2 nanotube arrays with Z-scheme heterostructure for improved photoelectrochemical water splitting. ACS Sustainable Chem. Eng. 2019, 7, 2483–2491.

    Article  CAS  Google Scholar 

  23. Ai, G. J.; Li, H. X.; Liu, S. P.; Mo, R.; Zhong, J. X. Solar water splitting by TiO2/CdS/Co-Pi nanowire array photoanode enhanced with Co-Pi as hole transfer relay and CdS as light absorber. Adv. Funct. Mater. 2015, 25, 5706–5713.

    Article  CAS  Google Scholar 

  24. Yoo, I. H.; Kalanur, S. S.; Seo, H. A nanoscale p−n junction photoelectrode consisting of an NiOx layer on a TiO2/CdS nanorod core-shell structure for highly efficient solar water splitting. Appl. Catal. B: Environ. 2019, 250, 200–212.

    Article  CAS  Google Scholar 

  25. Dhakshinamoorthy, A.; Asiri, A. M.; García, H. Metal-organic framework (MOF) compounds: Photocatalysts for redox reactions and solar fuel production. Angew. Chem., Int. Ed. 2016, 55, 5414–5445.

    Article  CAS  Google Scholar 

  26. Sheberla, D.; Bachman, J. C.; Elias, J. S.; Sun, C. J.; Shao-Horn, Y.; Dincă, M. Conductive MOF electrodes for stable supercapacitors with high areal capacitance. Nat. Mater. 2017, 16, 220–224.

    Article  CAS  Google Scholar 

  27. Jo, Y. K.; Jeong, S. Y.; Moon, Y. K.; Jo, Y. M.; Yoon, J. W.; Lee, J. H. Exclusive and ultrasensitive detection of formaldehyde at room temperature using a flexible and monolithic chemiresistive sensor. Nat. Commun. 2021, 12, 4955.

    Article  CAS  Google Scholar 

  28. Lin, Y. S. Molecular sieves for gas separation. Science 2016, 353, 121–122.

    Article  CAS  Google Scholar 

  29. Mukherjee, S.; Zaworotko, M. J. Crystal engineering of hybrid coordination networks: From form to function. Trends Chem. 2020, 2, 506–518.

    Article  CAS  Google Scholar 

  30. Jo, Y. M.; Lim, K.; Yoon, J. W.; Jo, Y. K.; Moon, Y. K.; Jang, H. W.; Lee, J. H. Visible-light-activated type II heterojunction in Cu3(hexahydroxytriphenylene)2/Fe2O3 hybrids for reversible NO2 sensing: Critical role of π−π* transition. ACS Cent. Sci. 2021, 7, 1176–1182.

    Article  CAS  Google Scholar 

  31. Yoon, J. W.; Kim, J. H.; Kim, C.; Jang, H. W.; Lee, J. MOF-based hybrids for solar fuel production. Adv. Energy Mater. 2021, 11, 2003052.

    Article  CAS  Google Scholar 

  32. Yang, H.; Bright, J.; Kasani, S.; Zheng, P.; Musho, T.; Chen, B. L.; Huang, L.; Wu, N. Q. Metal-organic framework coated titanium dioxide nanorod array p−n heterojunction photoanode for solar water-splitting. Nano Res. 2019, 12, 643–650.

    Article  CAS  Google Scholar 

  33. Yoon, J. W.; Kim, D. H.; Kim, J. H.; Jang, H. W.; Lee, J. H. NH2−MIL−125(Ti)/TiO2 nanorod heterojunction photoanodes for efficient photoelectrochemical water splitting. Appl. Catal. B: Environ. 2019, 244, 511–518.

    Article  CAS  Google Scholar 

  34. Zhang, W.; Li, R.; Zhao, X.; Chen, Z.; Law, A. W. K.; Zhou, K. A cobalt-based metal-organic framework as cocatalyst on BiVO4 photoanode for enhanced photoelectrochemical water oxidation. ChemSusChem 2018, 11, 2710–2716.

    Article  CAS  Google Scholar 

  35. Zhou, S. Q.; Yue, P. F.; Huang, J. W.; Wang, L.; She, H. D.; Wang, Q. Z. High-performance photoelectrochemical water splitting of BiVO4@Co-MIm prepared by a facile in-situ deposition method. Chem. Eng. J. 2019, 371, 885–892.

    Article  CAS  Google Scholar 

  36. Wang, H. L.; He, X.; Li, W. X.; Chen, H.; Fang, W.; Tian, P.; Xiao, F.; Zhao, L. Hematite nanorod arrays top-decorated with an MIL-101 layer for photoelectrochemical water oxidation. Chem. Commun. 2019, 55, 11382–11385.

    Article  CAS  Google Scholar 

  37. Li, Y.; Fu, Y. Q.; Ni, B. L.; Ding, K. N.; Chen, W. K.; Wu, K. C.; Huang, X.; Zhang, Y. F. Effects of ligand functionalization on the photocatalytic properties of titanium-based MOF: A density functional theory study. AIP Adv. 2018, 8, 035012.

    Article  Google Scholar 

  38. Musho, T.; Li, J. T.; Wu, N. Q. Band gap modulation of functionalized metal-organic frameworks. Phys. Chem. Chem. Phys. 2014, 16, 23646–23653.

    Article  CAS  Google Scholar 

  39. Grau-Crespo, R.; Aziz, A.; Collins, A. W.; Crespo-Otero, R.; Hernández, N. C.; Rodriguez-Albelo, L. M.; Ruiz-Salvador, A. R.; Calero, S.; Hamad, S. Modelling a linker mix-and-match approach for controlling the optical excitation gaps and band alignment of zeolitic imidazolate frameworks. Angew. Chem., Int. Ed. 2016, 55, 16012–16016.

    Article  CAS  Google Scholar 

  40. Aziz, A.; Ruiz-Salvador, A. R.; Hernández, N. C.; Calero, S.; Hamad, S.; Grau-Crespo, R. Porphyrin-based metal-organic frameworks for solar fuel synthesis photocatalysis: Band gap tuning via iron substitutions. J. Mater. Chem. A 2017, 5, 11894–11904.

    Article  CAS  Google Scholar 

  41. Botas, J. A.; Calleja, G.; Sánchez-Sánchez, M.; Orcajo, M. G. Effect of Zn/Co ratio in MOF-74 type materials containing exposed metal sites on their hydrogen adsorption behaviour and on their band gap energy. Int. J. Hydrog. Energy 2011, 36, 10834–10844.

    Article  CAS  Google Scholar 

  42. Nguyen, V. H.; Nguyen, T. D.; Bach, L. G.; Hoang, T.; Bui, Q. T. P.; Tran, L. D.; Nguyen, C. V.; Vo, D. V. N.; Do, S. T. Effective photocatalytic activity of mixed Ni/Fe-base metal-organic framework under a compact fluorescent daylight lamp. Catalysts 2018, 8, 487.

    Article  Google Scholar 

  43. Zhao, X. J.; Pachfule, P.; Li, S.; Simke, J. R. J.; Schmidt, J.; Thomas, A. Bifunctional electrocatalysts for overall water splitting from an iron/nickel-based bimetallic metal-organic framework/dicyandiamide composite. Angew. Chem., Int. Ed. 2018, 57, 8921–8926.

    Article  CAS  Google Scholar 

  44. Zhang, X.; Luo, J. S.; Wan, K.; Plessers, D.; Sels, B.; Song, J. X.; Chen, L. G.; Zhang, T.; Tang, P. Y.; Morante, J. R. et al. From rational design of a new bimetallic MOF family with tunable linkers to OER catalysts. J. Mater. Chem. A 2019, 7, 1616–1628.

    Article  CAS  Google Scholar 

  45. Shi, L.; Wang, T.; Zhang, H. B.; Chang, K.; Meng, X. G.; Liu, H. M.; Ye, J. H. An amine-functionalized iron(III) metal-organic framework as efficient visible-light photocatalyst for Cr(VI) reduction. Adv. Sci. 2015, 2, 1500006.

    Article  Google Scholar 

  46. Zango, Z. U.; Jumbri, K.; Sambudi, N. S.; Bakar, N. H. H. A.; Abdullah, N. A. F.; Basheer, C.; Saad, B. Removal of anthracene in water by MIL-88(Fe), NH2-MIL-88(Fe), and mixed-MIL-88(Fe) metal-organic frameworks. RSC Adv. 2019, 9, 41490–41501.

    Article  CAS  Google Scholar 

  47. Xiao, F. X.; Hung, S. F.; Miao, J. W.; Wang, H. Y.; Yang, H. B.; Liu, B. Metal-cluster-decorated TiO2 nanotube arrays: A composite heterostructure toward versatile photocatalytic and photoelectrochemical applications. Small 2015, 11, 554–567.

    Article  CAS  Google Scholar 

  48. Gu, Q.; Gao, Z. W.; Yu, S. J.; Xue, C. Constructing Ru/TiO2 heteronanostructures toward enhanced photocatalytic water splitting via a RuO2/TiO2 heterojunction and Ru/TiO2 schottky junction. Adv. Mater. Interfaces 2016, 3, 1500631.

    Article  Google Scholar 

  49. Zheng, F. Q.; Xiang, D.; Li, P.; Zhang, Z. W.; Du, C.; Zhuang, Z. H.; Li, X. K.; Chen, W. Highly conductive bimetallic Ni-Fe metal organic framework as a novel electrocatalyst for water oxidation. ACS Sustainable Chem. Eng. 2019, 7, 9743–9749.

    Article  CAS  Google Scholar 

  50. Zhang, Y. Q.; Wang, J. L.; Ye, L.; Zhang, M. L.; Gong, Y. Q. In situ assembly of bimetallic MOF composites on IF as efficient electrocatalysts for the oxygen evolution reaction. Dalton Trans 2021, 50, 4720–4726.

    Article  CAS  Google Scholar 

  51. Zheng, F. Q.; Zhang, Z. W.; Xiang, D.; Li, P.; Du, C.; Zhuang, Z. H.; Li, X. K.; Chen, W. Fe/Ni bimetal organic framework as efficient oxygen evolution catalyst with low overpotential. J. Colloid Interface Sci. 2019, 555, 541–547.

    Article  CAS  Google Scholar 

  52. Zhang, Z.; Yates, J. T. Jr. Band bending in semiconductors: Chemical and physical consequences at surfaces and interfaces. Chem. Rev. 2012, 112, 5520–5551.

    Article  CAS  Google Scholar 

  53. Selinsky, R. S.; Ding, Q.; Faber, M. S.; Wright, J. C.; Jin, S. Quantum dot nanoscale heterostructures for solar energy conversion. Chem. Soc. Rev. 2013, 42, 2963–2985.

    Article  CAS  Google Scholar 

  54. Dotan, H.; Sivula, K.; Grätzel, M.; Rothschild, A.; Warren, S. C. Probing the photoelectrochemical properties of hematite (α-Fe2O3) electrodes using hydrogen peroxide as a hole scavenger. Energy Environ. Sci. 2011, 4, 958–964.

    Article  CAS  Google Scholar 

  55. Zhong, D. K.; Choi, S.; Gamelin, D. R. Near-complete suppression of surface recombination in solar photoelectrolysis by “Co-Pi” catalyst-modified W: BiVO4. J. Am. Chem. Soc. 2011, 133, 18370–18377.

    Article  CAS  Google Scholar 

  56. Rao, P. M.; Cai, L. L.; Liu, C.; Cho, I. S.; Lee, C. H.; Weisse, J. M.; Yang, P. D.; Zheng, X. L. Simultaneously efficient light absorption and charge separation in WO3/BiVO4 core/shell nanowire photoanode for photoelectrochemical water oxidation. Nano Lett. 2014, 14, 1099–1105.

    Article  CAS  Google Scholar 

  57. Zhou, L. T.; Zhao, C. Q.; Giri, B.; Allen, P.; Xu, X. W.; Joshi, H.; Fan, Y. Y.; Titova, L. V.; Rao, P. M. High light absorption and charge separation efficiency at low applied voltage from Sb-doped SnO2/BiVO4 core/shell nanorod-array photoanodes. Nano Lett. 2016, 16, 3463–3474.

    Article  CAS  Google Scholar 

  58. Louie, M. W.; Bell, A. T. An investigation of thin-film Ni-Fe oxide catalysts for the electrochemical evolution of oxygen. J. Am. Chem. Soc. 2013, 135, 12329–12337.

    Article  CAS  Google Scholar 

  59. Hai, G. T.; Jia, X. L.; Zhang, K. Y.; Liu, X.; Wu, Z. Y.; Wang, G. High-performance oxygen evolution catalyst using two-dimensional ultrathin metal-organic frameworks nanosheets. Nano Energy 2018, 44, 345–352.

    Article  CAS  Google Scholar 

  60. Huo, J. M.; Wang, Y.; Yan, L. T.; Xue, Y. Y.; Li, S. N.; Hu, M. C.; Jiang, Y. C.; Zhai, Q. G. In situ semi-transformation from heterometallic MOFs to Fe−Ni LDH/MOF hierarchical architectures for boosted oxygen evolution reaction. Nanoscale 2020, 12, 14514–14523.

    Article  CAS  Google Scholar 

  61. Trotochaud, L.; Young, S. L.; Ranney, J. K.; Boettcher, S. W. Nickel-iron oxyhydroxide oxygen-evolution electrocatalysts: The role of intentional and incidental iron incorporation. J. Am. Chem. Soc. 2014, 136, 6744–6753.

    Article  CAS  Google Scholar 

  62. Friebel, D.; Louie, M. W.; Bajdich, M.; Sanwald, K. E.; Cai, Y.; Wise, A. M.; Cheng, M. J.; Sokaras, D.; Weng, T. C.; Alonso-Mori, R. et al. Identification of highly active Fe sites in (Ni, Fe)OOH for electrocatalytic water splitting. J. Am. Chem. Soc. 2015, 137, 1305–1313.

    Article  CAS  Google Scholar 

  63. Li, J.; Li, F.; Jin, J. Hole extraction and injection pathways constructed by the in situ growth of ultra-thin Fe-doped NiOOH co-catalysts on a fluorine-doped α-Fe2O3 photoanode. J. Power Sources 2021, 482, 228957.

    Article  CAS  Google Scholar 

  64. Sun, B.; Shi, T. L.; Peng, Z. C.; Sheng, W. J.; Jiang, T.; Liao, G. L. Controlled fabrication of Sn/TiO2 nanorods for photoelectrochemical water splitting. Nanoscale Res. Lett. 2013, 8, 462.

    Article  Google Scholar 

  65. Liu, Y. K.; Jiang, S.; Li, S. J.; Zhou, L.; Li, Z. H.; Li, J. M.; Shao, M. F. Interface engineering of (Ni, Fe)S2@MoS2 heterostructures for synergetic electrochemical water splitting. Appl. Catal. B: Environ. 2019, 247, 107–114.

    Article  CAS  Google Scholar 

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Acknowledgements

This work was supported by a grant from the Korea Environmental Industry & Technology Institute (No. 2020002700011).

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  1. Department of Materials Science and Engineering, Korea University, Seoul, 02841, Republic of Korea

    Ji Won Yoon, Jae-Hyeok Kim, Young-Moo Jo & Jong-Heun Lee

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Heterojunction between bimetallic metal-organic framework and TiO2: Band-structure engineering for effective photoelectro-chemical water splitting

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Yoon, J.W., Kim, JH., Jo, YM. et al. Heterojunction between bimetallic metal-organic framework and TiO2: Band-structure engineering for effective photoelectrochemical water splitting. Nano Res. 15, 8502–8509 (2022). https://doi.org/10.1007/s12274-022-4451-y

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