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Highly active zigzag-like Pt-Zn alloy nanowires with high-index facets for alcohol electrooxidation

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A Publisher's Erratum to this article was published on 05 July 2019

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Abstract

The development of highly efficient Pt-based alloy nanocatalysts is important but remains challenging for fuel cells commercialization. Here, a new class of zigzag-like platinum-zinc (Pt-Zn) alloy nanowires (NWs) with rough surface and controllable composition is reported. The merits of anisotropic one-dimensional nanostructure, stable high-index facets and coordinatively unsaturated Pt sites endow the composition-optimal Pt94Zn6 NWs with a mass activity of 7.2 and 6.2 times higher than that of commercial Pt black catalysts toward methanol/ethanol oxidation, respectively. Alloying-induced d-band electron modulation and lattice strain effects weaken the adsorption strength of poisoning species, which originally enhances the catalytic activity of Pt-Zn NWs. This study provides a new perspective of Pt-Zn electrocatalysts with intrinsic mechanism for enhanced catalytic performance.

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Change history

  • 05 July 2019

    The article Highly active zigzag-like Pt-Zn alloy nanowires with high-index facets for alcohol electrooxidation, written by Xiaoqiang Cui and Weitao Zheng, was erroneously originally published electronically on the publisher’s internet portal (currently SpringerLink) on 6 April 2019 with incomplete Electronic Supplementary Material (ESM), which should contain 16 figures and 3 tables. You will find the complete supplementary material file online linked to this publisher’s erratum. The publisher apologizes to the authors and readers for this mistake.

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Acknowledgements

This work was supported by the National Key Research and Development Program of China (No. 2016YFA0200400), the National Natural Science Foundation of China (Nos. 51571100, 51602305, 51522212, 51421002, and 51672307), Program for JLU Science and Technology Innovative Research Team (JLUSTIRT, 2017TD-09), the Fundamental Research Funds for the Central Universities and the Graduate Innovation Fund of Jilin University.

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Authors and Affiliations

  1. State Key Laboratory of Automotive Simulation and Control, School of Materials Science and Engineering, Key Laboratory of Automobile Materials of MOE and Jilin University, Changchun, 130012, China

    Yanchao Xu, Xiaoqiang Cui, Shuting Wei, Jinchang Fan & Weitao Zheng

  2. Laboratory of Advanced Materials and Electron Microscopy, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing, 100190, China

    Qinghua Zhang, Lin Gu & Fanqi Meng

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  1. Yanchao Xu
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  2. Xiaoqiang Cui
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  3. Shuting Wei
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  4. Qinghua Zhang
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  5. Lin Gu
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  7. Jinchang Fan
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Correspondence to Xiaoqiang Cui or Weitao Zheng.

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Xu, Y., Cui, X., Wei, S. et al. Highly active zigzag-like Pt-Zn alloy nanowires with high-index facets for alcohol electrooxidation. Nano Res. 12, 1173–1179 (2019). https://doi.org/10.1007/s12274-019-2374-z

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