Abstract
Mechanically enhanced Poly(lactic acid) (PLA)/Polybutylene adipate terephthalate (PBAT)/nano filler composite film was prepared by melt blending. Halloysite nanotubes (HNTs) and modified montmorillonites (oMMTs) were used as filler, separately or simultaneously. The improvement of the miscibility between PLA and PBAT by the help of oMMTs was observed using cross-sectional SEM images and rheological analysis. The mechanical properties of the composite films were studied with DMA and UTM. The bi-fillered composite film displayed the improvement in the modulus and the tensile strength by the interconnected network of HNTs and oMMTs. The PLA/PBAT/bi-filler film shows a prospective vision for the biodegradable packaging area.
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References
J. Lunt, Polym. Degrad. Stabil., 59, 145 (1998).
M. Jamshidian, E. A. Tehrany, M. Imran, M. Jacquot, and S. Desobry, Comprehensive Reviews in Food Science and Food Safety, 9, 552 (2010).
X. Tang, P. Kumar, S. Alavi, and K. Sandeep, Crit. Rev. Food Sci. Nutr., 52, 426 (2012).
V. Siracusa, P. Rocculi, S. Romani, and M. Dalla Rosa, Trends in Food Sci. Technol., 19, 634 (2008).
S. Tajik, Y. Maghsoudlou, F. Khodaiyan, S. M. Jafari, M. Ghasemlou, and M. Aalami, Carbohydr. Polym., 97, 817 (2013).
X. Li, X. Ai, H. Pan, J. Yang, G. Gao, H. Zhang, H. Yang, and L. Dong, Polym. Adv. Technol., 29, 1706 (2018).
F. Feng and L. Ye, J. Appl. Polym. Sci., 119, 2778 (2011).
H. U. Zaman, J. C. Song, L.-S. Park, I.-K. Kang, S.-Y. Park, G. Kwak, B.-S. Park, and K.-B. Yoon, Polym. Bull., 67, 187 (2011).
J. Ishihara, M. Harada, K. Nakano, and K. Enomoto, AIP Conference Proceedings, 1779, 080002 (2016).
N. Tenn, N. G. Follain, J. R. M. Soulestin, R. L. Crétois, S. Bourbigot, and S. P. Marais, J. Phys. Chem. C, 117, 12117 (2013).
W. L. Tham, W. S. Chow, B. T. Poh, and Z. A. Mohd Ishak, J. Compos. Mater., 50, 3925 (2016).
E. Garofalo, P. Scarfato, L. Di Maio, and L. Incarnato, AIP Conference Proceedings, 1599, 422 (2014).
J.-W. Rhim, S.-I. Hong, and C.-S. Ha, LWT-Food Sci. Technol., 42, 612 (2009).
W. Chow and S. Lok, J. Therm. Anal. Calorim., 95, 627 (2009).
Y. Dong, J. Marshall, H. J. Haroosh, S. Mohammadzadehmoghadam, D. Liu, X. Qi, and K.-T. Lau, Compos. Part A-Appl. Sci. Manuf., 76, 28 (2015).
F. Uddin, Metall. Mater. Trans. A, 39, 2804 (2008).
M. Du, B. Guo, and D. Jia, Polym. Int., 59, 574 (2010).
Y. Kim, Y. Song, and H. Kim, Cellulose, 25, 1239 (2018).
R. Polanský, P. Kadlec, Z. Kolská, and V. Švorčík, Appl. Clay Sci., 147, 19 (2017).
Z. Z. Yu, M. Yang, Q. Zhang, C. Zhao, and Y. W. Mai, J. Polym. Sci. Part B: Polym. Phys., 41, 1234 (2003).
G. Gorrasi, M. Tortora, V. Vittoria, E. Pollet, B. Lepoittevin, M. Alexandre, and P. Dubois, Polymer, 44, 2271 (2003).
S. Ko, M. Hong, B. Park, R. Gupta, H. Choi, and S. Bhattacharya, Polym. Bull., 63, 125 (2009).
F. Signori, M.-B. Coltelli, and S. Bronco, Polym. Degrad. Stabil., 94, 74 (2009).
H. He, B. Liu, B. Xue, and H. Zhang, J. Thermoplast. Compos. Mater., doi: https://doi.org/10.1177/0892705719890907 (2019).
R. Salehiyan and K. Hyun, Korean J. Chem. Eng., 30, 1013 (2013).
H.-T. Chiu, S.-Y. Huang, Y.-F. Chen, M.-T. Kuo, T.-Y. Chiang, C.-Y. Chang, and Y.-H. Wang, Int. J. Polym. Sci., 2013, 951696 (2013).
N. Bumbudsanpharoke, W. Lee, J. C. Choi, S.-J. Park, M. Kim, and S. Ko, Clays and Clay Minerals, 65, 387 (2017).
A. Carbonell-Verdu, J. Ferri, F. Dominici, T. Boronat, L. Sanchez-Nacher, R. Balart, and L. Torre, Exp. Polym. Lett., 12, 808 (2018).
N. T. Kilic, B. N. Can, M. Kodal, and G. Ozkoc, J. Appl. Polym. Sci., 136, 47217 (2019).
M. J. Osman, N. A. Ibrahim, and W. M. Z. W. Yunus, Oriental J. Chem., 33, 3015 (2017).
Y. Yuan and T. R. Lee, “Surface Science Techniques”, p.3, Springer, 2013.
M. J. Saif, H. M. Asif, and M. Naveed, J. Chilean Chem. Soc., 63, 4109 (2018).
Acknowledgement
This research was supported by the National Research Foundation of Korea (NRF) Grant funded by the Ministry of Science and ICT for First-Mover Program for Accelerating Disruptive Technology Development (NRF-2018M3C1B9069748) and Korea Institute for Advancement of Technology (KIAT) grant funded by the Korea government (MOTIE) (P0012770).
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Ko, E., Kim, T., Ahn, J. et al. Synergic Effect of HNT/oMMT Bi-filler System for the Mechanical Enhancement of PLA/PBAT Film. Fibers Polym 22, 2163–2169 (2021). https://doi.org/10.1007/s12221-021-1006-x
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DOI: https://doi.org/10.1007/s12221-021-1006-x