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Preparation of Acryloyl β-Cyclodextrin Organic Polymer Monolithic Column and Its Application in Solid-Phase Microextraction and HPLC Analysis for Carbofuran and Carbaryl in Rice

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Abstract

An acryloyl β-cyclodextrin (A-β-CD) monolithic column for solid-phase microextraction (SPME) and determination of carbofuran and carbaryl by high-performance liquid chromatography (HPLC) have been prepared through a “one-step” polymerization method. The synthesis conditions, including the volume of cross-linker, the ratio and volume of mixed porogenic solvent consisted of methanol and N,N-dimethylformamide were optimized. The prepared monolithic column was characterized by thermogravimeteric analysis (TGA), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), and Brunner-Emmet-Teller (BET) measurement. The eluent type, volume and flow rate, sample volume, flow rate, acidity, and ionic strength were optimized in detail. Under the optimized conditions, a simple, rapid, and sensitive SPME-HPLC method was developed for determination of carbofuran and carbaryl in rice samples. The method yielded a linear calibration curve in the concentration ranges of 1.5–200 μg/kg for carbofuran and 0.3–200 μg/kg for carbaryl with correlation coefficients (R 2) of above 0.9955. Limits of detection (S/N = 3) were 0.5 μg/kg for carbofuran and 0.1 μg/kg for carbaryl, respectively. The recoveries of this method ranged from 88.1 to 105.8%. The relative standard deviations were less than 8.1%.

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Acknowledgements

This work was supported by the Education Commission of Hubei Province of China (grant no. T201101, D20120106) and the Open Fund of Ministry-of-Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules (2013-KL-007). The authors would like to thank their colleagues for their valuable technical assistance.

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Authors and Affiliations

  1. Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Ministry-of-Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules and College of Chemistry and Chemical Engineering, Hubei University, Wuhan, 430062, China

    Bin Sun, Chunpeng Wang, Qi Wang, Ling Chen, Xueping Dang, Jianlin Huang & Huaixia Chen

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  1. Bin Sun
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  2. Chunpeng Wang
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  3. Qi Wang
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  4. Ling Chen
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  5. Xueping Dang
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  6. Jianlin Huang
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  7. Huaixia Chen
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Correspondence to Huaixia Chen.

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Conflict of Interest

Author Bin Sun declares that he has no conflict of interest. Author Chunpeng Wang declares that she has no conflict of interest. Author Qi Wang declares that she has no conflict of interest. Author Ling Chen declares that she has no conflict of interest. Author Xueping Dang declares that she has no conflict of interest. Author Jianlin Huang declares that she has no conflict of interest. Author Huaixia Chen declares that she has no conflict of interest.

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Sun, B., Wang, C., Wang, Q. et al. Preparation of Acryloyl β-Cyclodextrin Organic Polymer Monolithic Column and Its Application in Solid-Phase Microextraction and HPLC Analysis for Carbofuran and Carbaryl in Rice. Food Anal. Methods 10, 3847–3855 (2017). https://doi.org/10.1007/s12161-017-0931-1

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  • DOI: https://doi.org/10.1007/s12161-017-0931-1

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