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Novel partially bio-based fluorinated polyimides from dimer fatty diamine for UV-cured coating

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Abstract

A series of novel partially bio-based fluorinated polyimides with double-bond end groups (BGPIs) from 4,4′-(hexafluoroisopropylidene) diphthalic anhydride, 4,4′-(hexafluoroisopropylidene) dianiline, Priamine 1074, 4-aminobenzoic acid, and glycidyl methacrylate were synthesized via a copolycondensation method in m-cresol. The chemical structure and performances of BGPIs were fully characterized by Fourier transform infrared spectroscopy, proton nuclear magnetic resonance, gel permeation chromatography, solubility test, X-ray diffraction, and differential scanning calorimetry. It was determined that the prepared BGPIs were in the amorphous phase and readily soluble in conventional aprotic polar solvents. Additionally, the properties of as-prepared UV-cured coatings based on BGPIs were also evaluated by real-time Fourier transform infrared, thermogravimetric analysis, UV–Vis spectroscopy, and so on. Results revealed that all coatings exhibited satisfactory curing, higher adhesion, lower water uptakes, outstanding optical transparency, and fairly favorable thermal stability under a high content of biomass up to 48.9%. Therefore, these bio-based polymers could be considered as a potential sustainable candidate for high-temperature UV-curable coatings in the microelectronic field.

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (No. 51403082), the National Nature Science Foundation of Jiangsu Province (No. BK20140160), Innovation Foundation of Jiangsu (No.BY2015019-14), and the Fundamental Research Funds for the Central Universities (JUSRP11514).

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Authors and Affiliations

  1. The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi, 214122, People’s Republic of China

    Jingcheng Liu, Kuan Wang, Yazhen Xie, Fei Gao, Qingtao Zeng, Yan Yuan, Ren Liu & Xiaoya Liu

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  1. Jingcheng Liu
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  2. Kuan Wang
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  3. Yazhen Xie
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  4. Fei Gao
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  5. Qingtao Zeng
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  6. Yan Yuan
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  7. Ren Liu
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  8. Xiaoya Liu
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Correspondence to Jingcheng Liu.

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Liu, J., Wang, K., Xie, Y. et al. Novel partially bio-based fluorinated polyimides from dimer fatty diamine for UV-cured coating. J Coat Technol Res 14, 1325–1334 (2017). https://doi.org/10.1007/s11998-017-9931-8

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