Skip to main content
SpringerLink
Log in

Crystal and Electronic Structure of (Y,Pr) x Sm1−x BO3 Oxide

  • Published:
Journal of Electronic Materials Aims and scope Submit manuscript

Abstract

The effects of Y and Pr substitution on the electronic and crystal structure of triclinic SmBO3 have been investigated using x-ray diffraction (XRD) analysis and x-ray absorption fine-structure spectroscopy. Polycrystalline structure was observed on substitution of Y3+ and Pr4+ ions with Sm3+ coordination. Yttrium-substituted samples were found to contain BO3 ligands around Sm atoms, while the crystal structure of YBO3 presented hexagonal geometry, not preserving the triclinic crystal structure. Also, praseodymium ions (Pr4+) formed isolated Pr2B5 crystal structure by distorting some BO3 ligands. Moreover, electronic structure studies revealed that 4f levels of Sm and Pr were inactive in bonding interaction and did not support strong coupling between neighboring Sm and Y/Pr atoms.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. P. Han and X. Jiang, Adv. Powder Technol. 26, 977 (2015).

    Article  Google Scholar 

  2. J. Lin, D. Sheptyakov, and Y. Wang, Chem. Mater. 16, 2418 (2004).

    Article  Google Scholar 

  3. H. Emme and H. Huppertz, Chem. Eur. J. 9, 3623 (2003).

    Article  Google Scholar 

  4. J. Su and J. Zhang, J. Elastom. Plast. 46, 368 (2014).

    Article  Google Scholar 

  5. J. Su, S.J. Chen, and J. Zhang, Plast. Rubber Compos. 42, 75 (2013).

    Article  Google Scholar 

  6. J. Su, S.J. Chen, and J. Zhang, J. Compos. Mater. 46, 589 (2012).

    Article  Google Scholar 

  7. J. Su, S.J. Chen, and J. Zhang, J. Appl. Polym. Sci. 122, 3277 (2011).

    Article  Google Scholar 

  8. R.L. Cohen and K.W. West, Phys. Rev. Lett. 23, 383 (1970).

    Article  Google Scholar 

  9. A. Yanase and H. Harima, Prog. Theor. Phys. Suppl. 108, 19 (1992).

    Article  Google Scholar 

  10. Y.W. Liu, X.F. Rui, Y.Y. Fu, and Y.W. Han Zhang, J. Metastable Nanocryst. Mater. 23, 24 (2005).

    Google Scholar 

  11. R.P. Santoro, R.E. Newnham, and M.J. Redman, J. Am. Ceram. Soc. 46, 253 (1963).

    Article  Google Scholar 

  12. V.G. Kuznetsova, B.F. Dzhurinskii, K.K. Palkina, and L.A. Butman, Koordinatsionnaya Khimiya (=Coord. Chem. (USSR)) 2, 286 (1976).

    Google Scholar 

  13. P. Becker, Adv. Mater. 10, 979 (1998).

    Article  Google Scholar 

  14. Z. Li, J. Zeng, and Y. Li, Small 3, 438 (2007).

    Article  Google Scholar 

  15. N. Akçamlı, D. Ağaoğulları, Ö. Balcı, M.L. Öveçoğlu, and İ. Duman, Ceram. Int. 42, 10045 (2016).

    Article  Google Scholar 

  16. H.O. Abd-Alkader and N.M. Dearz, Int. J. Electrochem. Sci. 8, 8614 (2013).

    Google Scholar 

  17. L. Lutterotti, D. Chateigner, S. Ferrari, and J. Ricote, Thin Solid Films 450, 34 (2004).

    Article  Google Scholar 

  18. A.L. Ankudinov, B. Ravel, J.J. Rehr, and S.D. Conradson, Phys. Rev. B 56, R1712 (1997).

    Article  Google Scholar 

  19. B. Ravel, J. Synchrotron Radiat. 8, 314 (2001).

    Article  Google Scholar 

  20. B. Ravel and M. Newville, J. Synchrotron Radiat. 12, 537 (2005).

    Article  Google Scholar 

Download references

Acknowledgements

The authors would like to thank Dr. Prae Chirawatkul and the staff of SLRI (Siam Photon) for both their support and great hospitality.

Author information

Authors and Affiliations

  1. Faculty of Technology, Energy Systems Engineering, Mersin University, 33400, Tarsus, Turkey

    Osman Murat Ozkendir

  2. Faculty of Engineering, Hakkari University, 30000, Hakkari, Turkey

    H. Gundogmus

  3. Synchrotron Light Research Institute (Public Organization), P.O. Box 93, Nakhon Ratchasima, 30000, Thailand

    Chatree Saiyasombat

Authors
  1. Osman Murat Ozkendir
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. H. Gundogmus
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Chatree Saiyasombat
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Osman Murat Ozkendir.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ozkendir, O.M., Gundogmus, H. & Saiyasombat, C. Crystal and Electronic Structure of (Y,Pr) x Sm1−x BO3 Oxide. J. Electron. Mater. 47, 2050–2056 (2018). https://doi.org/10.1007/s11664-017-6010-y

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11664-017-6010-y

Keywords

Search

Navigation