Abstract
Fused CaF2-SiO2-CaO-TiO2 fluxes are designed and applied to join EH36 shipbuilding steel under high heat input submerged arc welding. Pertinent elemental transfer behaviors of major alloying elements are quantified and possible chemical reactions have been postulated. It is found that transfer of Si and O is enhanced by increasing TiO2 addition, although that of Si is concurrently dependent on SiO2 activity. Furthermore, a unique neutral point is identified with regard to Ti transfer.
References
S.R. Nathan, V. Balasubramanian, S. Malarvizhi, and A.G. Rao: Int. J. Refract Metal Hard Mater., 2016, vol. 56, pp. 18–26.
D.W. Cho, D.V. Kiran, and S.J. Na: Int. J. Heat Mass Transfer., 2017, vol. 110, pp. 104–12.
C. Wang and J. Zhang: Acta Metall. Sin., 2021, vol. 57, pp. 1126–40.
C.A. Natalie and D.L. Olson: Ann. Rev. Mater. Sci., 1986, vol. 16, pp. 389–413.
Y. Zhang, T. Coetsee, H. Yang, T. Zhao, and C. Wang: Metall. Mater. Trans. B., 2020, vol. 51B, pp. 1947–52.
J. Zhang, C. Wang, and T. Coetsee: Metall. Mater. Trans. B., 2021, vol. 52B, pp. 1937–44.
C.B. Dallam, S. Liu, and D.L. Olson: Weld. J., 1985, vol. 64, pp. 140–51.
J. Zhang, J. Leng, and C. Wang: Metall. Mater. Trans. B., 2019, vol. 50B, pp. 2083–87.
J. Zhang, T. Coetsee, H.B. Dong, and C. Wang: Metall. Mater. Trans. B., 2020, vol. 51B, pp. 1350–54.
T. Lienert, T. Siewert, S. Basu, and V. Acoff: ASM handbook, Volume 6A: welding fundamentals and processes, ASM International, Materials Park, 2011, pp. 55–63.
L.H.S. Barbosa, P.J. Modenesi, L.B. Godefroid, and A.R. Arias: Int. J. Fatigue., 2019, vol. 119, pp. 43–51.
A.M. Paniagua-Mercado, V.M. Lopez-Hirata, H.J. Dorantes-Rosales, P.E. Diaz, and E.D. Valdez: Mater. Charact., 2009, vol. 60, pp. 36–39.
L. Lan, X. Kong, C. Qiu, and D. Zhao: Mater. Des., 2016, vol. 90, pp. 488–98.
Z. Wu, W. Zheng, G. Li, H. Matsuura, and F. Tsukihashi: Metall. Mater. Trans. B., 2015, vol. 46B, pp. 1226–41.
J. Zhang, T. Coetsee, H.B. Dong, and C. Wang: Metall. Mater. Trans. B., 2020, vol. 51B, pp. 1953–57.
J. Zhang, T. Coetsee, and C. Wang: Metall. Mater. Trans. B., 2020, vol. 51B, pp. 16–21.
S. Kou: Welding metallurgy, 2nd ed. Wiley, New Jersey, 2002, pp. 65–96.
C. Chai and T. Eagar: Weld. J., 1982, vol. 61, pp. 229–32.
U. Mitra and T.W. Eager: Metall. Trans. B., 1991, vol. 22B, pp. 83–110.
U. Mitra and T.W. Eager: Metall. Trans. B., 1991, vol. 22B, pp. 73–82.
C.S. Chai and T.W. Eager: Metall. Trans. B., 1981, vol. 12B, pp. 539–47.
J.E. Indacochea, M. Blander, N. Christensen, and D.L. Olson: Metall. Trans. B., 1985, vol. 16B, pp. 237–45.
J. Zhang, T. Coetsee, H.B. Dong, and C. Wang: Metall. Mater. Trans. B., 2020, vol. 51B, pp. 885–90.
R. Kohno, T. Takami, N. Mori, and K. Nagano: Weld. J., 1982, vol. 1982, pp. 373–81.
B. Singh, Z.A. Khan, A.N. Siddiquee, and S. Maheshwari: J. Alloys Compd., 2016, vol. 667, pp. 158–69.
U. Mitra and T.W. Eagar: Metall. Trans. B., 1991, vol. 22B, pp. 65–72.
G. Deyev and D. Deyev: Surface phenomena in fusion welding processes, 1st ed. CRC Press, Boca Raton, 2005, pp. 21–47.
K.S. Bang, C. Park, H.C. Jung, and J.B. Lee: Met. Mater. Int., 2009, vol. 15, pp. 471–77.
C.S. Chai and T.W. Eagar: Weld. J., 1980, vol. 59, pp. 93–98.
P. Kanjilal, T. Pal, and S. Majumdar: J. Mater. Process. Technol., 2006, vol. 171, pp. 223–31.
Z. Jiang, H. Li, Z. Chen, Z. Huang, D. Zou, and L. Liang: Steel Res. Int., 2005, vol. 76, pp. 740–45.
A. Polar, J.E. Indacochea, and M. Blander: Weld. J., 1990, vol. 1990, pp. 68–74.
T. Lau, G.C. Weatherly, and A.M. Lean: Weld. J., 1985, vol. 1985, pp. 343–49.
T. Coetsee, R. Mostert, P. Pistorius, and P. Pistorius: J. Mater. Res. Technol., 2021, vol. 11, pp. 2021–36.
U. Mitra and T.W. Eager: Metall. Trans. A., 1984, vol. 15A, pp. 217–27.
I. Madariaga and I. Gutierrez: Acta Mater., 1999, vol. 47, pp. 951–60.
E. Baune, C. Bonnet, and S. Liu: Weld. J., 2000, vol. 79, pp. 66–71.
J. Pu, S. Yu, and Y. Li: J. Mater. Process. Technol., 2017, vol. 240, pp. 145–53.
Acknowledgments
The authors sincerely thank the National Natural Science Foundation of China (Grant Nos., U20A20277, 52104295, 52011530180, and 52050410341), Royal Academy of Engineering (TSPC1070), Research Fund for Central Universities (Grant Nos. N2125003, N2025025), Regional Innovation Joint Fund of Liaoning Province (2020-YKLH-39), and the Open Foundation of State Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing (Grant No. KF21-02).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
On behalf of all authors, the corresponding author states that there is no conflict of interest.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Zhang, Y., Zhang, J., Liu, H. et al. Addressing Weld Metal Compositional Variations in EH36 Shipbuilding Steel Processed by CaF2-SiO2-CaO-TiO2 Fluxes. Metall Mater Trans B 53, 1329–1334 (2022). https://doi.org/10.1007/s11663-022-02480-y
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11663-022-02480-y