Skip to main content
SpringerLink
Log in

Impedance spectroscopy of cell with Pt electrodes on oxygen-conducting material with mayenite-related structure

  • Original Paper
  • Published:
Ionics Aims and scope Submit manuscript

Abstract

Ceramic Ca11.93(Al13.53V0.07)O33-x was investigated by impedance spectroscopy using two- and four-probe configurations. Cells with non-impregnated and Pr-impregnated Pt electrodes were studied. Properties of both the ceramic and electrode O2,Pt/O2− systems were distinguished. The existence of a surface layer is proposed as an explanation of the discrepancy between the reported conductivity data of single crystal mayenite as measured by four- and two-probe techniques.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11

Similar content being viewed by others

References

  1. Chebotin V.N., Perfil’ev M.V. (1978; 1984) Elektrokhimiya tverdykh elektrolitov (Electrochemistry of solid electrolytes). Khimiya, Moscow; Republished by Washington: Technical Information Center, U.S. Department of Energy

  2. Balkanski M, Takahashi T, Tuller HL (1992) Solid state ionics. Elsevier, Amsterdam

    Google Scholar 

  3. Tressaud A. (ed) (2010) Chichester functionalized inorganic fluorides: synthesis, characterization and properties of nanostructured solids. John Wiley & Sons

  4. Nakamuro A, Mizusaki J (2015) New research trends of fluorite-based oxide materials. Nova publishers, New York

    Google Scholar 

  5. Ishihara T (2009) Perovskite oxide for solid oxide fuel cells. Springer, Berlin

    Book  Google Scholar 

  6. Granger P, Parvulescu V, Kaliaguine S, Prellier W (2016) Perovskites and related mixed oxides: concepts and applications. Wiley-VCH, Weinheim

    Book  Google Scholar 

  7. Koshurnikova EV, Kalinina LA, Ushakova YN, P’yankova MV, Murin IV (2013) Synthesis, structure, and physico-chemical properties of sulfide ceramics CaY2S4–Yb2S3. Russ J Electrochem 49(8):769–775

    Article  CAS  Google Scholar 

  8. Ananchenko BA, Kalinina LA, Ushakova Yu N, Koshurnikova EV (2013) Electrolytic properties and stability of solid solutions of ytterbium sulfide in calcium thioytterbate. Russ J Electrochem 49(8):763–768

    Article  CAS  Google Scholar 

  9. Boysen H, Lerch M, Stys A, Senyshyn A (2007) Structure and oxygen mobility in mayenite (Ca12Al14O33): a high-temperature neutron powder diffraction study. Acta Cryst B63:675–682

    Article  Google Scholar 

  10. Hosono H, Abe Y (1987) Occurrence of superoxide radical ion in crystalline 12CaO·7Al2O3 prepared via solid-state reactions. Inorg Chem 26:1192–1195

    Article  CAS  Google Scholar 

  11. Sakakura T, Tanaka K, Takenaka Y, Matsuishi S, Hosono H, Kishimoto S (2011) Determination of the local structure of a cage with an oxygen ion in Ca12Al14O33. Acta Crystallogr B 67(3):193–204

    Article  CAS  Google Scholar 

  12. Shkerin S (2005) Current production processes on metallic electrodes in contact with oxygen-conducting solid electrolytes with face-centered cubic lattice of the fluorite type. Russ J Electrochem 41(7):697–712

    Article  CAS  Google Scholar 

  13. Adler S (2004) Factors governing oxygen reduction in solid oxide fuel cell cathodes. Chem Rev 104:4791–4843

    Article  CAS  Google Scholar 

  14. Shkerin SN, Perfil’ev MV (1990) Reaction kinetics at the model electrode in the system O2,Pt/O2−. Electrode impedance dependence on the temperature and the electrolyte composition. Russ J Electrochem 26:1461–1467 (in Russian)

    CAS  Google Scholar 

  15. Shkerin SN (1994) The phenomenon of constant phase angle in the electrode system O2,Pt/O2−. The eduction of the individual characteristics of relaxation processes that determine the dispersion of the electrode impedance. Russ J Electrochem 30(9):1086–1089 (in Russian)

    CAS  Google Scholar 

  16. Shkerin SN (2003) Model gauze electrode O2,Pt/O2−: effect of the cell’s pretreatment and the single-crystal electrolyte orientation. Russ J Electrochem 39(8):863–866

    Article  CAS  Google Scholar 

  17. Shkerin SN (2004) Studies of a model mesh electrode O2,Pt/O2− under galvanostatic polarization. Russ J Electrochem 40:510–515

    Article  CAS  Google Scholar 

  18. Vshivkova A, Gorelov V (2016) Activation of oxygen reaction by praseodymium oxide film on platinum electrode in contact with YSZ electrolyte. Russ J Electrochem 52(5):488–493 (С. 549–554). doi:10.1134/S102319351605013X

    Article  CAS  Google Scholar 

  19. Tolkacheva AS, Shkerin SN, Plaksin SV (2017) Solid solutions of Ca12Al14O33+δ with V2O5 doping. Functional Materials Letters (FML-D-17-00006)

  20. Boukamp B (1986) A package for impedance/admittance analysis. Solid State Ionics 18&19:136–140

    Article  Google Scholar 

  21. Boukamp B (1986) A non-linear least squares fit procedure for analysis of immittance data of electrochemical systems. Solid State Ionics 20:31–44

    Article  CAS  Google Scholar 

  22. Shkerin SN, Profatilova IA, Lee JH (2009) Frequency dependence of conductivity of ethylene carbonate based electrolyte for Li-ion battery. Ionics 15:35–42. doi:10.1007/s11581-008-0235-y

    Article  CAS  Google Scholar 

  23. Teusner M, Souza R, Krause H, Ebbinghaus S, Belghoul B, Martin M (2015) Oxygen diffusion in mayenite. J Phys Chem C 119(18):9721–9727. doi:10.1021/jp512863u

    Article  CAS  Google Scholar 

  24. Hayashi K, Matsuishi S, Hirano M, Hosono H (2004) Instability of extraframework oxide ions and uptake of oxygen gas. J Phys Chem B 108:8920–8925

    Article  CAS  Google Scholar 

  25. Lacerda M, Irvine J, Glasser FP, West AR (1988) High oxide ion conductivity in Ca12Al14O33. Nature 332:525–526. doi:10.1038/332525a0

    Article  CAS  Google Scholar 

  26. Lee D-H, Kogel L, Ebbinghaus S, Valov I, Wiemhoefer H-D, Lerch M, Lanek J (2009) Defect chemistry of the cage compound, Ca(12)Al(14)O(33-delta)-understanding the route from a solid electrolyte to a semiconductor and electride. Phys Chem Chem Phys 11:3105–3114. doi:10.1039/b818474g

    Article  CAS  Google Scholar 

  27. Eufinger J-P, Schmidt A, Lerch M, Janek J (2015) Novel anion conductors-conductivity, thermodynamic stability and hydration of anion-substituted mayenite-type cage compounds C12A7:X (X = O, OH, Cl, F, CN, S, N). Phys Chem Chem Phys 17(10):6844–6857. doi:10.1039/c4cp05442c

    Article  CAS  Google Scholar 

  28. Hayashi K, Hirano M, Hosono H (2005) Thermodynamics and kinetics of hydroxide ion formation in 12CaO·7Al2O3. J Phys Chem B 109(24):11900–11906. doi:10.1021/jp050807j

    Article  CAS  Google Scholar 

  29. Strandbakke R, Kongshaung C, Haugsrud R, Norby T (2009) High-temperature hydration and conductivity of mayenite, Ca12Al14O33. J Phys Chem C 113(20):8938–8944. doi:10.1021/jp9009299

    Article  CAS  Google Scholar 

  30. Yoon S-G, Kim SW, Hirano M, Yoon DH, Hosono H (2008) Pore-free 12CaO·7Al2O3 single-crystal growth by melt state control using the floating zone method. Cryst Growth Des 8(4):1271–1275. doi:10.1021/cg700996x

    Article  CAS  Google Scholar 

  31. Shkerin SN, Tolkacheva AS (2015) About mechanism of hymidity effecting on mayenite conductivity. Zametki uchenogo 5:179–186 (in Russian)

    Google Scholar 

  32. Palacios L, Torre A, Bruque S, Garcia-Munoz JL, Garcia-Granda S, Sheptyakov D, Aranda MAG (2007) Crystal structures and in-situ formation study of mayenite electrides. Inorg Chem 46:4167–4176

    Article  CAS  Google Scholar 

  33. Irvine J, Lacerda M, West AR (1988) Ca12Al14O33 — a possible high-temperature moisture sensor. Mat Res Bull 23:1033–1038. doi:10.1007/BF01015244

    Article  CAS  Google Scholar 

  34. Shkerin SN, Tolkacheva AS, Korzun IV, Plaksin SV, Vovkotrub EG, Zabolotskaya EV (2016) Phase transitions in mayenite. J Therm Anal Calorim 124(3):1209–1216

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Ural Branch of the Russian Academy of Sciences, Institute of High-Temperature Electrochemistry, Ekaterinburg, 620990, Russia

    S. N. Shkerin & A. S. Tolkacheva

  2. Institute of Material Science and Metallurgy, Ural Federal University, Ekaterinburg, 620002, Russia

    A. S. Tolkacheva

  3. Ural Branch of the Russian Academy of Sciences, Institute of Electrophysics Ekaterinburg, Ekaterinburg, 620990, Russia

    A. V. Nikonov & N. B. Pavzderin

Authors
  1. S. N. Shkerin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. S. Tolkacheva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. V. Nikonov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. N. B. Pavzderin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. N. Shkerin.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Shkerin, S.N., Tolkacheva, A.S., Nikonov, A.V. et al. Impedance spectroscopy of cell with Pt electrodes on oxygen-conducting material with mayenite-related structure. Ionics 23, 2153–2160 (2017). https://doi.org/10.1007/s11581-017-2043-8

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11581-017-2043-8

Keywords

Search

Navigation