Abstract
Employment of edible oils as alternative green fuel for vehicles had raised debates on the sustainability of food supply especially in the third-world countries. The non-edible oil obtained from the abundantly available rubber seeds could mitigate this issue and at the same time reduce the environmental impact. Therefore, this paper investigates the catalytic cracking reaction of a model compound named linoleic acid that is enormously present in the rubber seed oil. Batch-scale experiments were conducted using 8.8 mL Inconel batch reactor having a cyclic horizontal swing span of 2 cm with a frequency of 60 cycles per minute at 450 °C under atmospheric condition for 90 min. The performance of HZSM-5, HBeta, HFerrierite, HMordenite and HY catalysts was tested for their efficiency in favouring gasoline range hydrocarbons. The compounds present in the organic liquid product were then analysed using GC-MS and classified based on PIONA which stands for paraffin, isoparaffin, olefin, naphthenes and aromatics respectively. The results obtained show that HZSM-5 catalyst favoured gasoline range hydrocarbons that were rich in aromatics compounds and promoted the production of desired isoparaffin. It also gave a higher cracking activity; however, large gaseous as by-products were produced at the same time.
Similar content being viewed by others
References
Ahmad M, Farhana R, Raman AAA, Bhargava SK (2016) Synthesis and activity evaluation of heterometallic nano oxides integrated ZSM-5 catalysts for palm oil cracking to produce biogasoline. Energy Convers Manag 119:352–360. https://doi.org/10.1016/j.enconman.2016.04.069
Ameen M, Azizan MT, Yusup S, Ramli A, Yasir M (2017a) Catalytic hydrodeoxygenation of triglycerides: an approach to clean diesel fuel production. Renew Sust Energ Rev 80:1072–1088. https://doi.org/10.1016/j.rser.2017.05.268
Ameen M, Azizan MT, Yusup S, Ramli A (2017b) Hydroprocessing of rubber seed oil over Ni-Mo/γ-Al2O3 for the green diesel production. Chem Eng Trans 61:1843–1848. https://doi.org/10.3303/CET1761305
Bokhari A, Chuah LF, Yusup S, Klemeš JJ, Akbar MM, Kamil RNM (2016a) Cleaner production of rubber seed oil methyl ester using a hydrodynamic cavitation: optimisation and parametric study. J Clean Prod 136:31–41. https://doi.org/10.1016/j.jclepro.2016.04.091
Bokhari A, Chuah LF, Yusup S, Klemeš JJ, Kamil RNM (2016b) Optimisation on pretreatment of rubber seed ( Hevea brasiliensis ) oil via esterification reaction in a hydrodynamic cavitation reactor. Bioresour Technol 199:414–422. https://doi.org/10.1016/j.biortech.2015.08.013
Bokhari A, Yusup S, Chuah LF, Klemeš JJ, Asif S, Ali B, Akbar MM, Kamil RNM (2017) Pilot scale intensification of rubber seed (Hevea brasiliensis) oil via chemical interesterification using hydrodynamic cavitation technology. Bioresour Technol 242:272–282. https://doi.org/10.1016/j.biortech.2017.03.046
Caldeira VPS, Santos AGD, Pergher SBC, Costa MJF, Araujo AS (2016) Use of a low-cost template-free zsm-5 for atmospheric petroleum residue pyrolysis. Quim Nova 39:292–297. https://doi.org/10.5935/0100-4042.20160019
Cañizares P, Carrero A, Sánchez P (2000) Isomerization of n-butene over ferrierite zeolite modified by silicon tetrachloride treatment. Appl Catal A Gen 190:93–105. https://doi.org/10.1016/S0926-860X(99)00265-3
Don TN, Hung TN, Huyen PT et al (2016) Synthesis, characterization and catalytic activity of nano-zeolite Y for the alkylation of benzene with isopropanol. Indian J Chem Technol 23:392–399
Doronin VP, Potapenko OV, Lipin PV, Sorokina TP, Buluchevskaya LA (2012) Catalytic cracking of vegetable oils for production of high-octane gasoline and petrochemical feedstock. Pet Chem 52:392–400. https://doi.org/10.1134/S0965544112060059
Fotouh TMA (2016) Experimental study on the influence of ethanol and automotive gasoline blends. J Pet Environ Biotechnol 07:1–6. https://doi.org/10.4172/2157-7463.C1.022
Gurdeep Singh HK, Yusup S, Abdullah B, Cheah KW (2017) Refining of crude rubber seed oil as a feedstock for biofuel production. J Environ Manage 203:1011–1016. https://doi.org/10.1016/j.jenvman.2017.04.021
Imdadul HK, Zulkifli NWM, Masjuki HH, Kalam MA, Kamruzzaman M, Rashed MM, Rashedul HK, Alwi A (2017) Experimental assessment of non-edible candlenut biodiesel and its blend characteristics as diesel engine fuel. Environ Sci Pollut Res 24:2350–2363. https://doi.org/10.1007/s11356-016-7847-y
Ishihara A, Tsukamoto T, Hashimoto T, Nasu H (2018) Catalytic cracking of soybean oil by ZSM-5 zeolite-containing silica-aluminas with three layered micro-meso-meso-structure. Catal Today 303:123–129. https://doi.org/10.1016/j.cattod.2017.09.033
Kim D, Park G, Choi B, Kim YB (2017) Reaction characteristics of dimethyl ether (DME) steam reforming catalysts for hydrogen production. Int J Hydrog Energy 42:29210–29221. https://doi.org/10.1016/j.ijhydene.2017.10.020
Kraiem T, Ben HA, Belayouni H, Jeguirim M (2017) Production and characterization of bio-oil from the pyrolysis of waste frying oil. Environ Sci Pollut Res 24:9951–9961. https://doi.org/10.1007/s11356-016-7704-z
Li L, Quan K, Xu J, Liu F, Liu S, Yu S, Xie C, Zhang B, Ge X (2014) Liquid hydrocarbon fuels from catalytic cracking of rubber seed oil using USY as catalyst. Fuel 123:189–193. https://doi.org/10.1016/j.fuel.2014.01.049
Martínez-Franco R, Paris C, Martínez-Armero ME, Martínez C, Moliner M, Corma A (2016) High-silica nanocrystalline Beta zeolites: efficient synthesis and catalytic application. Chem Sci 7:102–108. https://doi.org/10.1039/C5SC03019F
Martini G, Manfredi U, Krasenbrink A, et al (2013) Effect of oxygenates in gasoline on fuel consumption and emissions in three Euro 4 passenger cars contact information. European Union
Ramli NAS, Amin NAS (2015) Fe/HY zeolite as an effective catalyst for levulinic acid production from glucose: characterization and catalytic performance. Appl Catal B Environ 163:487–498. https://doi.org/10.1016/j.apcatb.2014.08.031
Ramya G, Sivakumar T, Arif M, Ahmed Z (2015) Application of microporous catalysts in the production of biofuels from non edible vegetable oils and used restaurant oil. Energy Sources, Part A Recover Util Environ Eff 37:878–885. https://doi.org/10.1080/15567036.2011.590855
Rengga WDP, Handayani PA, Kadarwati S, Feinnudin A (2015) Kinetic study on catalytic cracking of rubber seed (Hevea brasiliensis) oil to liquid fuels. Bull Chem React Eng Catal 10:50–60. https://doi.org/10.9767/bcrec.10.1.5852.50-60
Sirajudin N, Jusoff K, Yani S et al (2013) Biofuel production from catalytic cracking of palm oil. World Appl Sci J 26:67–71. https://doi.org/10.5829/idosi.wasj.2013.26.nrrdsi.26012
Subsadsana M, Kham-or P, Sangdara P, Suwannasom P, Ruangviriyachai C (2017) Synthesis and catalytic performance of bimetallic NiMo- and NiW-ZSM-5/MCM-41 composites for production of liquid biofuels. J Fuel Chem Technol 45:805–816. https://doi.org/10.1016/S1872-5813(17)30039-7
Suyanta S, Izul FI (2012) Cracking of palm oil over H-AIMCM-41 catalyst. J Chem Chem Eng 6:531–535
Taufiqurrahmi N, Mohamed AR, Bhatia S (2011) Nanocrystalline zeolite beta and zeolite y as catalysts in used palm oil cracking for the production of biofuel. J Nanopart Res 13:3177–3189. https://doi.org/10.1007/s11051-010-0216-8
Vichaphund S, Aht-Ong D, Sricharoenchaikul V, Atong D (2015) Production of aromatic compounds from catalytic fast pyrolysis of Jatropha residues using metal/HZSM-5 prepared by ion-exchange and impregnation methods. Renew Energy 79:28–37. https://doi.org/10.1016/j.renene.2014.10.013
Vijayakumar C, Ramesh M, Murugesan A, Panneerselvam N, Subramaniam D, Bharathiraja M (2016) Biodiesel from plant seed oils as an alternate fuel for compression ignition engines—a review. Environ Sci Pollut Res 23:24711–24730. https://doi.org/10.1007/s11356-016-7754-2
Voelcker J (2014) 1.2 Billion Vehicles On World’s Roads Now, 2 Billion By 2035: Report. In: Green Car Reports. http://www.greencarreports.com/news/1093560_1-2-billion-vehicles-on-worlds-roads-now-2-billion-by-2035-report. Accessed 23 Sep 2017
Vu HX, Schneider M, Bentrup U, Dang TT, Phan BMQ, Nguyen DA, Armbruster U, Martin A (2015a) Hierarchical ZSM-5 materials for an enhanced formation of gasoline-range hydrocarbons and light olefins in catalytic cracking of triglyceride-rich biomass. Ind Eng Chem Res 54:1773–1782. https://doi.org/10.1021/ie504519q
Vu XH, Nguyen S, Dang TT, BMQ P, Nguyen DA, Armbruster U, Martin A (2015b) Catalytic cracking of triglyceride-rich biomass toward lower olefins over a nano-ZSM-5/SBA-15 analog composite. Catalysts 5:1692–1703. https://doi.org/10.3390/catal5041692
Wang Z, Yu S (2016) Production of liquid hydrocarbon fuel from catalytic cracking of rubber seed oil using new mesoporous molecular sieves. ACS Sustain Chem Eng 4:5594–5599. https://doi.org/10.1021/acssuschemeng.6b01441
Widayatno WB, Guan G, Rizkiana J, Yang J, Hao X, Tsutsumi A, Abudula A (2016) Upgrading of bio-oil from biomass pyrolysis over Cu-modified β-zeolite catalyst with high selectivity and stability. Applied Catal B, Environ 186:166–172. https://doi.org/10.1016/j.apcatb.2016.01.006
Wiedemann SCC, Muñoz-Murillo A, Oord R, van Bergen-Brenkman T, Wels B, Bruijnincx PCA, Weckhuysen BM (2015) Skeletal isomerisation of oleic acid over ferrierite: influence of acid site number, accessibility and strength on activity and selectivity. J Catal 329:195–205. https://doi.org/10.1016/j.jcat.2015.05.013
Yigezu ZD, Muthukumar K (2014) Catalytic cracking of vegetable oil with metal oxides for biofuel production. Energy Convers Manag 84:326–333. https://doi.org/10.1016/j.enconman.2014.03.084
Acknowledgements
The authors would like to thank the two collaborating universities, Universiti Teknologi PETRONAS, Malaysia and Kumamoto University, Japan for their continuous support.
Funding
This study received funding from Ministry Of Higher Education (MOHE), Malaysia through Long-Term Research Grant Scheme (LRGS).
Author information
Authors and Affiliations
Corresponding author
Additional information
Responsible editor: Philippe Garrigues
Rights and permissions
About this article
Cite this article
Gurdeep Singh, H.K., Yusup, S., Quitain, A.T. et al. Production of gasoline range hydrocarbons from catalytic cracking of linoleic acid over various acidic zeolite catalysts. Environ Sci Pollut Res 26, 34039–34046 (2019). https://doi.org/10.1007/s11356-018-3223-4
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11356-018-3223-4