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A multipoint (49 points) study of dry deposition of polycyclic aromatic hydrocarbons (PAHs) in Erzurum, Turkey by using surrogated snow surface samplers

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Abstract

Dry deposition of atmospheric 18 polycyclic aromatic hydrocarbon (PAH) components was investigated in the scope of the study by using surrogate snow samplers at 49 different sampling points in and around the city center of Erzurum, Turkey. Snow was sampled twice, the first of which was taken immediately after the first fresh snow cover and placed into aluminum trays to obtain dry deposition surface while the second sample was taken from the snow cover (accumulated snow) exposed to an 8-day dry deposition period and then analyzed and extracted. All the samples taken from the samplers were extracted using solid and liquid phase extraction and analyzed through GC-MS. It was observed that at the end of an 8-day dry period, snow samples enriched 5.5 times more in PAH components than the baseline. PAH deposition was determined to be influenced mainly by coal, mixed source, traffic, diesel fuel, and petrol fuel at 43, 27, 20, 8, and 2 % of sampling points, respectively. Local polluting sources were found to be effective on the spatial distribution of dry deposition of PAH components in urban area.

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References

  • Bayraktar H, Turalioglu FS (2005) Composition of wet and bulk deposition in Erzurum, Turkey. Chemosphere 59:1537–1546

    Article  CAS  Google Scholar 

  • Birgül A, Tasdemir Y, Cindoruk SS (2011) Atmospheric wet and dry deposition of polycyclic aromatic hydrocarbons (PAHs) determined using a modified sampler. Atmos Res 101:341–353

    Article  Google Scholar 

  • Bozlaker A, Muezzinoglu A, Odabasi M (2008) Atmospheric concentrations, dry deposition and air–soil exchange of polycyclic aromatic hydrocarbons (PAHs) in an industrial region in Turkey. J Hazard Mater 153:1093–1102

    Article  CAS  Google Scholar 

  • Callén MS, López JM, Iturmendi A, Mastral AM (2013) Nature and sources of particle associated polycyclic aromatic hydrocarbons (PAH) in the atmospheric environment of an urban area. Environ Pollut 183:166–174

    Article  Google Scholar 

  • Caricchia AM, Chiavarini S, Pezza M (1999) Polycyclic aromatic hydrocarbons in the urban atmospheric particulate matter in the city of Naples (Italy). Atmos Environ 33:3731–3738

    Article  CAS  Google Scholar 

  • Chen S-C, Liao C-M (2006) Health risk assessment on human exposed to environmental polycyclic aromatic hydrocarbons pollution sources. Sci Total Environ 366:112–123

    Article  CAS  Google Scholar 

  • Chen Y, Feng Y, Xiong S, Liu D, Wang G, Sheng G, Fu J (2011) Polycyclic aromatic hydrocarbons in the atmosphere of Shanghai, China. Environ Monit Assess 172:235–247

    Article  CAS  Google Scholar 

  • Daisey Leyko MA, Kneip TJ (1979) Source identification and allocation of polynuclear aromatic hydrocarbon compounds in the New York City aerosol: methods and applications. In: Jones PLPW (ed) Polynuclear Aromatic Hydrocarbons. Ann Arbor Science Publishers, Inc., Ann Arbor, Michigan, pp 201–215

    Google Scholar 

  • Delgado-Saborit JM, Stark C, Harrison RM (2013) Use of a versatile high efficiency multiparallel denuder for the sampling of PAHs in ambient air: gas and particle phase concentrations, particle size distribution and artifact formation. Environ SciTechnol 48:499–507

    Article  Google Scholar 

  • Demircioglu E, Sofuoglu A, Odabasi M (2011) Atmospheric concentrations and phase partitioning of polycyclic aromatic hydrocarbons in Izmir, Turkey. CLEAN – Soil, Air, Water 39:319–327

    Article  CAS  Google Scholar 

  • Esen F, Cindoruk SS, Tasdemir Y (2008) Bulk deposition of polycyclic aromatic hydrocarbons (PAHs) in an industrial site of Turkey. Environ Pollut 152:461–467

    Article  CAS  Google Scholar 

  • Franz TP, Eisenreich SJ, Holsen TM (1998) Dry deposition of particulate polychlorinated biphenyls and polycyclic aromatic hydrocarbons to Lake Michigan. Environ Sci Technol 32:3681–3688

    Article  CAS  Google Scholar 

  • Gabrieli J, Decet F, Luchetta A, Valt M, Pastore P, Barbante C (2010) Occurrence of PAH in the seasonal snowpack of the Eastern Italian Alps. Environ Pollut 158:3130–3137

    Article  CAS  Google Scholar 

  • Gaga EO (2004) Investigation of polycyclic aromatic hydrocarbon (PAH) deposition in Ankara, The Graduate School of Natural and Applied Sciences, Vol. PhD Thesis. The Middle East Technical University, Ankara

    Google Scholar 

  • Gaga EO, Ari A (2011) Gas–particle partitioning of polycyclic aromatic hydrocarbons (PAHs) in an urban traffic site in Eskisehir, Turkey. Atmos Res 99:207–216

    Article  CAS  Google Scholar 

  • Gaga EO, Tuncel G, Tuncel SG (2004) PAH composition of snow samples in Ankara City. Fresenius Environ Bull 23:1295–1302

    Google Scholar 

  • Golomb D, Ryan D, Eby N, Underhill J, Zemba S (1997) Atmospheric deposition of toxics onto Massachusetts Bay—I. Metals. Atmos Environ 31:1349–1359

    Article  CAS  Google Scholar 

  • Gschwend PM, Hites RA (1981) Fluxes of polycyclic aromatic hydrocarbons to marine and lacustrine sediments in the northeastern United States. Geochim Cosmochim Acta 45:2359–2367

    Article  CAS  Google Scholar 

  • Harrison RM, Smith DJT, Luhana L (1996) Source apportionment of atmospheric polycyclic aromatic hydrocarbons collected from an urban location in Birmingham, U.K. Environ Sci Technol 30:825–832

    Article  CAS  Google Scholar 

  • Hassan S, Khoder MI (2012) Gas–particle concentration, distribution, and health risk assessment of polycyclic aromatic hydrocarbons at a traffic area of Giza, Egypt. Environ Monit Assess 184:3593–3612

    Article  CAS  Google Scholar 

  • Hertel RF, Rosner G, Kielhorn J (1998) Selected non-heterocyclic polycyclic aromatic hydrocarbons, World Health Organization, Geneva. World Health Organization, Geneva

    Google Scholar 

  • Hidy GM (2003) Snowpack and precipitation chemistry at high altitudes. Atmos Environ 37:1231–1242

    Article  CAS  Google Scholar 

  • Kamal A, Malik RN, Martellini T, Cincinelli A (2015) Source, profile and carcinogenic risk assessment for cohorts occupationally exposed to dust-bound PAHs in Lahore and Rawalpindi cities (Punjab province, Pakistan). Environ Sci Pollut Res 22:10580–10591

    Article  CAS  Google Scholar 

  • Kavouras IG, Stephanou EG (2002) Particle size distribution of organic primary and secondary aerosol constituents in urban, background marine, and forest atmosphere. J Geophys Res-Atmos 107:AAC 7-1–AAC 7–12

    Article  Google Scholar 

  • Khalili NR, Scheff PA, Holsen TM (1995) PAH source fingerprints for coke ovens, diesel, and gasoline engines, highway tunnels, and wood combustion emissions. Atmos Environ 29:533–542

    Article  CAS  Google Scholar 

  • Kleeman MJ, Schauer JJ, Cass GR (2000) Size and composition distribution of fine particulate matter emitted from motor vehicles. Environ Sci Technol 34:1132–1142

    Article  CAS  Google Scholar 

  • Larsson M, Hagberg J, Rotander A, Bavel B, Engwall M (2013) Chemical and bioanalytical characterisation of PAHs in risk assessment of remediated PAH-contaminated soils. Environ Sci Pollut Res 20:8511–8520

    Article  CAS  Google Scholar 

  • Li J, Cheng H, Zhang G, Qi S, Li X (2009) Polycyclic aromatic hydrocarbon (PAH) deposition to and exchange at the air–water interface of Luhu, an urban lake in Guangzhou, China. Environ Pollut 157:273–279

    Article  CAS  Google Scholar 

  • Liu Y, Chen L, Zhao J, Wei Y, Pan Z, Meng X-Z, Huang Q, Li W (2010) Polycyclic aromatic hydrocarbons in the surface soil of Shanghai, China: concentrations, distribution and sources. Org Geochem 41:355–362

    Article  CAS  Google Scholar 

  • Melnikov S, Carroll J, Gorshkov A, Vlasov S, Dahle S (2003) Snow and ice concentrations of selected persistent pollutants in the Ob–Yenisey River watershed. Sci Total Environ 306:27–37

    Article  CAS  Google Scholar 

  • Meyer T, Lei YD, Wania F (2006) Measuring the release of organic contaminants from melting snow under controlled conditions. Environ SciTechnol 40:3320–3326

    Article  CAS  Google Scholar 

  • Motelay-Massei A, Garban B, Tiphagne-larcher K, Chevreuil M, Ollivon D (2006) Mass balance for polycyclic aromatic hydrocarbons in the urban watershed of Le Havre (France): transport and fate of PAHs from the atmosphere to the outlet. Water Res 40:1995–2006

    Article  CAS  Google Scholar 

  • Motelay-Massei A, Ollivon D, Garban B, Tiphagne-Larcher K, Chevreuil M (2007) Fluxes of polycyclic aromatic hydrocarbons in the Seine estuary, France: mass balance and role of atmospheric deposition. Hydrobiologia 588:145–157

    Article  CAS  Google Scholar 

  • Oda J, Nomura S, Yasuhara A, Shibamoto T (2001) Mobile sources of atmospheric polycyclic aromatic hydrocarbons in a roadway tunnel. Atmos Environ 35:4819–4827

    Article  CAS  Google Scholar 

  • Odabasi M, Bagiroz HO (2002) Sulfate dry deposition fluxes and overall deposition velocities measured with a surrogate surface. Sci Total Environ 297:193–201

    Article  CAS  Google Scholar 

  • Odabasi M, Vardar N, Sofuoğlu A, Taşdemir Y, Holsen TM (1999) Polycyclic aromatic hydrocarbons (PAHs) in Chicago air. Sci Total Environ 227:57–67

    Article  CAS  Google Scholar 

  • Odabası M, Sofuoglu A, Tasdemir Y, Holsen TM (1999) Measurement of dry deposition and air-water exchange of polycyclic aromatic hydrocarbons with the water surface sampler. Environ SciTechnol 33:426–434

    Article  Google Scholar 

  • Ortiz R, Vega S, Gutiérrez R, Gibson R, Schettino B, Lourdes Ramirez M (2012) Presence of polycyclic aromatic hydrocarbons (PAHs) in top soils from rural terrains in Mexico City. Bull Environ Contam Toxicol 88:428–432

    Article  CAS  Google Scholar 

  • Paloluoğlu C, Bayraktar H, Turalıoğlu FS, Gaga EO (2013) Atmospheric dry deposition of flux of benzo[a]pyrene with surrogated snow sampling Erzurum Urban Center. HKAD 2:55–64, Turkish National Committee of Air Pollution determination

    Google Scholar 

  • Pandey SK, Kim K-H, Brown RJC (2011) A review of techniques for the determination of polycyclic aromatic hydrocarbons in air. TrAC 30:1716–1739

    CAS  Google Scholar 

  • Papageorgoulou A, Manoli E, Touloumi E, Samara C (1999) Polycyclic aromatic hydrocarbons in the ambient air of Greek towns in relation to other atmospheric pollutants. Chemosphere 39:2183–2199

    Article  Google Scholar 

  • Rogge WF, Hildemann LM, Mazurek MA, Cass GR, Simoneit BRT (1993) Sources of fine organic aerosol. 5. Natural gas home appliances. Environ Sci Technol 27:2736–2744

    Article  CAS  Google Scholar 

  • Seinfeld JH (1986) Atmospheric chemistry and physics of air pollution. A Wiley-Interscience publication, New York

  • Shannigrahi AS, Fukushima T, Ozaki TN (2005) Comparison of different methods for measuring dry deposition fluxes of particulate matter and polycyclic aromatic hydrocarbons (PAHs) in the ambient air. Atmos Environ 39:653–662

    Article  CAS  Google Scholar 

  • Sheu HL, Lee WJ, Tsai JH, Fan YC, Su CC, Chao HR (1996) Particle size distribution of polycyclic aromatic hydrocarbons in the ambient air of a traffic intersection. J Environ Sci Health 31:1293–1316

    Google Scholar 

  • Skrdlikova L, Landlova L, Klanova J, Lammel G (2011) Wet deposition and scavenging efficiency of gaseous and particulate phase polycyclic aromatic compounds at a central European suburban site. Atmos Environ 45:4305–4312

    Article  CAS  Google Scholar 

  • Tasdemir Y, Esen F (2007) Dry deposition fluxes and deposition velocities of PAHs at an urban site in Turkey. Atmos Environ 41:1288–1301

    Article  CAS  Google Scholar 

  • Tasdemir Y, Esen F (2008) Deposition of polycyclic aromatic hydrocarbons (PAHs) and their mass transfer coefficients determined at a trafficked site. Archieves of Environ Contam Toxicol 55:191–198

    Article  CAS  Google Scholar 

  • Terzi E, Samara C (2005) Dry deposition of polycyclic aromatic hydrocarbons in urban and rural sites of Western Greece. Atmos Environ 39:6261–6270

    Article  CAS  Google Scholar 

  • Vasconcellos P, Souza DZ, Magalhaes D, Da Rocha GO (2011) Seasonal variation of n-alkanes and polycyclic aromatic hydrocarbon concentrations in PM10 samples collected at urban sites of São Paulo State, Brazil. Water Air Soil Poll 222:325–336

    Article  CAS  Google Scholar 

  • Viskari EL, Rekila R, Roy S, Lehto O, Ruuskanen J, Karenlampi L (1997) Airborne pollutants along a roadside: assessment using snow analyses and moss bags. Environ Pollut 97:153–160

    Article  CAS  Google Scholar 

  • Wang X-T, Miao Y, Zhang Y, Li YC, Wu MH, Yu G (2013) Polycyclic aromatic hydrocarbons (PAHs) in urban soils of the megacity Shanghai: occurrence, source apportionment and potential human health risk. Sci Total Environ 447:80–89

    Article  CAS  Google Scholar 

  • Wania F, Mackay D (1993) Global fractionation and cold condensation of low volatility organochlorine compounds in Polar Regions. Ambio 22:10–18

    Google Scholar 

  • Wu SP, Tao S, Liu WX (2006) Particle size distributions of polycyclic aromatic hydrocarbons in rural and urban atmosphere of Tianjin, China. Chemosphere 62:357–367

    Article  CAS  Google Scholar 

  • Yi SM, Holsen TM, Zhu X, Noll KE (1997) Sulfate dry deposition measured with a water surface sampler: a comparison to modeled results. J Geophys Res-Atmos 102:19695–19705

    Article  CAS  Google Scholar 

  • Yunker MB, Macdonald RW, Vingarzan R, Mitchell RH, Goyette D, Sylvestre S (2002) PAHs in the Fraser River basin: a critical appraisal of PAH ratios as indicators of PAH source and composition. Org Geochem 33:489–515

    Article  CAS  Google Scholar 

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Acknowledgment

We would like to thank the financial support provided by TUBITAK in the scope of the project 107Y021.

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Correspondence to Hanefi Bayraktar.

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Responsible editor: Hongwen Sun

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Bayraktar, H., Paloluoğlu, C., Turalioğlu, F.S. et al. A multipoint (49 points) study of dry deposition of polycyclic aromatic hydrocarbons (PAHs) in Erzurum, Turkey by using surrogated snow surface samplers. Environ Sci Pollut Res 23, 12400–12413 (2016). https://doi.org/10.1007/s11356-016-6427-5

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