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Structure and magnetic properties of a serendipitously synthesized copper(II) complex: [Cu(3-Br-2-pyone)6](ClO4)2

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Abstract

Hexakis(3-bromo-2(1H)-pyridone)copper(II) perchlorate was prepared. Crystals and powdered bulk samples were characterized using IR, single-crystal and powder X-ray diffraction, combustion analysis, EPR and temperature-dependent magnetic susceptibility data. The complex crystallizes in the triclinic space group P\(\bar{1}\) and comprises a Jahn–Teller distorted Cu(II)–O6 coordination sphere with the ligands coordinated via the pyridone O-atoms. EPR and variable temperature susceptibility measurements show that the complex is well isolated magnetically in the lattice.

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Acknowledgements

FEW is grateful for support from PCI Synthesis Inc. (now SEQENS) and the Dr. Bernard’38 and Vera Wantman Kopelman’40 Endowed Science Fund.

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Authors and Affiliations

  1. Carlson School of Chemistry and Biochemistry, Clark University, Worcester, MA, USA

    Faith E. Witkos, Jeffrey C. Monroe & Mark M. Turnbull

  2. Department of Physics, Clark University, Worcester, MA, USA

    Christopher P. Landee

  3. School of Physical and Chemical Sciences, University of Canterbury, Private Bag 4800, Christchurch, New Zealand

    Jan L. Wikaira

Authors
  1. Faith E. Witkos
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  2. Jeffrey C. Monroe
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  3. Christopher P. Landee
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  4. Mark M. Turnbull
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  5. Jan L. Wikaira
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Correspondence to Mark M. Turnbull.

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11243_2019_375_MOESM1_ESM.docx

Powder X-ray diffraction patterns for 1 (calculated and experimental, Figure S1) and χ(T) for compound 1 (Figure S2). (DOCX 274 kb)

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Witkos, F.E., Monroe, J.C., Landee, C.P. et al. Structure and magnetic properties of a serendipitously synthesized copper(II) complex: [Cu(3-Br-2-pyone)6](ClO4)2. Transit Met Chem 45, 237–243 (2020). https://doi.org/10.1007/s11243-019-00375-7

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  • DOI: https://doi.org/10.1007/s11243-019-00375-7

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