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Syntheses and crystal structures of two new coordination polymers of Cd(II) using organic spacer and inorganic-bridging ligands

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Abstract

Two new cadmium (II) complexes [Cd(hmt)(dca)2] n (1) and [Cd3(hmt)2(SeCN)6(H2O)2] n (2) (hmt=hexamethylenetetramine, dca=dicyanamide) have been synthesized and characterized by X-ray single-crystal analysis. The complex 1 is a 2D rectangular grid of octahedral cadmium (II) with CdN6 chromophore where cadmium centers are doubly bridged by dicyanamide and hmt along a-axis, which are interlinked by dicyanamide running along c-axis. Whereas, complex 2 is a 1D chain of octahedral cadmium (II) with a three-leg ladder topology running along a-axis. The Cd(II) centers are doubly bridged through SeCN (infinite rail) along a-axis and singly bridged by hmt (two-step rung) along c-axis, having cadmium centers with CdSe2N3O and CdSe2N4 chromophores. The adjacent chains through H-bonding between coordinated water and hmt, and Se\(\cdots\)Se interaction are extended to 2D supramolecular architecture.

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Acknowledgement

The authors acknowledge CSIR (India) for financial support.

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Authors and Affiliations

  1. Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, Jadavpur, Kolkata, 700 032, India

    Ananta Kumar Ghosh, Debajyoti Ghoshal & Nirmalendu Ray Chaudhuri

  2. Department of Chemistry, University of Reading, Whiteknights, Reading, RG6 6AD, United Kingdom

    Michael G. B. Drew

  3. Department of Physics, Jadavpur University, Kolkata, 700 032, India

    Golam Mostafa

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  1. Ananta Kumar Ghosh
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  2. Debajyoti Ghoshal
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  3. Michael G. B. Drew
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  4. Golam Mostafa
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  5. Nirmalendu Ray Chaudhuri
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Correspondence to Nirmalendu Ray Chaudhuri.

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Ghosh, A.K., Ghoshal, D., Drew, M.G.B. et al. Syntheses and crystal structures of two new coordination polymers of Cd(II) using organic spacer and inorganic-bridging ligands. Struct Chem 17, 85–90 (2006). https://doi.org/10.1007/s11224-006-9017-1

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  • DOI: https://doi.org/10.1007/s11224-006-9017-1

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