The history of spectral studies of surface processes at St. Petersburg University from the pioneering pre-war experiments by Terenin and Kassparov to the present day is described. The development of experimental techniques and advances in the studies of surface acid and basic sites, functional groups, and adsorption complexes is discussed. Spectroscopy in a wide temperature range allows studying such phenomena as lateral interactions between adsorbed molecules and linkage isomerism and obtaining information on the mechanism of dark and photostimulated reactions. Attention is paid to the application of computer modeling and quantum chemistry in the study of surface processes.
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Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 11, pp. 6–13, November, 2021.
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Tsyganenko, A.A. Developmemt of the Researches on IR Spectroscopy of Surfaces at St. Petersburg University. Russ Phys J 64, 1990–1998 (2022). https://doi.org/10.1007/s11182-022-02548-x
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DOI: https://doi.org/10.1007/s11182-022-02548-x