Abstract
The product of the reaction of valeraldehyde with chlorine dioxide was determined, and the solvent effect on the reaction kinetics was studied. The major oxidation product is valeric acid. The reaction rate is described by the second-order equation w = k[RCHO]·[ClO2]. The rate constants were measured in the 297–328 K interval, and the activation parameters of the reaction were determined.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2287–2289, November, 2008.
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Ganieva, E.S., Ganiev, I.M., Grabovskiy, S.A. et al. Oxidation of valeraldehyde by chlorine dioxide. Russ Chem Bull 57, 2332–2334 (2008). https://doi.org/10.1007/s11172-008-0331-1
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DOI: https://doi.org/10.1007/s11172-008-0331-1