Abstract
In this study, rare-earth perovskite-type oxides LaTiO3±δ, LaMnO3 and LaMn0.5Ti0.5O3 were prepared by the sol–gel method and tested for the photocatalytic decomposition of an azo dye, basic red 46, under visible light. The experimental results showed that the photocatalytic activity of LaMn0.5Ti0.5O3 was much higher than that of LaMnO3 and LaTiO3±δ. Then, the discoloration efficiency of basic red 46 was studied over LaMn0.5Ti0.5O3 prepared by several methods. The structure, morphology and light absorption of prepared samples were characterized by XRD, SEM and UV–vis (DRS mode) spectroscopy. The best photocatalytic performance exhibited by the LaMn0.5Ti0.5O3 prepared using the Pechini sol–gel method and its excellent activity results from narrower band-gap energy, smaller particles size and porosity structure which is capable of supporting the enhanced loading of organic contaminants on surface. In the following, graphene/LaMn0.5Ti0.5O3 nanocomposite photocatalysts were synthesized for the first time. The photocatalytic efficiency of the graphene/LaMn0.5Ti0.5O3 nanocomposites was higher than that of pristine LaMn0.5Ti0.5O3 and graphene(50%wt)/LaMn0.5Ti0.5O3 had the greatest photocatalytic activity (degradation 90% after 5 h). The excellent photocatalytic activity can be attributed to the high separation efficiency of photoinduced electron–hole pairs resulting from the excellent conductivity of in graphene/LaMn0.5Ti0.5O3.
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References
Khanna A, Shetty VK (2014) Sol Energy 99:67–76
Gnanamani A, Bhaskar M, Ganga R, Sekaran G, Sadulla S (2004) Chemosphere 56(9):833–841
Pare B, Jonnalagadda S, Tomar H, Singh P, Bhagwat V (2008) Desalination 232(1):80–90
Daneshvar N, Salari D, Khataee A (2003) J Photochem Photobiol A 157(1):111–116
Ku Y, Wang L-C, Ma C-M, Chou Y-C (2011) Water Air Soil Pollut 215(1–4):97–103
Liu D-R, Jiang Y-S, Gao G-M (2011) Chemosphere 83(11):1546–1552
Rasoulifard MH, Marandi R, Majidzadeh H, Bagheri I (2011) Environ Eng Sci 28(3):229–235
Rasoulifard M, Dorraji MS, Taherkhani S (2016) J Taiwan Inst Chem E 58:324–332
Shifu C, Lei C, Shen G, Gengyu C (2005) Chem Phys Lett 413(4):404–409
Fakhouri H, Pulpytel J, Smith W, Zolfaghari A, Mortaheb HR, Meshkini F, Jafari R, Sutter E, Arefi-Khonsari F (2014) Appl Catal B 144:12–21
Bae SW, Ji SM, Hong SJ, Jang JW, Lee JS (2009) Int J Hydrog Energy 34(8):3243–3249
Fu S, Niu H, Tao Z, Song J, Mao C, Zhang S, Chen C, Wang D (2013) J Alloys Compd 576:5–12
Jie H, Jie M, Jiahua M, Huang H (2014) J Rare Earths 32(12):1126–1134
Pena M, Fierro J (2001) Chem Rev 101(7):1981–2018
Li D, Zheng J, Zou Z (2006) J Phys Chem Solids 67(4):801–806
Abazari R, Sanati S, Saghatforoush LA (2014) Mater Sci Semicond Process 25:301–306
Torres-Martínez LM, Cruz-López A, Juárez-Ramírez I, Meza-de la Rosa ME (2009) J Hazard Mater 165(1):774–779
Hu J, Ma J, Wang L, Huang H (2014) J Alloys Compd 583:539–545
Liang D, Cui C, Hu H, Wang Y, Xu S, Ying B, Li P, Lu B, Shen H (2014) J Alloys Compd 582:236–240
Yoo D-H, Cuong TV, Pham VH, Chung JS, Khoa NT, Kim EJ, Hahn SH (2011) Curr Appl Phys 11(3):805–808
Wu C, Zhang Y, Li S, Zheng H, Wang H, Liu J, Li K, Yan H (2011) Chem Eng J 178:468–474
Zhang D, Pu X, Ding G, Shao X, Gao Y, Liu J, Gao M, Li Y (2013) J Alloys Compd 572:199–204
Low J, Yu J, Li Q, Cheng B (2014) Phys Chem Chem Phys 16(3):1111–1120
Hu R, Li C, Wang X, Sun Y, Jia H, Su H, Zhang Y (2012) Catal Commun 29:35–39
Hosseini SA, Salari D, Niaei A, Oskoui SA (2013) J Ind Eng Chem 19(6):1903–1909
Nakhostin Panahi P, Salari D, Tseng H-H, Niaei A, Mousavi SM (2017) Environ Technol 38(15):1852–1861
Panahi PN, Niaei A, Salari D, Mousavi SM, Delahay G (2015) J Environ Sci 35:135–143
Al-Areqi NA, Al-Alas A, Al-Kamali AS, Ghaleb KA, Al-Mureish K (2014) J Mol Catal A 381:1–8
Susanti YD, Afifah N, Saleh R (2017) Multifunctional photocatalytic degradation of methylene blue using LaMnO3/Fe3O4 nanocomposite on different types of graphene. J Phys 1:012021
Feraru S, Borhan A, Samoila P, Mita C, Cucu-Man S, Iordan A, Palamaru M (2015) J Photochem Photobiol A 307:1–8
Hu J, Ma J, Wang L, Huang H, Ma L (2014) Powder Technol 254:556–562
Wei Z-X, Xiao C-M, Zeng W-W, Liu J-P (2013) J Mol Catal A 370:35–43
Abbasi A, Hamadanian M, Salavati-Niasari M, Mortazavi-Derazkola S (2017) J Colloid Interface Sci 500:276–284
Wei Y, Zhang X, Xu J, Wang J, Huang Y, Fan L, Wu J (2014) Appl Catal B 147:920–928
Wang L, Pang Q, Song Q, Pan X, Jia L (2015) Fuel 140:267–274
Wei Z-X, Ye S-B, Wang X-M (2016) Ceram Int 42(7):9196–9203
Yoshino M, Kakihana M, Cho WS, Kato H, Kudo A (2002) Chem Mater 14(8):3369–3376
Yoshioka K, Petrykin V, Kakihana M, Kato H, Kudo A (2005) J Catal 232(1):102–107
Yang S, Gong Y, Zhang J, Zhan L, Ma L, Fang Z, Vajtai R, Wang X, Ajayan PM (2013) Adv Mater 25(17):2452–2456
Reddy J, Kurra S, Guje R, Palla S, Veldurthi NK, Ravi G, Vithal M (2015) Ceram Int 41(2):2869–2875
Wang X, Zhi L, Müllen K (2008) Nano Lett 8(1):323–327
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The authors would like to acknowledge the financial support from University of Zanjan and Iranian Nanotechnology Initiative.
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Nakhostin Panahi, P., Rasoulifard, M.H. & Hekmati, F. Photocatalytic discoloration of an azo-dye using LaMn0.5Ti0.5O3 double perovskite under visible light irradiation and enhancement of photocatalytic activity by using graphene. Reac Kinet Mech Cat 128, 539–554 (2019). https://doi.org/10.1007/s11144-019-01629-2
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DOI: https://doi.org/10.1007/s11144-019-01629-2