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Mesoporous organic–inorganic hybrid material containing hydrosilylated soybean oil

  • Original Paper: Sol-gel, hybrids and solution chemistries
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Abstract

Vegetable oils are attractive substrates for use as renewable feedstock in polymer industry. Hydrosilylation is a way to insert silicon groups in an olefin, and if the silylated olefin has hydrolysable groups, it can be used as precursor reagent in sol–gel synthesis. In this work, for the first time, the hydrosilylation of the vegetable soybean oil is reported, and it was used as sol–gel molecular precursor, along with tetraethylorthosilicate, varying their proportions. The obtained organic–inorganic silica-based hybrid material was characterized by infrared spectroscopy, N2 adsorption–desorption isotherms, scanning electron microscopy, and thermogravimetric analysis. The hybrid contains the oil chain covalently anchored, and it presents interesting textural characteristics, such as high surface area and mesoporosity, which seem not be markedly affected by the organic amount added.

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Acknowledgments

The authors thank to CNPq, CAPES, FAPERGS, and PROPESQ/UFRGS for financial support and grants. This work was also supported by PRONEX/CNPq/FAPERGS-04/0887-0 and 10/0050-6. The authors thank also the CME-UFRGS for SEM images.

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Authors and Affiliations

  1. Instituto de Química, Universidade Federal do Rio Grande do Sul, CP 15003, Porto Alegre, RS, CEP 91501-970, Brazil

    Rodrigo dos S. Fuscaldo, Eliana W. de Menezes, Martha F. S. Lima, Edilson V. Benvenutti & José R. Gregório

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  1. Rodrigo dos S. Fuscaldo
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  2. Eliana W. de Menezes
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  3. Martha F. S. Lima
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  4. Edilson V. Benvenutti
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  5. José R. Gregório
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Correspondence to José R. Gregório.

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Fuscaldo, R.d.S., de Menezes, E.W., Lima, M.F.S. et al. Mesoporous organic–inorganic hybrid material containing hydrosilylated soybean oil. J Sol-Gel Sci Technol 78, 457–464 (2016). https://doi.org/10.1007/s10971-016-3957-8

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  • DOI: https://doi.org/10.1007/s10971-016-3957-8

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