Abstract
Conductivity measurements in dilute aqueous solutions of L-glutamic acid, DL-glutamic acid, sodium-L-glutamate and magnesium-L-glutamate, were performed in the 288.15 to 323.15 K temperature range. The limiting molar conductivities of glutamic anions, λ o(HGlu−,T) and the dissociation constants of glutamic acid, K 2(T) were derived by the use of the Debye–Hückel equation for the activity coefficients and the Onsager, and Quint and Viallard conductivity equations.
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Greenstein, J.P., Winitz, M.: Chemistry of the Amino Acids. Wiley, New York (1961)
Edsall, J.T., Blanchard, M.H.: The activity ratio of zwitterions and uncharged molecules in ampholyte solutions. The dissociation constants of amino acid esters. J. Am. Chem. Soc. 55, 2353–2337 (1933)
Harris, L.J.: Note on the dissociation constants of certain amino acids, including valine, glutamic acid. J. Biol. Chem. 84, 179–181 (1929)
Miyamoto, S., Schmidt, C.L.A.: The apparent dissociation constants of phenylalanine and of dihydroxyphenylalanine and the apparent free energy and entropy changes of certain amino acids due to ionization. J. Biol. Chem. 90, 165–178 (1931)
Kortüm, G., Vogel, W., Andrussow, K.: Dissociation Constants of Organic Acids in Aqueous Solution. Butterworths, London (1961)
Robinson, R.A., Stokes, R.H.: Electrolyte Solutions, 2nd edn. Butterworths, London (1965)
Singh, R.K.P., Yadava, K.L.: Determination of the dissociation constants of α-amino acids by ionophoretic: II Amino acids with an additional functional group. J. Electrochem. Soc. India 34, 128–130 (1985)
Partanen, J.I., Juusola, P.M., Minkkinen, P.O.: Redetermination of the thermodynamic values of the first and second dissociation constants of glutamic acid in aqueous solutions at 298.15 K. Acta Chem. Scand. 52, 198–206 (1998)
Martell, A.E., Smith, R.M.: Amino Acids. Critical Stability Constants, vol. 1. Plenum, New York (1974)
Hoskins, W.M., Randall, M., Schmidt, C.L.A.: The conductance and activity coefficients of glutamic and aspartic acids and their monosodium salts. J. Biol. Chem. 88, 215–239 (1930)
Mehl, J.W., Schmidt, C.L.A.: The conductivities of aqueous solutions of glycine, d,l-valine and l-asparagine. J. Gen. Physiology 18, 467–479 (1935)
Rajeswari, M.R.: Electrostatic interactions between side chains of α-amino acids: conductance studies. J. Biochem. Mol. Biol. Biophys. 2, 287–292 (1999)
Apelblat, A., Azoulay, D., Sahar, A.: Properties of aqueous thorium nitrate solutions. Part 1, Densities, viscosities, conductivities, pH, solubility and activities at freezing point. J. Chem. Soc. Faraday Trans. I 69, 1618–1623 (1973)
Orekhova, Z., Ben-Hamo, M., Manzurola, E., Apelblat, A.: Electrical conductance and volumetric studies in aqueous solutions of nicotinic acid. J. Solution Chem. 34, 687–700 (2005)
Orekhova, Z., Sambira, Y., Manzurola, E., Apelblat, A.: Electrical conductance and volumetric studies in aqueous solutions of DL-pyroglutamic acid. J. Solution Chem. 34, 853–867 (2005)
Harned, H.S., Owen, B.B.: The Physical Chemistry of Electrolytic Solutions, 3rd edn. Reinhold, New York (1958)
Brummer, S.B., Hills, G.J.: Kinetics of ionic conductance. Trans. Faraday Soc. 57, 1816–1822 (1961)
Kielland, J.: Individual activity coefficients of ions in aqueous solutions. J. Am. Chem. Soc. 59, 1675–1678 (1937)
Harris, D.C.: Quantitative Chemical Analysis. Freeman, San Francisco (1982)
Quint, J.: Contribution à l’étude de la conductibilité électrique des mélanges d’électrolytes. PhD Thesis, University Clermont-Ferrand, April 1976
Quint, J., Viallard, A.: Electrical conductance of electrolyte mixtures of any type. J. Solution Chem. 7, 533–548 (1978)
Apelblat, A., Barthel, J.: Conductance studies on aqueous citric acid. Z. Naturforsch. 46a, 131–140 (1991)
Tsurko, E.N., Neueder, R., Barthel, J., Apelblat, A.: Conductivity of phosphoric acid, sodium, potassium, and ammonium phosphates in dilute aqueous solutions from 278.15 K to 308.15 K. J. Solution Chem. 28, 973–999 (1999)
Apelblat, A.: Dissociation constants and limiting conductances of organic acids in water. J. Mol. Liq. 95, 99–145 (2002)
Apelblat, A., Bešter-Rogač, M., Barthe, J., Neueder, R.: An analysis of electrical conductances of aqueous solutions of polybasic organic acids. Benzenehexacarboxylic (mellitic) acid and its neutral and acidic salts. J. Phys. Chem. B 110, 8893–8906 (2006)
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Apelblat, A., Manzurola, E. & Orekhova, Z. Electrical Conductance Studies in Aqueous Solutions with Glutamic Ions. J Solution Chem 36, 891–900 (2007). https://doi.org/10.1007/s10953-007-9156-z
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DOI: https://doi.org/10.1007/s10953-007-9156-z