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Volumetric Properties of Aqueous Binary Mixtures of 1-Butanol, Butanediols, 1,2,4-Butanetriol and Butanetetrol at 298.15 K

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Abstract

Excess molar volumes, V m E, and partial molar volumes, ↕ 2, have been determined for dilute aqueous solutions of 1-butanol, 1,2-butanediol, 2,3-butanediol, 1,3-butanediol, 1,4-butanediol, 1,2,4-butanetriol and 1,2,3,4-butanetetrol (erythritol) at 298.15 K, as a function of composition from density measurements. The limiting partial molar volumes, ↕ 2∞, of alcohols in aqueous solution are evaluated through extrapolation. Interactions of the different solutes with water are discussed in terms of the relationship among polar and non-polar groups on water structure and the effect of the position of hydroxyl groups in the molecule.

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Authors and Affiliations

  1. Departamento de Química, Universidad Nacional de Colombia, Bogotá, Colombia

    Carmen M. Romero

  2. Departamento de Química, Universidad de Córdoba, Montería, Colombia

    Manuel S. Páez

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  1. Carmen M. Romero
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  2. Manuel S. Páez
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Correspondence to Carmen M. Romero.

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Romero, C.M., Páez, M.S. Volumetric Properties of Aqueous Binary Mixtures of 1-Butanol, Butanediols, 1,2,4-Butanetriol and Butanetetrol at 298.15 K. J Solution Chem 36, 237–245 (2007). https://doi.org/10.1007/s10953-006-9106-1

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  • DOI: https://doi.org/10.1007/s10953-006-9106-1

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