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Fabrication of ordered mesoporous carbons with tunable pore architecture by the cosolvent

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Abstract

Ordered mesoporous carbons (OMCs) with tunable mesophase were prepared by a novel cosolvent method using low molecular resin as carbon precursor, and P123(Poly(ethyleneoxide)-poly(propyleneoxide)-poly(ethyleneoxide)triblock copolymers, EO20PO70EO20) as a template via an Evaporation-induced Self-assembly Process (EISA). The results show that the pore structure of OMCs could be oriented from 2D hexagonal (p6mm) to 2D centered rectangular (C2mm) structure. Two key descriptors of mesophase were identified. One is the ratio of PEO/PPO of triblock copolymer, and the other one is cosolvent, both of which would have effects on the interface of mesophase during the EISA process. Furthermore, it was confirmed that the ordered mesophase could be obtained in a very short time during the EISA process even accompanied by the microemulsion phenomenon.

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References

  1. S. Abouali, M. Akbari Garakani, J.K. Kim, Electrochim. Acta 284, 436–443 (2018)

    Article  CAS  Google Scholar 

  2. J. Deng, X. Yu, X. Qin, B. Liu, Y.B. He, B. Li, F. Kang, Energy Storage Mater. 11, 184–190 (2018)

    Article  Google Scholar 

  3. C. Liang, S. Dai, J. Am. Chem. Soc. 128, 5316–5317 (2006)

    Article  CAS  PubMed  Google Scholar 

  4. H. Chen, Q. Li, N. Teng, D. Long, C. Ma, Y. Wei, J. Wang, L. Ling, Electrochim. Acta 214, 231–240 (2016)

    Article  CAS  Google Scholar 

  5. X. Peng, F. Hu, J. Huang, Y. Wang, H. Dai, Z. Liu, Microp. Mesopor. Mater. 228, 196–206 (2016)

    Article  CAS  Google Scholar 

  6. F. Liu, Z. Guo, H. Ling, Z. Huang, D. Tang, Microp. Mesopor. Mater. 227, 104–111 (2016)

    Article  CAS  Google Scholar 

  7. W. Xu, Z. Wu, S. Tao, J. Mater. Chem. A 4, 16272–16287 (2016)

    Article  CAS  Google Scholar 

  8. Y. Liang, Z. Li, X. Yang, R. Fu, D. Wu, Chem. Commun. 49, 9998–10000 (2013)

    Article  CAS  Google Scholar 

  9. A.H. Lu, G.P. Hao, Q. Sun, X.Q. Zhang, W.C. Li, Macromol. Chem. Phys. 213, 1107–1131 (2012)

    Article  CAS  Google Scholar 

  10. Q. Shi, R. Zhang, Y. Lv, Y. Deng, A.A. Elzatahrya, D. Zhao, Carbon, 84, 335–346 (2015)

    Article  CAS  Google Scholar 

  11. Y. Liang, Z. Li, R. Fu, D. Wu, J. Mater. Chem. A 1, 3768–3773 (2013)

    Article  CAS  Google Scholar 

  12. M. Barczak, K. Michalak-Zwierz, K. Gdula, K. Tyszczuk-Rotko, R. Dobrowolski, A. Dąbrowski, Microporous Mesoporous Mater. 211, 162–173 (2015)

    Article  CAS  Google Scholar 

  13. C. He, X. Hu, Ind. Eng. Chem. Res. 50, 14070–14083 (2011)

    Article  CAS  Google Scholar 

  14. D. Zhang, L. Zheng, Y. Ma, L. Lei, Q. Li, Y. Li, H. Luo, H. Feng, Y. Hao, ACS. Appl. Mater. Interface 6, 2657–2665 (2014)

    Article  CAS  Google Scholar 

  15. M. Enterría, J.L. Figueiredo, Carbon 108, 79–102 (2016)

    Article  CAS  Google Scholar 

  16. D. Zhang, M. Han, Y. Li, B. Wang, K. Wang, Y. Wang, T. Yang, J. He, H. Feng, J. Porous. Mater. 25, 29–35 (2017)

    Article  CAS  Google Scholar 

  17. R. Ryoo, S.H. Joo, S. Jun, J. Phys. Chem. B 103, 7743–7747 (1999)

    Article  CAS  Google Scholar 

  18. A. Sánchez-Sánchez, V. Fierro, M.T. Izquierdo, A. Celzard, J. Mater. Chem. A 4, 6140–6148 (2016)

    Article  CAS  Google Scholar 

  19. G.P. Mane, S.N. Talapaneni, K.S. Lakhi, H. Ilbeygi, U. Ravon, K. Al-Bahily, T. Mori, D.-H. Park, A. Vinu, Angew. Chem. Int. Ed. 56, 8481–8485 (2017)

    Article  CAS  Google Scholar 

  20. H. Tan, J. Tang, X. Zhou, D. Golberg, S.K. Bhatia, Y. Sugahara, Y. Yamauchi, Chem. Commun. 54, 9494–9497 (2018)

    Article  CAS  Google Scholar 

  21. P. Li, Y. Song, Q. Lin, J. Shi, L. Liu, L. He, H. Ye, Q. Guo, Microp. Mesopor. Mater. 159, 81–86 (2012)

    Article  CAS  Google Scholar 

  22. P.W. Xiao, L. Zhao, Z.-Y. Sui, M.Y. Xu, B.-H. Han, Microp. Mesopor. Mater. 253, 215–222 (2017)

    Article  CAS  Google Scholar 

  23. H. Wang, W. Wang, M. Asif, Y. Yu, Z. Wang, J. Wang, H. Liu, J. Xiao, Nanoscale 7, 15534–15541 (2017)

    Article  Google Scholar 

  24. G. Hasegawa, K. Kanamori, T. Kiyomura, H. Kurata, T. Abe, K. Nakanishi, Chem. Mater. 28, 3944–3950 (2016)

    Article  CAS  Google Scholar 

  25. N. Liu, H. Song, X. Chen, J. Mater. Chem. 21, 5345–5351 (2011)

    Article  CAS  Google Scholar 

  26. Q. Zhang, F. Matsuoka, H.S. Suh, P.A. Beaucage, S. Xiong, D.M. Smilgies, K.W. Tan, J.G. Werner, P.F. Nealey, U.B. Wiesner, ACS Nano 12, 347–358 (2017)

    Article  CAS  PubMed  Google Scholar 

  27. G. Deng, Y. Zhang, C. Ye, Z. Qiang, G.E. Stein, K.A. Cavicchi, B.D. Vogt, Chem. Commun. 50, 12684–12687 (2014)

    Article  CAS  Google Scholar 

  28. M. Zhao, D.-L. Zhao, X.-Y. Han, H.-X. Yang, Y.-J. Duan, X.M. Tian, Electrochim. Acta 287, 21–28 (2018)

    Article  CAS  Google Scholar 

  29. T.Y. Ma, L. Liu, Z.Y. Yuan, Chem. Soc. Rev. 42, 3977–4003 (2013)

    Article  CAS  PubMed  Google Scholar 

  30. H. Sai, K.W. Tan, K. Hur, E. Asenath-Smith, R. Hovden, Y. Jiang, M. Riccio, D.A. Muller, V. Elser, L.A. Estroff, S.M. Gruner, U. Wiesner, Science 341, 530–534 (2013)

    Article  CAS  PubMed  Google Scholar 

  31. J. Gorka, C. Fenning, M. Jaroniec, Colloids Surf. A 352, 113–117 (2009)

    Article  CAS  Google Scholar 

  32. J. Choma, K. Jedynak, M. Marszewski, M. Jaroniec, Adsorption 19, 563–569 (2013)

    Article  CAS  Google Scholar 

  33. P. Li, Y. Song, Z. Tang, G. Yang, Q. Guo, L. Liu, J. Yang, J. Colloid Interface Sci. 401, 161–163 (2013)

    Article  CAS  PubMed  Google Scholar 

  34. D. Zhao, Q. Huo, J. Feng, J. Kim, Y. Han, G.D. Stucky, Chem. Mater. 11, 2668–2672 (1999)

    Article  CAS  Google Scholar 

  35. C.M. Yang, C.Y. Lin, Y. Sakamoto, W.C. Huang, L.L. Chang, Chem. Commun. 45, 5969–5971 (2008)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The research was supported by the financial support of the Shanxi Province Foundation for Youths (2015021072), the Program for the Innovative Talents of Taiyuan Institute of Technology (TITXD201403), Special Youth Science and Technology Innovation (QKCZ201635), National Training Programs of Innovation and Entrepreneurship for Undergraduates (201614101004), the Fund for Shanxi “1331 Project” Key Subjects Construction and greatly thanks Fund of Testing from Institute of High Energy and Physics for SAXS measurements assistance.

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Authors and Affiliations

  1. Department of Materials Engineering, Taiyuan Institute of Technology, Taiyuan, 030008, Shanxi, China

    Peng Li, Xiaoxiao Ma, Yanliang Zhao, Junhua Tan, Fei Liu & Kaijin Zhu

  2. School of Materials Science and Engineering, North University of China, Taiyuan, 030051, China

    Xiaoxiao Ma

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  1. Peng Li
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  2. Xiaoxiao Ma
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  3. Yanliang Zhao
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  4. Junhua Tan
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Correspondence to Peng Li.

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Li, P., Ma, X., Zhao, Y. et al. Fabrication of ordered mesoporous carbons with tunable pore architecture by the cosolvent. J Porous Mater 26, 1131–1135 (2019). https://doi.org/10.1007/s10934-018-0715-z

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  • DOI: https://doi.org/10.1007/s10934-018-0715-z

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