Abstract
In this paper, a nanometer-sized spherical carbon black (CB) with an average diameter of 30 nm was utilized to construct the compact carbon structure aiming at the electrode for high volumetric capacitance supercapacitors. The CB surface was modified by oxygen-doping to enhance the reaction with the electrolyte ions. BET result shows that oxygen-doping leads to the significant drop in both the SSA and the total pore volume of CB. Electrochemical measurement demonstrates that the oxygen-doped CB behaves an outstanding capacitive performance, its volumetric capacitance and gravimetric capacitance being up to 253 F cm−3 and 233 F g−1, almost 21.2 times improvement in comparison to those of the pristine CB (12 F cm−3 and 11 F g−1), respectively. Moreover, the oxygen-doped CB also exhibits an excellent cyclic stability, its capacitance remains 91.6% even after 10,000 cycles. Because of its advantages in mass production and low cost, the nano-sized carbon black can be considered as a competitive candidate for the mass production of the electrode materials for high volumetric performance supercapacitors.
Similar content being viewed by others
References
P. Simon, Y. Gogotsi, Materials for electrochemical capacitors. Nat. Mater. 7, 845–854 (2008)
Y. Yun, S. Cho et al., Microporous carbon nanoplates from regenerated silk proteins for super-capacitors. Adv. Mater. 25, 1993–1998 (2013)
J.R. Miller, R.A. Outlaw, B.C. Holloway, Graphene double-layer capacitor with ac line-filtering performance. Science 329, 1637–1639 (2010)
L. Wei, M. Sevilla et al., Polypyrrole-derived activated carbons for high-performance electrical double-layer capacitors with ionic liquid electrolyte. Adv. Funct. Mater. 22, 827–834 (2012)
P.-C. Gao, W.-Y. Tsai et al., Graphene-like carbide derived carbon for high-power supercapacitors. Nano Energy 12, 197–206 (2015)
L. Hao, X. Li, L. Zhi, Carbonaceous electrode materials for supercapacitors. Adv. Mater. 28, 3899–3904 (2013)
H. Cheng, L. Long, D. Shu, J. Wu, Y. Gong, C. He, et al., The supercapacitive behavior and excellent cycle stability of graphene/MnO2 composite prepared by an electrostatic self-assembly process. Int. J. Hydrog. Energy 39, 16151–16161 (2014)
J. Yan, T. Wei, Z. Fan, et al., Interconnected frameworks with a sandwiched porous carbon layer/graphene hybrids for supercapacitors with high gravimetric and volumetric performances. Adv. Energy Mater. 4, 140500 (2014)
Y. Li, Z. Dan, Preparation of reduced graphite oxide with high volumetric capacitance in super-capacitors. Chem. Commun. 51, 5598 (2015)
N. Jung, S. Kwon, et al., Synthesis of chemically bonded graphene/carbon nanotube composites and their application in large volumetric capacitance supercapacitors, Adv. Mater. 25, 6854–6858 (2013)
J. Yan, T. Wei et al., Template-assisted low temperature synthesis of functionalized graphene for ultrahigh volumetric performance supercapacitors, ACS Nano 8, 4720–4729 (2014)
F. Gao et al., Ultrahigh volumetric capacitance and cyclic stability of fiuorine and nitrogen co-doped carbon microspheres. Nat. Commun. 6, 8503 (2015)
N. Jäckel, D. Weingarth, M. Zeiger, M. Aslan, I. Grobelsek, V. Presser, Comparison of carbon onions and carbon blacks as conductive additives for carbon supercapacitors in organic electrolytes. J. Power Sources 272, 1122–1133 (2014)
H.W. Kroto, Carbon onions introduce new flavour to fullerene studies. Nature 359, 670–671 (1992)
P. Yan, J. Xu, X. Zhang, R. Zhang, Fabrication and enhanced supercapacitive performance of graphene/nano-carbide derived carbon composites. Int. J. Hydrog. Energy 41, 14820–14829 (2016)
F. Zeng, Y. Kuang, N. Zhang, Z. Huang, Y. Pan, Z. Hou et al., Multilayer super-short carbon nanotube/reduced graphene oxide architecture for enhanced supercapacitor properties. J. Power Sources 247, 396–401 (2014)
G. Milczarek, A. Ciszewski, I. Stepniak, Oxygen-doped activated carbon fiber cloth as electrode material for electrochemical capacitor. J. Power Sources 196, 7882–7885 (2011)
T. Shang, R. Ren, Y. Zhu, X. Jin, Oxygen- and nitrogen-co-doped activated carbon from waste particleboard for potential application in high-performance capacitance. Electrochim. Acta 163, 32–40 (2015)
D. Zha, P. Xiong, X. Wang, Strongly coupled manganese ferrite/carbon black/polyaniline hybrid for low-cost supercapacitors with high rate capability. Electrochim. Acta 185, 218–228 (2015)
S. Biniak, G. Szymanski, J. Siedlewski, A. Swiatkowski, The characterization of activated carbons with oxygen and nitrogen surface groups. Carbon 35, 1799–1810 (1997)
Y.N. Sudhakar, H. Hemant, S.S. Nitinkumar, P. Poornesh, M. Selvakumar, Green synthesis and electrochemical characterization of rGO–CuO nanocomposites for supercapacitor applications. Ionics 23(2), 1267–1276 (2017)
Z. Yu, L. Chen, L. Song, S. Yu, Free-standing boron and oxygen co-doped carbon nanofiber films for large volumetric capacitance and high rate capability supercapacitors. Nano Energy 15, 235–243 (2015)
B.E. Conway, Electrochemical Supercapacitors: Scientific Fundamentals and Technological Applications (Kluwer Academic Plenum Publisher, New York, 1999)
H. Wu, X. Wang, The effects of electrolyte on the supercapacitive performance of activated calcium carbide-derived carbon. J. Power Sources 226, 202–209 (2013)
Acknowledgements
Project 51872253 supported by National Natural Science Foundation of China.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Liu, Y., Zhang, X., Liu, K. et al. Huge enhancement in supercapacitive performance of oxygen-doped nano-carbon black. J Porous Mater 26, 1171–1176 (2019). https://doi.org/10.1007/s10934-018-0702-4
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10934-018-0702-4