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Synthesis of carbon molecular sieve microspheres via amino phenolic resin as precursor formed from in-situ reaction composite micelles

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Abstract

The carbon molecular sieve microspheres (CMSm) is one kind of porous carbonaceous materials. Owing to its high surface area and stability, CMSm have been attracted immense attention in various fields. In this study, the CMSm with tunable pore structure has been synthesized via self-assembling, in-situ reaction and soft-templating method in aqueous system. Meanwhile, the influence of carbonization temperature, heating rate, surfactant content and the amount of pore-forming agent (1, 3, 5-trimethylbenzene) on the morphology and pore properties of CMSm were studied. The result of nitrogen adsorption/desorption analysis indicates that the volume of the micropores increases as carbonization temperature increases, and generally decreases as the heating rate increases. The amount of surfactant and pore-forming agent have little influence on the volume of the micropores. It is also found that the CMSm have good hydrogen storage performance.

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Acknowledgements

This work was financially supported by the Natural Science Foundation of China (Nos. 21171004, 20771004), the Project of science and technology project of Anhui Province (No. 1604a0802113), Anhui Province Academic Technology Leader Training Funded Projects, and the Research Team Project of Functional Polymer and Chemical Building Materials of Anhui Province Key Laboratory of Advanced Building Materials.

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Authors and Affiliations

  1. Anhui Key Laboratory of Advanced Building Materials, Anhui Jianzhu University, Hefei, 230601, People’s Republic of China

    Jin Liu, Yong-fei Xu, Zhen Li & Xian-biao Wang

  2. School of Materials Science and Chemical Engineering, Anhui Jianzhu University, Hefei, 230601, People’s Republic of China

    Xiao-hui Ding, Sai-sai Chen, Jin Liu, Yong-fei Xu, Zhen Li & Xian-biao Wang

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  1. Xiao-hui Ding
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  2. Sai-sai Chen
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  3. Jin Liu
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  4. Yong-fei Xu
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  5. Zhen Li
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  6. Xian-biao Wang
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Correspondence to Jin Liu.

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Ding, Xh., Chen, Ss., Liu, J. et al. Synthesis of carbon molecular sieve microspheres via amino phenolic resin as precursor formed from in-situ reaction composite micelles. J Porous Mater 25, 1373–1380 (2018). https://doi.org/10.1007/s10934-017-0549-0

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  • DOI: https://doi.org/10.1007/s10934-017-0549-0

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