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Synthesis and Self-assembling Properties of 2,2′:6′,2″-Terpyridine-Based Carbon Nanotube Coordination Polymers

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Abstract

A novel metallo-supramolecular polytopic ligand was synthesized from the attachment reaction involving an amino group-functionalized multi-wall carbon nanotube and 4-chloro-2,2′:6′,2″-terpyridine used for the preparation of metallo-supramolecular polymers with Co(II) or Ni(II) ions. Different colors were observed depending on either the ligands or the metal ions in this type of supramolecular assembly. The created supramolecular polymers were characterized by means of structure, morphology, and stimuli-responsive performance employing scanning electron microscopy, amperometric techniques, UV–Vis and Fourier transform infrared spectroscopy. UV–Vis spectroscopy and cyclic voltammetry studies confirmed that both the optical and electrochemical properties of metallo-supramolecular materials are affected by the substituent at the pyridine periphery.

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Acknowledgments

Authors would like to thank TÜBİTAK—The Scientific and Technological Research Council of Turkey for the financial support with the project number TBAG110T153 and MAG110M751.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Sciences and Literature, Inonu University, 44280, Malatya, Turkey

    Süleyman Köytepe & Turgay Seçkin

  2. Department of Chemistry, Faculty of Sciences, Firat University, 23100, Elazig, Turkey

    M. Hurşit Demirel

Authors
  1. Süleyman Köytepe
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  2. M. Hurşit Demirel
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  3. Turgay Seçkin
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Correspondence to Turgay Seçkin.

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Köytepe, S., Demirel, M.H. & Seçkin, T. Synthesis and Self-assembling Properties of 2,2′:6′,2″-Terpyridine-Based Carbon Nanotube Coordination Polymers. J Inorg Organomet Polym 23, 1104–1112 (2013). https://doi.org/10.1007/s10904-013-9894-x

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  • DOI: https://doi.org/10.1007/s10904-013-9894-x

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