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Supramolecular Structures Constructed by Connection of One-Dimensional Polymer Chains Through the Dimeric Water Clusters in Coordination Polymers of Pyromellitate Ligand

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Abstract

Three mixed-ligand coordination polymers [Cu(H2pm)(na)2(H2O)2] n ·4nH2O (1), [Ni(H2pm)(pa)2] n ·4nH2O (2), [Co(H2pm)(pa)2] n ·4nH2O (3) (H2pm = dianion of pyromellitic acid, na = nicotinamide, pa = picolinamide) were investigated mainly from the point of supramolecular architecture in their respective crystal packings. The structural properties of 1–3 were characterized by X-ray diffraction technique and Fourier transform infrared (FT-IR) spectroscopy. In all complexes, the metal centers are bridged by pyromellitate ligands to form 1D polymer chains of 2,2-TT type. However, these chains propagate in a different way as linear or zig-zag fashions. The polymer chains are connected by N–H···O hydrogen bonds to form sheet structures which include dimeric water clusters. The complexes have different supramolecular networks with respect to the behavior of dimeric water clusters between the sheet structures. The FT-IR investigation of the complexes was performed within the mid-IR region, mainly focusing on the characteristic vibrations of pyromellitic acid, nicotinamide and picolinamide moieties by considering their free states and ligand behaviours in the case of complex formation. The magnetic properties of 1–3 were investigated by electron paramagnetic resonance (EPR) spectroscopy and magnetic susceptibility measurements. EPR studies of 1 and 2 show that the paramagnetic centers have axially symmetric g values and unpaired electrons are dominantly in \( d_{{x^{2} - y^{2} }} \) ground state. The magnetic susceptibility results indicate possible antiferromagnetic (1 and 2) and ferromagnetic (3) couplings mediated by the carboxylate bridges between the metal centers.

Graphical Abstract

The adjacent supramolecular sheets are linked by dimeric water clusters.

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References

  1. Y. Kang, C. Seward, D. Song, S. Wang, Inorg. Chem. 42, 2789 (2003)

    Article  CAS  Google Scholar 

  2. A.K. Ghosh, D. Ghoshal, T.-H. Lu, G. Mostafa, N.R. Chaudhuri, Cryst. Growth Des. 4, 851 (2004)

    Article  CAS  Google Scholar 

  3. S.R. Batten, R. Robson, Angew. Chem. Int. Ed. 37, 1460 (1998)

    Article  Google Scholar 

  4. M.J. Zaworotko, Chem. Commun. 37, 1 (2001)

    Article  Google Scholar 

  5. H. Carlsson, M. Haukka, A. Bousseksou, J.-M. Latour, E. Nordlander, Inorg. Chem. 43, 8252 (2004)

    Article  CAS  Google Scholar 

  6. L.J. Zhang, J.Q. Xu, Z. Shi, W. Xu, T.G. Wang, Dalton Trans. 6, 1148 (2003)

    Article  Google Scholar 

  7. N.W. Ockwig, O. Delgado-Friedrichs, M. O’Keeffe, O.M. Yaghi, Acc. Chem. Res. 38, 176 (2005)

    Article  CAS  Google Scholar 

  8. S.G. Ang, B.W. Sun, Cryst. Growth Des. 5, 383 (2005)

    Article  CAS  Google Scholar 

  9. S.-I. Noro, H. Miyasaka, S. Kitagawa, T. Wada, T. Okubo, M. Yamashita, T. Mitani, Inorg. Chem. 44, 133 (2005)

    Article  CAS  Google Scholar 

  10. P. Diaz, J. Benet-Buchholz, R. Vilar, A.J.P. White, Inorg. Chem. 45, 1617 (2006)

    Article  CAS  Google Scholar 

  11. F.S. Delgado, J. Sanchiz, C. Ruiz-Pérez, F. Lloret, M. Julve, Inorg. Chem. 42, 5938 (2003)

    Article  CAS  Google Scholar 

  12. Q. Shi, R. Cao, D.-F. Sun, M.-C. Hong, Y.-C. Liang, Polyhedron 20, 3287 (2001)

    Article  CAS  Google Scholar 

  13. D.-Q. Chu, J.-Q. Xu, L.-M. Duan, T.-G. Wang, A.-Q. Tang, L. Ye, Eur. J. Inorg. Chem. 5, 1135 (2001)

    Article  Google Scholar 

  14. J.-Z. Zou, Q. Liu, Z. Xu, X.-Z. You, X.-Y. Huang, Polyhedron 17, 1863 (1998)

    Article  CAS  Google Scholar 

  15. J. Cho, A.J. Lough, J.C. Kim, Inorg. Chim. Acta 342, 305 (2003)

    Article  CAS  Google Scholar 

  16. F.D. Rochon, G. Massarweh, Inorg. Chim. Acta 304, 190 (2000)

    Article  CAS  Google Scholar 

  17. Y. Li, N. Hao, Y. Lu, E. Wang, Z. Kang, C. Hu, Inorg. Chem. 42, 3119 (2003)

    Article  CAS  Google Scholar 

  18. G.M. Sheldrick, SHELXS-97 and SHELXL-97 (University of Göttingen, Germany, 1997)

    Google Scholar 

  19. L.J. Farrugia, J. Appl. Cryst. 32, 837 (1999)

    Article  CAS  Google Scholar 

  20. L.J. Farrugia, J. Appl. Cryst. 30, 565 (1997)

    Article  CAS  Google Scholar 

  21. C.F. Macrae, P.R. Edgington, P. McCabe, E. Pidcock, G.P. Shields, R. Taylor, M. Towler, J. van de Streek, J. Appl. Crystallogr. 39, 453 (2006)

    Article  CAS  Google Scholar 

  22. K. Brandenburg, DIAMOND, Demonstration Version 3.1.e (Crystal Impact GbR, Bonn, 2006)

    Google Scholar 

  23. J. Černák, M. Orendáč, I. Potočňák, J. Chomič, A. Orendáčováš, J. Skoršepa, A. Feher, Coord. Chem. Rev. 224, 51 (2002)

    Article  Google Scholar 

  24. A.S. Abd-El-Aziz, I. Manners, J. Inorg. Organomet. Polym Mater. 15, 157 (2005)

    Article  CAS  Google Scholar 

  25. R.D. Willet, Z. Wang, S. Molnar, K. Brewer, C.P. Landee, M.M. Turnbull, W. Zhang, Mol. Cryst. Liq. Cryst. 233, 277 (1993)

    Article  Google Scholar 

  26. A.F. Wells, Structural Inorganic Chemistry, 5th edn. (Clarendon Press, Oxford, 1984)

    Google Scholar 

  27. J.D. Lee, Concise Inorganic Chemistry, 4th edn. (Chapman and Hall Ltd, London, 1991)

    Google Scholar 

  28. S.-F. Si, R.-J. Wang, Y.-D. Li, Inorg. Chem. Commun. 6, 1152 (2003)

    Article  CAS  Google Scholar 

  29. J.-X. Juan, H.-P. Xiao, M.-L. Hu, Z. Kristallogr, NCS 219, 224 (2004)

    Google Scholar 

  30. R. Diniz, H.A. Abreu, W.B. Almeida, M.T. Sansiviero, N.G. Fernandes, Eur. J. Inorg. Chem. 6, 1115 (2002)

    Article  Google Scholar 

  31. J.C. Kim, H. Jo, A.J. Lough, J. Cho, U. Lee, S.Y. Pyun, Inorg. Chem. Commun. 6, 474 (2003)

    Article  CAS  Google Scholar 

  32. O. Fabelo, J. Pasán, F. Lloret, M. Julve, C. Ruiz-Pérez, CrystEngComm 9, 815 (2007)

    Article  CAS  Google Scholar 

  33. M.C. Etter, Acc Chem. Res. 23, 120 (1990)

    Article  CAS  Google Scholar 

  34. J. Bernstein, R.E. Davis, L. Shimoni, N.L. Chang, Angew. Chem. Int. Ed. Engl. 34, 1555 (1995)

    Article  CAS  Google Scholar 

  35. R. Diniz, H.A. de Abreu, W.B. de Almeida, N.G. Fernandes, M.T.C. Sansiviero, Spectrochim. Acta Part A 61, 1747 (2005)

    Article  Google Scholar 

  36. J. Cho, A.J. Lough, J.C. Kim, Inorg. Chim. Acta 342, 305 (2003)

    Article  CAS  Google Scholar 

  37. P. Novak, S. Sekusak, D.V. Topic, Z. Popovic, J. Chem. Soc. Faraday Trans. 94, 1051 (1998)

    Article  CAS  Google Scholar 

  38. Q. Shi, R. Cao, D.F. Sun, M.C. Hong, Y.C. Liang, Polyhedron 20, 3287 (2001)

    Article  CAS  Google Scholar 

  39. D. Rabiger, M. Joullié, J. Org. Chem. 26, 1649 (1961)

    Article  CAS  Google Scholar 

  40. H. Paşaoğlu, S. Güven, Z. Heren, O. Büyükgüngör, J. Mol. Struct. 794, 270 (2006)

    Article  Google Scholar 

  41. S. Tyagi, S.M. Singh, S. Gencaslan, W.S. Sheldrick, P. Singh, Met.-Based Drugs 8, 337 (2002)

    Article  Google Scholar 

  42. M.S. Soylu, O.Z. Yeşilel, B. Karabulut, O. Büyükgüngör, Polyhedron 28, 2487 (2009)

    Article  CAS  Google Scholar 

  43. İ. Uçar, B. Karabulut, A. Bulut, O. Büyükgüngör, J. Mol. Struct. 834–836, 336 (2007)

    Article  Google Scholar 

  44. İ. Bulut, İ. Uçar, B. Karabulut, A. Bulut, J. Mol. Struct. 834–836, 276 (2007)

    Article  Google Scholar 

  45. M.K. Bhunia, S.K. Das, M.M. Seikh, K.V. Domasevitch, A. Bhaumik, Polyhedron 30, 2218 (2011)

    Article  CAS  Google Scholar 

  46. O. Fabelo, J. Pasán, L. Cañadillas-Delgado, F.S. Delgado, A. Labrador, F. Lloret, M. Julve, C. Ruiz-Pérez, Cryst. Growth Des. 8, 3984 (2008)

    Article  CAS  Google Scholar 

  47. İ. Uçar, E. Bozkurt, C. Kazak, A. Bulut, Spectrochim. Acta Part A 72, 11 (2009)

    Article  Google Scholar 

  48. M.J. Bew, B.J. Hathaway, R.F. Faraday, J. Chem. Soc. Dalton. Trans. 1229 (1972)

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Acknowledgment

This study has been supported financially by Ondokuz Mayıs University (Project No: PYO.FEN.1904.10.07). The authors sincerely thank to Prof. Dr. Orhan Büyükgüngör for data acquisition.

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Authors and Affiliations

  1. Department of Physics, Faculty of Arts and Sciences, Ondokuz Mayıs University, Samsun, Turkey

    Gökhan Kaştaş, Tuğba Ak Aycan, Hümeyra Paşaoğlu, Can Kocabıyık & Bünyamin Karabulut

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  1. Gökhan Kaştaş
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  2. Tuğba Ak Aycan
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  3. Hümeyra Paşaoğlu
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  4. Can Kocabıyık
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Correspondence to Gökhan Kaştaş.

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Kaştaş, G., Aycan, T.A., Paşaoğlu, H. et al. Supramolecular Structures Constructed by Connection of One-Dimensional Polymer Chains Through the Dimeric Water Clusters in Coordination Polymers of Pyromellitate Ligand. J Inorg Organomet Polym 22, 1003–1015 (2012). https://doi.org/10.1007/s10904-012-9686-8

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