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Microwave—assisted hydrothermal synthesis of monoclinic bismuth trioxide nanorods: optical and photocatalytic properties

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Abstract

Herein, the successful synthesis of bismuth trioxide (Bi2O3) nanorods via a new microwave-assisted hydrothermal technique is reported. Detailed characterizations for the prepared nanorods employing various analytical techniques were considered for their structural, compositional, morphological, optical and photocatalytic properties. The detailed results confirmed that the prepared nanorods have a well-crystalline structure, growing with a high density and having pure monoclinic crystal structure. The prepared nanorods exhibited good optical properties were confirmedly the room-temperature photoluminescence (PL) spectroscopy. The as-prepared Bi2O3 nanorod structures showed efficient photocatalytic activity for the degradation of methyl orange (MO) dyes under the application of UV light irradiation (365 nm). The pseudo-first order reaction rate constant is 0.007 min− 1. The fabricated Bi2O3 nanorods are very useful as ultraviolet light activated photocatalyst nanorod materials for decomposing methyl orange and various types of organic dyes.

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References

  1. F. Al-Hazmi, F. Alnowaiser, A.A. Al-Ghamdi, A.A. Al-Ghamdi, M.M. Aly, R.M. Al-Tuwirqi, F. El-Tantawy, A new large-scale synthesis of magnesium oxide nanowires: Structural and antibacterial properties. Superlattices Microstruct. 52, 200–209 (2012)

    Article  Google Scholar 

  2. A.K. Singh, U.T. Nakate, Microwave synthesis, characterization and photocatalytic properties of SnO2 nanoparticles, Adv. Nanoparticles, 2, 66–70, (2013).

    Article  Google Scholar 

  3. X. Liu, H. Cao, J. Yin, Generation and photocatalytic activities of Bi and Bi2O3 microspheres. Nano Res. 4(5), 470–482, (2011).

    Article  Google Scholar 

  4. S. Anandan, G.-J. Lee, P.-K. Chen, C. Fan, J.J. Wu, Removal of orange II dye in water by visible light assisted photocatalytic ozonation using Bi2O3 and Au/ Bi2O3 nanorods. Ind. Eng. Chem. Res. 49, 9729–9737 (2010).

    Article  Google Scholar 

  5. L. Zhou, W. Wang, H. Xu, S. Sun, M. Shang, Bi2O3 hierarchical nanostructures: controllable synthesis, growth mechanism, and their application in photocatalysis. Chem. Eur. J. 15, 1776–1782, (2009).

    Article  Google Scholar 

  6. S. Park, S. Kim, S. Lee, C. Lee, Acetone gas-sensing properties of multiple-networked Pd-decorated Bi2O3 nanorod sensors. Bull. Korean Chem. Soc. 36, 468–472, (2015).

    Google Scholar 

  7. X. Gou, R. Li, G. Wang, Z. Chen, D. Wexler, Room-temperature solution synthesis of Bi2O3 nanowires for gas sensing application, Nanotechnology, 20, 495501, (2009).

    Article  Google Scholar 

  8. X. Luan, J. Jiang, Q. Yang, M. Chen, M. Zhang, L. Li, Facile Synthesis of bismuth oxidenanoparticles by a hydrolysis solvothermal route and their visible light photocatalytic activity, Environ. Eng. Manag. J. 14(3),703–707, (2015).

    Google Scholar 

  9. S. Li, R. Nechache, I.A.V. Davalos, G. Goupil, L. Nikolova, M. Nicklaus, J. Laverdiere, A. Ruediger, F. Rosei, Ultrafast microwave hydrothermal synthesis of BiFeO3 nanoplates, J. Am. Ceram. Soc. 96 (10), 3155–3162, (2013).

    Google Scholar 

  10. R. Kumar, G. Kumar, A. Umar, ZnO nano-mushrooms for photocatalytic degradation of methyl orange, Mater. Lett. 97, 100–103 (2013).

    Article  Google Scholar 

  11. B. Ling, X.W. Sun, J.L. Zhao, Y.Q. Shen, Z.L. Dong, L.D. Sun, S.F. Li, S. Zhang, One-dimensional single-crystalline bismuth oxide micro/nanoribbons: morphology-controlled synthesis and luminescent properties. J. Nanosci. Nanotechnol. 10, 8322–8327 (2010).

    Article  Google Scholar 

  12. C.-H. Ho, C.-H. Chan, Y.-S. Huang, L.-C. Tien, L.-C. Chao, The study of optical band edge property of bismuth oxide nanowires α-Bi2O3, Opt. Expr. 21(10), 11965–11972 (2013).

    Article  Google Scholar 

  13. Z. Wu, F. Huang, Y. Shen, A. Xie, X. Song, Facile fabrication and optical property of beta-Bi2O3 with novel porous nanoring and nanoplate superstructures, J. Nanopart. Res. 13, 4575–4582, (2011).

    Article  Google Scholar 

  14. A. Ajmal, I. Majeed, R.N. Malik, H. Idriss, M.A. Nadeem, Principles and mechanisms of photocatalytic dye degradation on TiO2 based photocatalysts: a comparative overview, RSC Adv. 4, 37003–37026, (2014).

    Article  Google Scholar 

  15. M.E. Hassan, J. Chen, G. Liu, D. Zhu, J. Cai, Enhanced photocatalytic degradation of methyl orange dye under the daylight irradiation over CN-TiO2 modified with OMS-2, Materials, 7, 8024–8036, (2014).

    Article  Google Scholar 

  16. A. Sobhani-Nasab, M. Behpour, Synthesis, characterization, and morphological control of Eu2Ti2O7 nanoparticles through green method and its photocatalyst application, J. Mater. Sci. 27, 11946–11951, (2016).

    Google Scholar 

  17. S.M. Hosseinpour-Mashkani, M. Maddahfar, A. Sobhani-Nasab, Precipitation synthesis, characterization, morphological, control, and photocatalyst application of ZnWO4 nanoparticles. J. Electron. Mater. 45, 3612 (2016).

    Article  Google Scholar 

  18. S.M. Hosseinpour-Mashkani, A. Sobhani-Nasab, A simple sonochemical synthesis and characterization of CdWO4 nanoparticles and its photocatalytic application, J. Mater. Sci., 27, 3240–3244 (2016).

    Google Scholar 

  19. S.M. Hosseinpour-Mashkani, M. Maddahfar, A. Sobhani-Nasab, Novel silver-doped CdMoO4: synthesis, characterization, and its photocatalytic performance for methyl orange degradation through the sonochemical method, J. Mater. Sci., 27, 474–480, (2016).

    Google Scholar 

  20. S.M. Hosseinpour-mashkani, A. Sobhani-Nasab, M. Mehrzad, Controlling the synthesis SrMoO4 nanostructures and investigation its photocatalyst application, J. Mater. Sci., 27, 5758–5763, (2016).

    Google Scholar 

  21. S.M. Hosseinpour-Mashkani, M. Ramezani, A. Sobhani-Nasab, M. Esmaeili-Zare, Synthesis, characterization, and morphological control of CaCu3Ti4O12 through modify sol-gel method, J. Mater. Sci. Mater. Electron, 26, 6086–6091, (2015).

    Article  Google Scholar 

  22. M. Arabatzis, T. Stergiopoulos, M.C. Bernard, D. Labou, S.G. Neophytides, P. Falaras, Silver-modified titanium dioxide thin films for efficient photodegradation of methyl orange. Appl. Catal. B 42, 187–201 (2003).

    Article  Google Scholar 

  23. S.M. Hosseinpour-mashkani, A. Sobhani-Nasab, Simple synthesis and characterization of copper tungstate nanoparticles: investigation of surfactant effect and its photocatalyst application. J. Mater. Sci. 27, 7548–7553 (2016).

    Google Scholar 

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Correspondence to Farid El-Tantawy.

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Al-Ghamdi, A.A., Al-Turki, Y., Aal, N.A. et al. Microwave—assisted hydrothermal synthesis of monoclinic bismuth trioxide nanorods: optical and photocatalytic properties. J Mater Sci: Mater Electron 28, 8684–8693 (2017). https://doi.org/10.1007/s10854-017-6593-3

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  • DOI: https://doi.org/10.1007/s10854-017-6593-3

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