Abstract
Fine particles in the atmosphere from soil and sand resuspension contain a variety of organic compounds from natural biogenic and anthropogenic matter. Soil and sand samples from various sites near Kuwait city were collected, sieved to retain the fine particles, and extracted with a mixture of dichloromethane and methanol. The extracts were derivatized and analyzed by gas chromatography-mass spectrometry in order to characterize the chemical compositions and sources of the organic components. The major inputs of organic compounds were from both natural biogenic and anthropogenic sources in these samples. Vegetation was the major natural source of organic compounds and included n-alkanols, n-alkanoic acids, n-alkanes, sterols and triterpenoids. Saccharides had high concentrations (31–43%) in the sand dune and seafront samples, indicating sources from decomposed vegation materials and/or the presence of viable microbiota such as bacteria and fungi. Vehicular emission products, leakage of lubricating oils, discarded plastics and emissions from cooking operations were the major anthropogenic inputs in the samples from the urban areas. This input was mainly UCM, n-alkanes, hopanes, plasticizers and cholesterol, respectively.
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Abas, M. and Simoneit, B. R. T.: 1996, ‘Composition of extractable organic matter of air particles from Malaysia: An initial study’, Atmos. Environ. 30, 2779–2793.
Abas, M., Simoneit, B. R. T., Elias, V. O., Cabral, J. A. and Cardoso, J. N.: 1995, ‘Composition of higher molecular weight organic matter in smoke aerosol from biomass combustion in Amazonia’, Chemosphere 30, 995–1015.
Al-Mutlaq, K., Rushdi, A. I. and Simoneit, B. R. T.: 2002, ‘Characteristics and sources of organic matter in desert sand samples from the Riyadh and Al-Qasim areas of Saudi Arabia: Preliminary results’, Arab Gulf J. Sci. Res. 20(3), 141–155.
Al-Mutlaq, K., Rushdi, A. I. and Simoneit, B. R. T.: 2004, ‘Organic compound tracers of fine soil and sand particles during summer in the metropolitan area of Riyadh, Saudi Arabia’, Water, Air and Soil Pollut. (submitted)
Bray, E. E. and Evans, E. D.: 1961, ‘Distribution of n-paraffins as a clue to recognition of source beds’, Geochimica et Cosmochimica Acta 22, 2–15.
Broddin, G., Cautreels, W. and van Cauwenberghe, D.: 1980, ‘On the aliphatic and polyaromatic hydrocarbon levels in urban and background aerosols from Belgium and the Netherlands’, Atmos. Environ. 14, 895–910.
Cass, G. R., Rogge, W. F., Gray, H. A., Hildemann, L. M., Markowski, G. R., Mazurek, M.A. and Simoneit, B. R. T.: 1993, ‘Source contributions to atmospheric carbon particle concentrations’, in: Southern California Air Quality Study, Data Analysis, Air & Waste Management Assoc., Pittsburgh, PA, pp. 110–115.
Fraser, M. P., Cass, G. R., Simoneit, B. R. T. and Rasmussen, R. A.: 1997, ‘Air quality model evaluation data for organics: 4. C2 to C36 non-aromatic hydrocarbons’, Environ. Sci. Technol. 31, 2356–2367.
Fraser, M. P., Cass, G. R. and Simoneit, B. R. T.: 1998a, ‘Gas-phase and particle-phase organic compounds emitted from motor vehicle traffic in a Los Angeles roadway tunnel’, Environ. Sci. Technol. 32, 2051–2060.
Fraser, M. P., Cass, G. R., Simoneit, B. R. T. and Rasmussen, R. A.: 1998b, ‘Air quality model evaluation data for organics: 5. C6–C22 nonpolar and semipolar aromatic compounds’, Environ. Sci. Technol. 32, 1760–1770.
Gagosian, R. B. and Peltzer, E. T.: 1986, ‘The importance of atmospheric input of terrestrial organic material to deep sea sediments’, Org. Geochem. 10, 661–669.
Gagosian, R. B., Peltzer, E. T. and Merrill, J. T.: 1987, ‘Long-range transport of terrestrially derived lipids in aerosols from the South Pacific’, Nature 325, 800–803.
Holloway, P. J., 1982, ‘The chemical contribution of plant cutins’, in: D. F. Cutler, K. L. Alvin and C. E. Price (eds.), The Plant Cuticle, Linnean Soc., Academic Press, London, pp. 45–85.
Ketseridis, G., Hahn, J., Jaenicke, R. and Junge, C.: 1976, ‘Organic constituents of atmospheric particulate matter’, Atmos. Environ. 10, 603–610.
Lehninger, A. L.: 1970, Biochemistry, Worth Publishers, Inc. New York, 833 pp.
Marty, J.-C. and Saliot, A.: 1982, ‘Aerosols in equatorial Atlantic air: n-alkanes as a function of particle size’, Nature 298, 144–147.
Matsumoto, G. and Hanya, T.: 1980. ‘Organic constituents in atmospheric fallout in the Tokyo area’, Atmos. Environ. 14, 1409–1419.
Mazurek, M. A., Simoneit, B. R. T. and Cass, G. R.: 1989, ‘Interpretation of high-resolution gas chromatography and high resolution gas chromatography/mass spectrometry data acquired from atmospheric organic aerosol samples’, Aerosol Sci. Technol. 10, 408–420.
Rogge, W. F., Hildemann, L. M., Mazurek, M. A., Cass, G. R. and Simoneit, B. R. T.: 1991, ‘Sources of fine organic aerosol: 1 – Charbroilers and meat cooking operations’, Environ. Sci. Technol. 25, 1112–1125.
Rogge, W. F., Mazurek, M. A., Hildemann, L. M., Cass, G. R., Simoneit and B. R. T.: 1993a, ‘Quantification of organic aerosols on a molecular level: Identification, abundance and seasonal variation’, Atmosph. Environ. 27A, 1309–1330.
Rogge, W. F., Hildemann, L. M., Mazurek, M. A., Cass, G. R. and Simoneit, B. R. T.: 1993b, ‘Sources of fine organic aerosol: 2. Noncatalyst and catalyst-equipped automobiles and heavy-duty diesel trucks’, Environ. Sci. Technol. 27, 636–651.
Rogge, W. F., Hildemann, L. M., Mazurek, M. A., Cass, G. R. and Simoneit, B. R. T.: 1993c, ‘Sources of fine organic aerosol. 3. Road dust, tire debris, and organometallic brake lining dust: Roads as sources and sinks’, Environ. Sci. Technol. 27, 1892–1904.
Rogge, W. F., Hildemann, L. M., Mazurek, M. A., Cass, G. R. and Simoneit, B. R. T.: 1993d, ‘Sources of fine organic aerosol: 4. Particulate abrasion products from leaf surfaces of urban plants’, Environ. Sci. Technol. 27, 2700–2711.
Rogge, W. F., Hildemann, L. M., Mazurek, M. A., Cass, G. R. and Simoneit, B. R. T.: 1993e, ‘Sources of fine organic aerosol: 5. Natural gas home appliances’, Environ. Sci. Technol. 27, 2736–2744.
Rogge, W. F., Hildemann, L. M., Mazurek, M. A., Cass, G. R. and Simoneit, B. R. T.: 1994, ‘Sources of fine organic aerosol: 6. Cigarette smoke in the urban atmosphere’, Environ. Sci. Technol. 28, 1375–1388.
Rogge, W. F., Hildemann, L. M., Mazurek, M. A., Cass, G. R. and Simoneit, B. R. T.: 1996, ‘Mathematical modeling of atmospheric fine particle-associated primary organic compound concentrations’, J. Geophys. Res. 101(D14), 19379–19394.
Rogge, W. F., Hildemann, L. M., Mazurek, M. A., Cass, G. R. and Simoneit, B. R. T.: 1997a, ‘Sources of fine organic aerosol: 7. Hot asphalt roofing tar pot fumes’, Environ. Sci. Technol. 31, 2726–2730.
Rogge, W. F., Hildemann, L. M., Mazurek, M. A., Cass, G. R. and Simoneit, B. R. T.: 1997b, ‘Sources of fine organic aerosol: 8. Boilers burning No. 2 distillate fuel oil’, Environ. Sci. Technol. 31, 2731–2737.
Rogge, W. F., Hildemann, L. M., Mazurek, M. A., Cass, G. R. and Simoneit, B. R. T.: 1998, ‘Sources of fine organic aerosol: 9. Pine, oak and synthetic log combustion in residential fireplaces’, Environ. Sci. Technol. 32, 13–22.
Rogge, W. F., Medeiros, P. M. and Simoneit, B. R. T.: 2004, ‘Saccharides and other organic tracers in soil samples from the Fugitive Dust Characterization Study’, Atmos. Environ. to be submitted.
Rushdi, A. I., Al-Mutlaq K. and Simoneit, B. R. T. 2005, ‘Sources of organic compounds in fine soil and sand particles during winter in the metropolitan area of Riyadh, Saudi Arabia’, Arch. Environ. Contam. Toxicol. 49, 547–470.
Schauer, J. J., Rogge, W. F., Hildemann, L. M., Mazurek, M. A., Cass, G. R. and Simoneit, B .R. T.: 1996, ‘Source apportionment of airborne particulate matter using organic compounds as tracers’, Atmos. Environ. 30, 3837–3855.
Simoneit, B. R. T.: 1977, ‘Organic matter in eolian dusts over the Atlantic Ocean’, Mar. Chem. 5, 443–464.
Simoneit, B. R. T.: 1980, ‘Eolian particulates from oceanic and rural areas – Their lipids, fulvic and humic acids and residual carbon’, in: A. G. Douglas and J. R. Maxwell (eds.), Advances in Organic Geochemistry 1979, Pergamon Press, Oxford, pp. 343–352.
Simoneit, B. R. T.: 1984, ‘Organic matter of the troposphere – III. Characterization and sources of petroleum and pyrogenic residues in aerosols over the western United States’, Atmos. Environ. 18, 51–67.
Simoneit, B. R. T.: 1986, ‘Characterization of organic constituents in aerosols in relation to their origin and transport: A review’, Int. J. Environ. Anal. Chem. 23, 207–237.
Simoneit, B. R. T.: 1989, ‘Organic matter of troposphere – V: Application of molecular marker analysis to biogenic emissions into the troposphere for source reconciliations’, J. Atmos. Chem. 8, 251–275.
Simoneit, B. R. T.: 1998, ‘Biomarker PAHs in the environment’, in: A. H. Neilson (ed.), The Handbook of Environmental Chemistry, vol. 3, Part I, Springer Verlag, Berlin, pp. 175–221.
Simoneit, B. R. T.: 1999, ‘A review of biomarker compounds as source indicators and tracers for air pollution’, Environ. Sci. Pollut. Res. 6, 153–163.
Simoneit, B. R. T. and Mazurek, M. A.: 1982, ‘Organic matter of the troposphere – II. Natural background of biogenic lipid matter in aerosols over the rural western United States’, Atmos. Environ. 16, 2139–2159.
Simoneit, B. R. T. and Mazurek, M. A.: 1989, ‘Organic tracers in ambient aerosols and rain’, Aerosol Sci Technol. 10, 267–291.
Simoneit, B. R. T., Mazurek, M. A. and Reed, W. E.: 1983, ‘Characterization of organic matter in aerosols over rural sites: Phytosterols’, in: M. Bjorøy et al. (eds.), Advances in Organic Geochemistry 1981, J. Wiley and Sons Ltd., Chichester, pp. 355–361.
Simoneit, B. R. T., Cox, R. E. and Standley, L. J.: 1988, ‘Organic matter of the troposphere – IV: Lipids in Harmattan aerosols of Nigeria’, Atmosph. Environment 22, 983–1004.
Simoneit, B. R. T., Cardoso, J. N. and Robinson, N.: 1990, ‘An assessment of the origin and composition of higher molecular weight organic matter in aerosols over Amazonia’, Chemosphere 21, 1285–1301.
Simoneit, B. R. T., Crisp, P. T., Mazurek, M. A. and Standley, L. J.: 1991a, ‘Composition of extractable organic matter of aerosols from the Blue Mountains and southeast coast of Australia’, Environ. Internat. 17, 405–419.
Simoneit, B. R. T., Sheng, G., Chen, X., Fu, J., Zhang, J. and Xu, Y.: 1991b, ‘Molecular marker study of extractable organic matter in aerosols from urban areas of China’, Atmosph. Environ. 25A, 2111–2129.
Simoneit, B. R. T., Cardoso, J. N. and Robinson, N.: 1991c, ‘An assessment of terrestrial higher molecular weight lipid compounds in air particulate matter over the South Atlantic from about 30–70°S’, Chemosphere, 23, 447–465.
Simoneit, B. R. T., Rogge, W. F., Mazurek, M. A., Standley, L. J., Hildemann, L. M. and Cass, G. R.: 1993, ‘Lignin pyrolysis products, lignans and resin acids as specific tracers of plant classes in emissions from biomass combustion’, Environ. Sci. Technol. 27, 2533–2541.
Simoneit, B. R. T., Schauer, J. J., Nolte, C. G., Oros, D. R., Elias, V. O., Fraser, M. P., Rogge W. F. and Cass, G. R.: 1999, ‘Levoglucosan, a tracer for cellulose in biomass burning and atmospheric particles’, Atmosph. Environ. 33, 173–182.
Simoneit, B. R. T., Elias, V. O., Kobayashi, M., Kawamura, K., Rushdi, A. I., Medeiros, P. M., Rogge, W. F. and Didyk, B. M.: 2004, ‘Sugars – dominant water-soluble organic compounds in soils and characterization as tracers in atmospheric particulate matter’, Environ. Sci. Technol. 38, 5939–5949.
Standley, L. J. and Simoneit, B. R. T.: 1987, ‘Composition of extractable plant wax, resin and thermally matured components in smoke particles from prescribed burns’, Environ. Sci. Technol. 21, 163–169.
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Rushdi, A.I., Al-Zarban, S. & Simoneit, B.R.T. Chemical Compositions and Sources of Organic Matter in Fine Particles of Soils and Sands from the Vicinity of Kuwait City. Environ Monit Assess 120, 537–557 (2006). https://doi.org/10.1007/s10661-005-9102-8
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DOI: https://doi.org/10.1007/s10661-005-9102-8