Abstract
New catalysts prepared by simple mixing of molecular iodine and inexpensive monodonor amines can efficiently catalyze the coupling of CO2 with different epoxides at moderate temperatures (60–90 °C), pressures (10–56 atm) and low (0.25–0.5 mol %) catalytic loading. The molecular systems can be considered as the simplest and most inexpensive catalyst for the reactions.
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Acknowledgements
The authors are grateful to the Center for the Study of Molecular Structure of the INEOS RAS of the Ministry of Science and Higher Education of the Russian Federation for the analysis by Raman spectroscopy and valuable advice. This work was supported by Russian science foundation (RSF-DST) grant № 19-43-02031. Biswajit Chowdhury wants to acknowledge DST for funding under the Indo-Russian project (Grant No DST/INT/RUS/P-25).
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Chowdhury, B., Zvinchuk, A.A., Aysin, R.R. et al. Amine-Iodine Adducts as Simple but Effective Catalysts for the Synthesis of Organic Carbonates from Epoxides and CO2. Catal Surv Asia 25, 419–423 (2021). https://doi.org/10.1007/s10563-021-09341-9
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DOI: https://doi.org/10.1007/s10563-021-09341-9