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Synthesis and Catalytic Property of Fibrous Titanium-Containing Graphite Oxide

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Abstract

A new layered graphite oxide is synthesized by a two-step oxidation of commercial graphite powders, which is further covalently modified by a titanium complex in order for oxidation of alkenes. Characterizations reveal the present graphite oxide is thicker than classical graphene oxide, but shows fibrous morphology after modification of titanium complex. Furthermore, the composition and morphology of synthetic composite are highly relative to the heating condition in preparation. In catalysis, high conversions of alkenes as well as various oxidized products are obtained by using available and green terminal oxidants. Lastly, a composite catalyst is reused for nine rounds in oxidation of R-(+)-limonene, approving its satisfactory stability for recycling. This work provides a highly promising catalytic material, showing values for the design of solid catalysts.

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Acknowledgements

This study was supported by the Fundamental Research Funds for the Central Universities (No. xjj2014005, Application of Porous Helical Materials in Catalytic Asymmetric Reactions).

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Authors and Affiliations

  1. Department of Applied Chemistry, School of Science, Xi’an Jiaotong University, No. 28, Xianning West Road, Xi’an, 710049, People’s Republic of China

    Cheng Pan, Benhua Huang, Xiaoyong Li, Aqun Zheng, Yu Li & Yang Sun

  2. School of Materials & Chemical Engineering, Xi’an Technological University, No. 2, Xuefu Road, Xi’an, 710021, People’s Republic of China

    Hua Zhu & Donghua Zhang

Authors
  1. Cheng Pan
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  2. Benhua Huang
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  3. Xiaoyong Li
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  4. Hua Zhu
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  5. Donghua Zhang
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  7. Yu Li
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Correspondence to Xiaoyong Li or Yang Sun.

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Pan, C., Huang, B., Li, X. et al. Synthesis and Catalytic Property of Fibrous Titanium-Containing Graphite Oxide. Catal Surv Asia 21, 160–174 (2017). https://doi.org/10.1007/s10563-017-9233-2

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