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Supported NHC-Benzimi@Cu Complex as a Magnetically Separable and Reusable Catalyst for the Multicomponent and Click Synthesis of 1,4-Disubstituted 1,2,3-Triazoles via Huisgen 1,3-Dipolar Cycloaddition

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Abstract

In this paper, we report a novel magnetically separable silica coated copper nano-magnetite NHC-benzimi@Cu complex as heterogeneous catalyst for the multicomponent click reaction via Huisgen 1,3-dipolar cycloaddition reaction of alkyl or aryl halide, sodium azide and terminal alkyne, which affords various1,4-disubstituted 1,2,3-triazoles. The multistep prepared nano catalyst has been characterized by various spectroscopic methods such as FT-IR, TGA, EDX, XRD, TEM and VSM. The heterogeneous nano catalyst structures coated on the copper surface are responsible for the excellent catalyst performances in the reaction. The reusability of the catalyst makes the present protocol more fascinating from an environmental and economic point of view.

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Acknowledgements

We gratefully acknowledge Indian Institute of Bombay (IITB), North-Eastern Hill University Shillong (NEHU), Indian Institute of Technology, Madras (IITM) for providing spectral facilities and Central Facility Centre (CFC) Shivaji University Kolhapur for providing quantitative spectral analysis.

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Authors and Affiliations

  1. Department of Chemistry, Padmabhushan Dr. Vasantraodada Patil College, Dist. Sangli., Tasgaon, M. S., 416312, India

    Arvind Pawar, Ashutosh Jagdale, Sandip Patil & Suresh Patil

  2. Department of Chemistry, Shivaji University, Kolhapur, M. S., 416004, India

    Shivanand Gajare, Wilson Chandane & Gajanan Rashinkar

  3. Department of Chemistry, Shikshanmaharshi Dr.Bapuji Salunkhe College, Miraj, M. S., 416412, India

    Arvind Pawar

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  1. Arvind Pawar
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  2. Shivanand Gajare
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Correspondence to Suresh Patil.

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Pawar, A., Gajare, S., Jagdale, A. et al. Supported NHC-Benzimi@Cu Complex as a Magnetically Separable and Reusable Catalyst for the Multicomponent and Click Synthesis of 1,4-Disubstituted 1,2,3-Triazoles via Huisgen 1,3-Dipolar Cycloaddition. Catal Lett 152, 1854–1868 (2022). https://doi.org/10.1007/s10562-021-03772-9

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