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Effective Catalyst for Oxidation Synthesis of 2,4,6-Trimethylbenzoyldipenylphosphine Oxide: V/MCM-41

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Abstract

2,4,6-Trimethylbenzoyldipenylphosphine oxide (TPO) is an important photoinitiator, nevertheless some drawbacks exist in its synthesis. So V/MCM-41 catalysts were designed. Compared with commonly used VO(acac)2, V/MCM-41 catalysts exhibited excellent TPO yield (92.5%), which makes the usage of inorganic vanadium possible and is benefit both in academic and in industry.

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Acknowledgements

This work was founded by National Natural Science Foundation of China (Grant No. 21103099), Basic Research Projects in Science and Technology Program of Qingdao (13-1-4-242-jch) and Research Foundation of Qingdao Fusilin Chemical Science &Technology Co., Ltd. (FSL-RF 2016).

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Authors and Affiliations

  1. College of Materials Science and Engineering, Shandong University of Science and Technology, Qingdao, 266590, China

    Tingting Wang, Zhiming Wang, Junjing Zhao, Qing Yu & Zhongwei Wang

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  1. Tingting Wang
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  2. Zhiming Wang
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  3. Junjing Zhao
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  4. Qing Yu
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  5. Zhongwei Wang
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Correspondence to Qing Yu or Zhongwei Wang.

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Wang, T., Wang, Z., Zhao, J. et al. Effective Catalyst for Oxidation Synthesis of 2,4,6-Trimethylbenzoyldipenylphosphine Oxide: V/MCM-41. Catal Lett 148, 953–957 (2018). https://doi.org/10.1007/s10562-018-2299-2

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  • DOI: https://doi.org/10.1007/s10562-018-2299-2

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