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Understanding the Effect of NO Adsorption on Potassium-Promoted Co3O4 for N2O Decomposition

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Abstract

Co3O4 and K/Co3O4 were tested in catalytic N2O decomposition. K/Co3O4 exhibited higher activity than Co3O4, which was drastically and irrecoverably decreased with added NO. Studies revealed that the Co2+ valence state changed after NO adsorption, and that potassium strengthened the Co–NO bond, impeding NO desorption, even above 400 °C.

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References

  1. Thiemens MH, Trogler WC (1991) Science 251:932

    Article  CAS  Google Scholar 

  2. Pérez-Ramírez J, Kapteijn F, Schöffel K, Moulijn JA (2003) Appl Catal B 44:117

    Article  Google Scholar 

  3. Kapteijn F, Rodriguez-Mirasol J, Moulijn JA (1996) Appl Catal B 9:25

    Article  CAS  Google Scholar 

  4. Li Y, Armor JN (1992) Appl Catal B 1:L21

    Article  CAS  Google Scholar 

  5. Centi G, Perathoner S, Vazzana F, Marella M, Tomaselli M, Mantegazza M (2000) Adv Environ Res 4:325

    Article  Google Scholar 

  6. Konsolakis M (2015) ACS Catal 5:6397

    Article  CAS  Google Scholar 

  7. Russo N, Fino D, Saracco G, Specchia V (2007) Catal Today 119:228

    Article  CAS  Google Scholar 

  8. Drago RS, Jurczyk K, Kob N (1997) Appl Catal B 13:69

    Article  CAS  Google Scholar 

  9. Obalová L, Karásková K, Wach A, Kustrowski P, Mamulová-Kutláková K, Michalik S, Jirátová K (2013) Appl Catal A 462–463:227

    Article  Google Scholar 

  10. Stelmachowski P, Maniak G, Kotarba A, Sojka Z (2008) Catal Commun 10:1062

    Article  Google Scholar 

  11. Tolman WB (2010) Angew Chem 49:1018

    Article  CAS  Google Scholar 

  12. Trogler WC (1999) Coordin Chem Rev 187:303

    Article  CAS  Google Scholar 

  13. Franken T, Palkovits R (2015) Appl Catal B 176–177:298

    Article  Google Scholar 

  14. Shen Q, Li L, Li J, Tian H, Hao Z (2009) J Hazard Mater 163:332

    Google Scholar 

  15. Xue L, Zhang C, He H, Teraoka Y (2007) Appl Catal B 75:167

    Article  CAS  Google Scholar 

  16. Asano K, Ohnishi C, Iwamoto S, Shioya Y, Inoue M (2008) Appl Catal B 78:242

    Article  CAS  Google Scholar 

  17. Bomben K, Moulder J, Sobol PE, Stickle W (1995) Handbook of X-ray photoelectron spectroscopy. Physical Electronics, Eden Prairie

    Google Scholar 

  18. Xue L, He H, Liu C, Zhang C, Zhang B (2009) Environ Sci Technol 43:890

    Article  CAS  Google Scholar 

  19. Chellam U, Xu Z, Zeng H (2000) Chem Mater 12:650

    Article  CAS  Google Scholar 

  20. Pitchon V, Guenin M, Praliaud H (1990) Appl Catal 63:333

    Article  CAS  Google Scholar 

  21. Haneda M, Kintaichi Y, Hamada H (2005) Appl Catal B 55:169

    Article  CAS  Google Scholar 

  22. Yan L, Ren T, Wang X, Ji D, Suo J (2003) Appl Catal B 45:85

    Article  CAS  Google Scholar 

  23. Hadjiivanov KI (2000) Catal Rev 42:71

    Article  CAS  Google Scholar 

  24. Pietrogiacomi D, Campa MC, Carbone LR, Tuti S, Occhiuzzi M (2016) Appl Catal B 187:218

    Article  CAS  Google Scholar 

  25. Park P, Kil J, Kung H, Kung M (1998) Catal Today 42:51

    Article  CAS  Google Scholar 

  26. Haneda M, Kintaichi Y, Bion N, Hamada H (2003) Appl Catal B 46:473

    Article  CAS  Google Scholar 

  27. Imanaka N, Masui T (2012) Appl Catal A 431–432:1

    Article  Google Scholar 

  28. Zasada F, Stelmachowski P, Maniak G, Paul J-F, Kotarba A, Sojka Z (2008) Catal Lett 127:126

    Article  Google Scholar 

Download references

Acknowledgements

This project was supported by the “R&D Center for Reduction of Non-CO2 Greenhouse Gases (2013001690010)” funded by the Korea Ministry of Environment (MOE) as a “Global Top Environment R&D Program.”

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Correspondence to Chang Hyun Ko or Sang Goo Jeon.

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Kim, MJ., Lee, SJ., Ryu, IS. et al. Understanding the Effect of NO Adsorption on Potassium-Promoted Co3O4 for N2O Decomposition. Catal Lett 147, 2886–2892 (2017). https://doi.org/10.1007/s10562-017-2180-8

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  • DOI: https://doi.org/10.1007/s10562-017-2180-8

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