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Iodosobenzoic Acid (IBA) Catalysed Benzylic and Aromatic C–H Oxidations

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Abstract

A metal-free reusable hypervalent iodine(III) reagent is employed as a stable catalyst for the selective oxidation of active methylenes, indoles and styrene C–H bond to corresponding carbonyl compounds. From both economic and environmental point of view use of 2-Iodosobenzoic acid for oxidations replacing metals, makes the reaction interesting.

Graphical Abstract

A metal-free reusable hypervalent iodine(III) reagent is employed as a stable catalyst for the selective oxidation of active methylenes, Indoles and styrene C–H bond to corresponding carbonyl compounds. From both an economic and environmental point of view use of oxygen as the oxidant, makes the reaction interesting.

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Acknowledgements

PSP gratefully acknowledge to the financial assistance provided by CSIR-Senior Research Associateship (Scientist’s Pool Scheme), New Delhi and VHB (JRF), thanks for the fellowship provided by DST, Govt of India. We also acknowledge director IICT for providing infrastructural facilities.

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Authors and Affiliations

  1. Crop Protection Chemicals Division, Indian Institute of Chemical Technology, Hyderabad, 500607, India

    Vittam Hima Bindu, Sai Prathima Parvathaneni & Vaidya Jayathirtha Rao

  2. AcSIR, Organic-II, Indian Institute of Chemical Technology, Hyderabad, 500607, India

    Vaidya Jayathirtha Rao

Authors
  1. Vittam Hima Bindu
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  2. Sai Prathima Parvathaneni
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  3. Vaidya Jayathirtha Rao
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Corresponding authors

Correspondence to Sai Prathima Parvathaneni or Vaidya Jayathirtha Rao.

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Bindu, V.H., Parvathaneni, S.P. & Rao, V.J. Iodosobenzoic Acid (IBA) Catalysed Benzylic and Aromatic C–H Oxidations. Catal Lett 147, 1434–1440 (2017). https://doi.org/10.1007/s10562-017-2050-4

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  • DOI: https://doi.org/10.1007/s10562-017-2050-4

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